Abstract:
Die vorliegende Erfindung betrifft neue Tetramethylcyclopropancarbonsäureester, Verfahren zu ihrer Herstellung, ihre Verwendung als Pflanzenschutzmittel, insbesondere als Insektizide und Akarizide sowie neue Zwischenprodukte zu ihrer Herstellung und Verfahren zu deren Herstellung. Die neuen Tetramethylcyclopropancarbonsäureester besitzen die Formel in welcher R für Mercapto, Methylthio, Alkylsulfinyl oder Alkylsulfonyl steht.
Abstract:
The present invention relates to the novel substituted aza(cyclo)alkanes of the general formula (I) in which R represents a five- or six-membered heterocyclic group which contains 1, 2, 3 or 4 nitrogen atoms and/or one or two oxygen or sulphur atoms as hetero atom ring members, the number of hetero atoms being 1, 2, 3 or 4, and which is optionally substituted by halogen, cyano, nitro, alkyl, haloalkyl, alkenyl, haloalkenyl, alkynyl, alkoxy, haloalkoxy, alkenyloxy, haloalkenyloxy, alkynyloxy, alkylthio, haloalkylthio, alkenylthio, haloalkenylthio, alkynylthio, alkylsulphinyl, haloalkylsulphinyl, alkylsulphonyl, haloalkylsulphonyl, amino, alkylamino, dialkylamino, aryl, arylthio, arylamino, aralkyl, formylamino, alkylcarbonylamino, formyl, carbamoyl, alkylcarbonyl and/or alkoxycarbonyl, R represents hydroxyalkyl, polyhydroxyalkyl, alkoxyalkyl or polyalkoxyalkyl, R represents hydrogen, alkyl, hydroxyalkyl, dihydroxyalkyl, alkoxyalkyl or dialkoxyalkyl, R and R together represent hydroxyalkanediyl, dihydroxyalkanediyl, alkoxyalkanediyl, dialkoxyalkanediyl, oxoalkanediyl or dioxoalkanediyl, R represents hydrogen, alkyl (which is optionally substituted by halogen, cyano, alkoxy, alkylthio, dialkylamino, trialkylsilyl, alkoxycarbonyl, carboxyl, carbamoyl, alkylaminocarbonyl, dialkylaminocarbonyl or by the radical R , R having the abovementioned meaning) or represents alkenyl (which is optionally substituted by halogen), alkynyl, benzyl (which is optionally substituted by halogen, cyano, nitro, alkyl, haloalkyl, alkoxy or alkoxycarbonyl), formyl, alkylcarbonyl (which is optionally substituted by halogen, cyano, phenyl, phenoxy or alkoxy), cycloalkylcarbonyl (which is optionally substituted by halogen and/or alkyl), alkenylcarbonyl (which is optionally substituted by halogen), phenylcarbonyl or naphthylcarbonyl (which are optionally substituted by halogen, alkyl, haloalkyl, cyano, nitro, alkoxy and/or alkoxycarbonyl), alkoxycarbonyl, benzyloxycarbonyl, phenoxycarbonyl, alkylthiocarbonyl, benzylthiocarbonyl, phenylthiocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, phenylaminocarbonyl (which is optionally substituted by halogen, cyano, nitro, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, haloalkylthio or alkoxycarbonyl), benzoylaminocarbonyl (which is optionally substituted by halogen, alkyl or haloalkyl), phenylsulphonylaminocarbonyl (which is optionally substituted by halogen, alkyl, haloalkyl, alkoxy, haloalkoxy or alkoxycarbonyl), alkylthio (which is optionally substituted by halogen), phenylthio (which is optionally substituted by halogen, nitro or alkyl), alkylsulphinyl, alkylsulphonyl (which is optionally substituted by halogen), phenylsulphinyl (which is optionally substituted by halogen, nitro or alkyl), phenylsulphonyl or naphthylsulphonyl (which are optionally substituted by halogen, cyano, nitro, alkyl, haloalkyl, alkoxy, haloalkoxy and/or alkoxycarbonyl), dialkyl(thio)phosphoryl, alkylalkoxy(thio)phosphoryl or dialkoxy(thio)phosphoryl, Y represents nitrogen or a CH group and Z represents cyano or nitro, to processes for their preparation and to their use as pesticides.
