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    PROCESS FOR PREPARING A MACROMONOMER
    1.
    发明申请
    PROCESS FOR PREPARING A MACROMONOMER 审中-公开
    生产大分子单体的方法

    公开(公告)号：WO2014095608A3

    公开(公告)日：2014-12-24

    申请号：PCT/EP2013076499

    申请日：2013-12-13

    Applicant: BASF SE

    Inventor： BITTNER CHRISTIAN ,  LANGLOTZ BJÖRN ,  WENZKE BENJAMIN ,  SPINDLER CHRISTIAN ,  REICHENBACH-KLINKE ROLAND ,  KLUMPE MARKUS ,  MEIER NICOLE ,  ANNEN ULRICH ,  OSTROWSKI THOMAS

    IPC: C08G65/26 ,  C08F216/14

    CPC classification number: C08G65/2696 ,  C08F216/1416 ,  C08F290/062 ,  C08F2216/1425 ,  C08G65/2609 ,  C08G65/2648 ,  C08G2650/36 ,  C08F220/58 ,  C08F2220/585 ,  C08F220/56

    Abstract: The present invention relates to a process for the preparation of hydrophobically associating macromonomers M and to the novel macromonomers produced by the inventive method. The macromonomers M comprise a copolymerizable, ethylenically unsaturated group and a polyether structure in block form which comprises a polyethylenoxy block and a hydrophobic polyalkylenoxy block consisting of alkylenoxy-units with at least 4 carbon atoms. Optionally, the macromonomers M may comprise a terminal polyethylenoxy block. The macromonomers produced by the inventive method are suitable for reaction with other monomers, in particular with acrylamide, to form a water-soluble, hydrophobically associating copolymer.

    Abstract translation: 本发明涉及一种用于疏水缔合大分子单体M和由本发明方法生产的新的大分子单体的制备方法。 大分子单体中号包括可共聚的烯键式不饱和基团和以框图的形式，它是由一个聚乙烯氧嵌段和具有至少4个碳原子的亚烷基氧基单元的聚亚烷基的疏水性嵌段的聚醚结构。 任选地，大分子单体M可具有末端聚氧乙烯嵌段。 通过本发明的方法制备的大分子单体是适合于与其它单体，特别是与丙烯酰胺反应成水溶性疏水缔合共聚物。

    PROCESS FOR THE ALKOXYLATION OF AMINO GROUP CONTAINING POLYMERS
    2.
    发明申请
    PROCESS FOR THE ALKOXYLATION OF AMINO GROUP CONTAINING POLYMERS 审中-公开
    含氨基聚合物的烷氧基化工艺

    公开(公告)号：WO2009065805A3

    公开(公告)日：2009-07-09

    申请号：PCT/EP2008065671

    申请日：2008-11-17

    Applicant: BASF SE ,  BOECKH DIETER ,  FRENZEL STEFAN ,  BITTNER CHRISTIAN ,  MISSKE ANDREA ,  ANNEN ULRICH ,  SAGER WILFRIED ,  EBERT SOPHIA ,  EICHHORN ANDREAS

    Inventor： BOECKH DIETER ,  FRENZEL STEFAN ,  BITTNER CHRISTIAN ,  MISSKE ANDREA ,  ANNEN ULRICH ,  SAGER WILFRIED ,  EBERT SOPHIA ,  EICHHORN ANDREAS

    IPC: C08G65/00 ,  C08G65/30

    CPC classification number: C08G65/2618 ,  C08G65/2633 ,  C08G65/2648 ,  C08L71/02 ,  C08L77/00 ,  C08L79/00 ,  C08L2666/20

    Abstract: The present invention relates to a process for the alkoxylation of a first polymer comprising at least one monomer unit having NH groups and optionally NH2 groups, wherein the first polymer has a molecular weight Mw of at least 500 g/mol, comprising the steps of (a) reacting the first polymer with alkylene oxide in a reaction mixture comprising a solvent until the average degree of alkoxylation of each NH group and each optional NH2 group, calculated as two NH groups, is from 0.75 to 1.25; (b) adding a second polymer of formula (I), wherein R is a linear or branched alkyl group having from 1 to 20 carbon atoms, each R' is independently a linear or branched alkyl group having from 1 to 20 carbon atoms or hydrogen, each n is independently from 1 to 5 and m is from 5 to 40, to the reaction mixture of step (a); (c) at least partially removing the solvent from the reaction mixture of step (b); and (d) further reacting the reaction mixture of step (c) with alkylene oxide at a given temperature until the average degree of alkoxylation of each NH group and each optional NH2 group, calculated as two NH groups, of the first polymer is from 2 to 40. The present invention also relates to a polymer composition obtainable from that process and the use of such a polymer composition.

