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    CHEMICAL PRODUCTION PROCESSES, SYSTEMS, AND CATALYST COMPOSITIONS
    1.
    发明申请
    CHEMICAL PRODUCTION PROCESSES, SYSTEMS, AND CATALYST COMPOSITIONS 审中-公开
    化学生产过程，体系和催化剂组合物

    公开(公告)号：WO2009029540A3

    公开(公告)日：2009-09-17

    申请号：PCT/US2008074090

    申请日：2008-08-22

    Applicant: BATTELLE MEMORIAL INSTITUTE ,  PETERSON THOMAS H ,  HOLLADAY JOHNATHAN E ,  ZACHER ALAN H ,  GRAY MICHEL J ,  WERPY TODD A ,  WHITE JAMES F

    Inventor： PETERSON THOMAS H ,  HOLLADAY JOHNATHAN E ,  ZACHER ALAN H ,  GRAY MICHEL J ,  WERPY TODD A ,  WHITE JAMES F

    IPC: C07C45/52 ,  B01J27/16 ,  C07C47/22

    CPC classification number: C07C45/52 ,  C07C49/17 ,  C07C47/22

    Abstract: Chemical production processes are provided that include exposing a reactant composition to a catalyst composition to form a product composition, with the reactant composition including a multihydric alcohol compound and the catalyst composition being effective to dehydrate at least a portion of the multihydric alcohol compound. Embodiments of the process provide that the reactant composition is exposed to the catalyst composition for less than about 0.25 seconds and/or that the catalyst is maintained at a temperature of from about 2800C to about 3200C. Processes utilizing a reactant composition including a multihydric alcohol compound and an inert compound are also provided.

    Abstract translation: 提供化学生产方法，其包括将反应物组合物暴露于催化剂组合物以形成产物组合物，其中反应物组合物包含多元醇化合物并且催化剂组合物有效使至少一部分多元醇化合物脱水。 该方法的实施方案规定反应物组合物暴露于催化剂组合物小于约0.25秒和/或催化剂保持在约280℃至约320℃的温度。 还提供了利用包含多元醇化合物和惰性化合物的反应物组合物的方法。

    HYDROGENOLYSIS PROCESSES AND HYDROGENOLYSIS CATALYST PREPARATION METHODS
    4.
    发明申请
    HYDROGENOLYSIS PROCESSES AND HYDROGENOLYSIS CATALYST PREPARATION METHODS 审中-公开
    氢化方法和氢化催化剂制备方法

    公开(公告)号：WO2009129325A3

    公开(公告)日：2010-03-18

    申请号：PCT/US2009040695

    申请日：2009-04-15

    Applicant: BATTELLE MEMORIAL INSTITUTE ,  HOLLADAY JOHNATHAN E ,  WHITE JAMES F ,  PETERSON THOMAS H ,  FRYE JOHN G ,  MUZATKO DANIELLE S ,  BARE SIMON R ,  VASSILAKIS JAMES G ,  ROSIN RICHARD R

    Inventor： HOLLADAY JOHNATHAN E ,  WHITE JAMES F ,  PETERSON THOMAS H ,  FRYE JOHN G ,  MUZATKO DANIELLE S ,  BARE SIMON R ,  VASSILAKIS JAMES G ,  ROSIN RICHARD R

    IPC: B01J21/18 ,  B01J23/889 ,  B01J23/89 ,  B01J37/18 ,  C07C17/23

    CPC classification number: B01J21/18 ,  B01J23/8896 ,  B01J23/8986 ,  B01J37/18

    Abstract: Hydrogenolysis processes are provided that can include providing a hydrogenolysis reactor having a catalyst therein. The catalyst can be exposed to a reducing agent in the absence of polyhydric alcohol compound while maintaining a temperature of the catalyst above 290°C. Hydrogenolysis processes can also include providing a passivated catalyst to within a reactor and exposing the catalyst to a reducing atmosphere while maintaining the catalyst at a temperature less than 210°C. Hydrogenolysis catalyst preparation methods are provided that can include exposing the catalyst to a first reducing atmosphere while maintaining the catalyst at a first temperature to reduce at least a portion of the catalyst. The method can also include passivating at least the portion of the catalyst and depassivating the portion of the catalyst in the presence of a second reducing atmosphere while maintaining the portion of the catalyst at a second temperature less than the first temperature.

    Abstract translation: 提供氢解方法，其可以包括提供其中具有催化剂的氢解反应器。 催化剂可以在不存在多元醇化合物的情况下暴露于还原剂，同时将催化剂的温度保持在290℃以上。 氢解方法还可以包括在反应器内提供钝化的催化剂，并将催化剂暴露于还原气氛，同时将催化剂保持在低于210℃的温度。 提供了氢解催化剂制备方法，其可以包括将催化剂暴露于第一还原气氛，同时将催化剂保持在第一温度以减少至少一部分催化剂。 该方法还可以包括钝化至少一部分催化剂，并且在第二还原气氛存在的情况下使催化剂的一部分钝化，同时保持催化剂的部分在低于第一温度的第二温度。

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