Abstract:
Novel 3-hydroxy-4-aryl-5-oxopyrazoline derivatives of the formula (I) are provided, in which A and B are identical or different and independently of one another in each case represent hydrogen, alkyl, alkenyl, alkynyl, alkoxyalkyl, alkylthioalkyl, cycloalkyl or optionally substituted aryl, or A and B together represent the bivalent radical of a saturated or unsaturated and optionally substituted mono-, bi-, tri- or polycyclic system, X represents alkyl, halogen or alkoxy, Y represents hydrogen, alkyl, halogen, alkoxy or haloalkyl, Z represents alkyl, halogen or alkoxy, n represents a number 0, 1, 2 or 3, G represents hydrogen (a) or the groups -CO-R (b), -SO2-R (d), or E (g), in which E represents a metal ion equivalent or an ammonium ion, L and M represent oxygen and/or sulphur, and R , R , R , R , R , R and R are as defined in the text of the application. The novel 3-hydroxy-4-aryl-5-oxopyrazoline derivatives of the formula (I) have a particularly pronounced activity against animal pests, in particular against insects and arachnids, and against weeds.
Abstract:
There are provided novel substituted pyridazinones of the general formula (I) in which R is alkyl, haloalkyl, alkoxyalkyl, alkylthioalkyl, (di)alkylaminoalkyl, alkenyl, haloalkenyl, in each case optionally substituted cycloalkyl, cycloalkylalkyl, aryl or aralkyl, R is halogen or alkyl, R and R independently of one another in each case represent hydrogen or alkyl, R and R are hydrogen, carboxyl, in each case optionally substituted straight-chain or branched alkyl, alkenyl, alkoxycarbonyl, aryl, aralkyl, or together with the carbon atom to which they are bonded an optionally substituted saturated or unsaturated carbocycle, R , R , R , R and R independently of one another in each case represent hydrogen, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio or haloalkylthio and X is oxygen or sulphur. The novel compounds of the formula (I) have a highly pronounced activity against pests, in particular a good insecticidal, acaricidal and ovicidal activity.
Abstract:
The present invention relates to the novel substituted aza(cyclo)alkanes of the general formula (I) in which R represents a five- or six-membered heterocyclic group which contains 1, 2, 3 or 4 nitrogen atoms and/or one or two oxygen or sulphur atoms as hetero atom ring members, the number of hetero atoms being 1, 2, 3 or 4, and which is optionally substituted by halogen, cyano, nitro, alkyl, haloalkyl, alkenyl, haloalkenyl, alkynyl, alkoxy, haloalkoxy, alkenyloxy, haloalkenyloxy, alkynyloxy, alkylthio, haloalkylthio, alkenylthio, haloalkenylthio, alkynylthio, alkylsulphinyl, haloalkylsulphinyl, alkylsulphonyl, haloalkylsulphonyl, amino, alkylamino, dialkylamino, aryl, arylthio, arylamino, aralkyl, formylamino, alkylcarbonylamino, formyl, carbamoyl, alkylcarbonyl and/or alkoxycarbonyl, R represents hydroxyalkyl, polyhydroxyalkyl, alkoxyalkyl or polyalkoxyalkyl, R represents hydrogen, alkyl, hydroxyalkyl, dihydroxyalkyl, alkoxyalkyl or dialkoxyalkyl, R and R together represent hydroxyalkanediyl, dihydroxyalkanediyl, alkoxyalkanediyl, dialkoxyalkanediyl, oxoalkanediyl or dioxoalkanediyl, R represents hydrogen, alkyl (which is optionally substituted by halogen, cyano, alkoxy, alkylthio, dialkylamino, trialkylsilyl, alkoxycarbonyl, carboxyl, carbamoyl, alkylaminocarbonyl, dialkylaminocarbonyl or by the radical R , R having the abovementioned meaning) or represents alkenyl (which is optionally substituted by halogen), alkynyl, benzyl (which is optionally substituted by