    Abstract translation: 本发明涉及包含至少一种具有NH基团和任选的NH 2基团的单体单元的第一聚合物的烷氧基化方法，其中第一聚合物具有至少500g / mol的分子量Mw，所述方法包括以下步骤： a）使第一聚合物与烯化氧在包含溶剂的反应混合物中反应，直到每个NH基团和每个任选的NH 2基团的平均烷氧基化程度（作为两个NH基团计算）为0.75至1.25; （b）加入式（I）的第二聚合物，其中R为具有1至20个碳原子的直链或支链烷基，每个R'独立地为具有1至20个碳原子的直链或支链烷基或氢 （a）的反应混合物中，每个n独立地为1至5且m为5至40; （c）至少部分地从步骤（b）的反应混合物中除去溶剂; （d）使步骤（c）的反应混合物与烯化氧在给定温度下进一步反应，直到第一聚合物中每个NH基团和任选的NH 2基团的平均烷氧基化度（作为两个NH基团计算）为2 本发明还涉及可从该方法获得的聚合物组合物和这种聚合物组合物的用途。

    4.
    发明专利
    未知

    公开(公告)号：BRPI0713128A2

    公开(公告)日：2012-04-17

    申请号：BRPI0713128

    申请日：2007-06-12

    Applicant: BASF SE

    Inventor： EISENBEIS ANSGAR ,  TROETSCH-SCHALLER IRENE ,  ANNEN ULRICH

    IPC: C10L1/222 ,  C10L1/224 ,  C10L1/2383 ,  C10L10/14 ,  C10L10/16

    Abstract: Provided is a mixture containing: (a) a polar oil-soluble nitrogen compounds which is capable of sufficiently dispersing paraffin crystals precipitated out under cold conditions in a fuel and is a reaction product formed from reacting a poly(C2- to C20-carboxylic acid), which has at least one tertiary amino group, with a primary or secondary amine; (b) an oil-soluble acid amide reaction product formed from reacting a polyamide, which has from 2 to 1000 carbon atoms, with a C8- to C30-fatty acid or fatty acid-like compound, which has a free carboxyl group; and (c) an oil-soluble reaction product formed from reacting an α,&bgr;-dicarboxylic acid, which has from 4 to 300 carbon atoms, or a derivatives thereof, with a primary alkylamine, wherein the sum of components (a) to (c) constitute 100 wt. % of the mixture. The mixture is suitable as a paraffin dispersant in fuels, especially those having a biodiesel content.

    6.
    发明专利
    未知

    公开(公告)号：AT451441T

    公开(公告)日：2009-12-15

    申请号：AT07730085

    申请日：2007-06-12

    Applicant: BASF SE

    Inventor： EISENBEIS ANSGAR ,  TROETSCH-SCHALLER IRENE ,  ANNEN ULRICH

    IPC: C10L1/222 ,  C10L1/224 ,  C10L1/2383 ,  C10L10/14

    Abstract: Provided is a mixture containing: (a) a polar oil-soluble nitrogen compounds which is capable of sufficiently dispersing paraffin crystals precipitated out under cold conditions in a fuel and is a reaction product formed from reacting a poly(C2- to C20-carboxylic acid), which has at least one tertiary amino group, with a primary or secondary amine; (b) an oil-soluble acid amide reaction product formed from reacting a polyamide, which has from 2 to 1000 carbon atoms, with a C8- to C30-fatty acid or fatty acid-like compound, which has a free carboxyl group; and (c) an oil-soluble reaction product formed from reacting an α,&bgr;-dicarboxylic acid, which has from 4 to 300 carbon atoms, or a derivatives thereof, with a primary alkylamine, wherein the sum of components (a) to (c) constitute 100 wt. % of the mixture. The mixture is suitable as a paraffin dispersant in fuels, especially those having a biodiesel content.

    PROCESO PARA PREPARAR UN MACROMONOMERO.
    7.
    发明专利
    PROCESO PARA PREPARAR UN MACROMONOMERO. 未知

    公开(公告)号：MX377939B

    公开(公告)日：2025-03-11

    申请号：MX2015007837

    申请日：2015-06-17

    Applicant: BASF SE

    Inventor： WENZKE BENJAMIN ,  LANGLOTZ BJÖRN ,  BITTNER CHRISTIAN ,  SPINDLER CHRISTIAN ,  KLUMPE MARKUS ,  MEIER NICOLE ,  REICHENBACH-KLINKE ROLAND ,  OSTROWSKI THOMAS ,  ANNEN ULRICH

    IPC: C08G65/26 ,  C08F216/14

    Abstract: La presente invención se refiere a un proceso para preparar macromonómeros hidrofóbicamente asociados M y a los nuevos macromonómeros preparados por medio del proceso de acuerdo con la invención. Los macromonómeros M comprenden un grupo copolimerizable etilénicamente insaturado y una estructura de poliéter en forma de bloque, donde el último consiste en un bloque de polietilenoxi y un bloque de polialquilenoxi hidrofóbico que consiste en unidades de alquilenoxi que tiene al menos 4 átomos de carbono. Opcionalmente, los macromonómeros M pueden tener un bloque polietilenoxi terminal. Los macromonómeros preparados por el proceso de acuerdo con la invención son apropiados para reaccionar con otros monómeros, en especial con acrilamida, para dar un copolímero hidrosoluble hidrofóbicamente asociado.

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