halogen, cyano, nitro, alkyl, haloalkyl, alkoxy or alkoxycarbonyl), formyl, alkylcarbonyl (which is optionally substituted by halogen, cyano, phenyl, phenoxy or alkoxy), cycloalkylcarbonyl (which is optionally substituted by halogen and/or alkyl), alkenylcarbonyl (which is optionally substituted by halogen), phenylcarbonyl or naphthylcarbonyl (which are optionally substituted by halogen, alkyl, haloalkyl, cyano, nitro, alkoxy and/or alkoxycarbonyl), alkoxycarbonyl, benzyloxycarbonyl, phenoxycarbonyl, alkylthiocarbonyl, benzylthiocarbonyl, phenylthiocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, phenylaminocarbonyl (which is optionally substituted by halogen, cyano, nitro, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, haloalkylthio or alkoxycarbonyl), benzoylaminocarbonyl (which is optionally substituted by halogen, alkyl or haloalkyl), phenylsulphonylaminocarbonyl (which is optionally substituted by halogen, alkyl, haloalkyl, alkoxy, haloalkoxy or alkoxycarbonyl), alkylthio (which is optionally substituted by halogen), phenylthio (which is optionally substituted by halogen, nitro or alkyl), alkylsulphinyl, alkylsulphonyl (which is optionally substituted by halogen), phenylsulphinyl (which is optionally substituted by halogen, nitro or alkyl), phenylsulphonyl or naphthylsulphonyl (which are optionally substituted by halogen, cyano, nitro, alkyl, haloalkyl, alkoxy, haloalkoxy and/or alkoxycarbonyl), dialkyl(thio)phosphoryl, alkylalkoxy(thio)phosphoryl or dialkoxy(thio)phosphoryl, Y represents nitrogen or a CH group and Z represents cyano or nitro, to processes for their preparation and to their use as pesticides.
Abstract:
There are described novel 3-aryl-pyrrolidine-2,4-dione derivatives of the formula (I) in which A-B represents -S-CH2-, -SO-CH2-, -SO2CH2-, -CH2-S-, -CH2SO-, -CH2SO2-, -S-, -SO- or -SO2-, X represents alkyl, halogen or alkoxy, Y represents hydrogen, alkyl, halogen, alkoxy or haloalkyl, Z represents alkyl, halogen or alkoxy, n represents a number from 0-3, R represents hydrogen or the groups -CO-R or -CO-O-R , where E represents a metal cation equivalent or an ammonium ion, R represents optionally halogen-substituted alkyl, alkenyl, alkoxyalkyl, alkylthioalkyl, polyalkoxyalkyl and optionally substituted cycloalkyl which can be interrupted by hetero atoms, or represents optionally substituted phenyl, optionally substituted phenylalkyl, substituted hetaryl, substituted phenoxyalkyl and substituted hetaryloxyalkyl, and R represents optionally halogen-substituted alkyl, cycloalkyl, alkenyl, alkoxyalkyl, polyalkoxyalkyl and optionally substituted phenyl, and several processes for their preparation. The novel compounds of the formula (I) can be used for controlling insects and arachnids and as weedkillers.
Abstract:
The invention relates to new O-halocyclobutyl S-alkyl (di)thiophosphonic(phosphoric) acid esters of the formula (I) … … in which X stands for oxygen or sulphur, p stands for zero, one or two, m stands for zero, one or two, n stands for 2, 3 or 4, R stands for alkyl, for alkoxy which is optionally interrupted by oxygen or sulphur and which can be substituted by halogen, alkenyloxy, alkynyloxy, for heterocyclylalkoxy or for cycloalkoxy which is optionally substituted by alkyl and/or halogen, which can be used as pesticides.
Abstract:
The present invention relates to a method and agent for controlling fleas on and in the surroundings of domestic animals, which is characterised in that the domestic animals are treated with collars which contain active substances which inhibit the development of insects.