公开(公告)号：WO2014048861A1

公开(公告)日：2014-04-03

申请号：PCT/EP2013/069653

申请日：2013-09-23

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： MIGNOGNA, Alessandro ,  BALBONI, Davide ,  CRISTOFORI, Antonio ,  MORINI, Giampiero

IPC: C08F10/06 ,  C08F4/651 ,  C08F4/654

CPC classification number: C08F110/06 ,  C08F10/06 ,  C08F4/651 ,  C08F4/6543 ,  C08F2500/12

Abstract: Catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor of formula (I), where R1 and R2, independently, are selected from hydrogen and C 1 -C 15 hydrocarbon groups, optionally contain an heteroatom selected from halogen, P, S, N, O and Si, which can be fused together to form one or more closed cycles and A is a bivalent bridging group.

Abstract translation: 包含Mg，Ti和式（I）的电子给体的烯烃聚合的催化剂组分，其中R 1和R 2独立地选自氢和C 1 -C 15烃基，任选地含有选自卤素，P，S ，N，O和Si，其可以一起熔合形成一个或多个闭合循环，A是二价桥连基团。

公开(公告)号：WO2012017038A1

公开(公告)日：2012-02-09

申请号：PCT/EP2011/063447

申请日：2011-08-04

Applicant: BASELL POLIOLEFINE ITALIA S.R.L. ,  MIGNOGNA, Alessandro ,  BALBONI, Davide ,  CRISTOFORI, Antonio ,  GUIDOTTI, Simona ,  MORINI, Giampiero ,  PATER, Jochem T. M.

Inventor： MIGNOGNA, Alessandro ,  BALBONI, Davide ,  CRISTOFORI, Antonio ,  GUIDOTTI, Simona ,  MORINI, Giampiero ,  PATER, Jochem T. M.

IPC: C08F10/06 ,  C08F4/651 ,  C08F4/646

CPC classification number: C08F10/06 ,  C08F110/06 ,  C08F4/651 ,  C08F2500/12 ,  C08F2500/15 ,  C08F4/6545

Abstract: Catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor of Formula (I) in which R, R 1 and R 4 groups, equal to or different from each other, are C 1 -C 15 hydrocarbon groups and the R groups can be linked to form a cycle, R 2 -R 3 groups, equal to or different from each other, are selected from hydrogen and C 1 -C 15 hydrocarbon groups, the R 1 -R 4 groups can optionally contain an heteroatom selected from halogen, P, S, N,O and Si, n is an integer from 0 to 5 and said electron donor and Ti atoms being present in an amount such that their molar ratio is equal to, or lower than, 0.65.

Abstract translation: 包含Mg，Ti和其中R，R 1和R 4基团彼此相同或不同的R，R 1和R 4基团的式（I）的电子给体的烯烃聚合用催化剂组分是C1-C15烃基，R基团可以连接 为了形成一个循环，相同或不同的R2-R3基团选自氢和C1-C15烃基，R1-R4基团可任选地含有选自卤素，P，S，N，O的杂原子 和Si，n为0至5的整数，并且所述电子给体和Ti原子的存在量使得它们的摩尔比等于或低于0.65。

公开(公告)号：WO2012175425A1

公开(公告)日：2012-12-27

申请号：PCT/EP2012/061466

申请日：2012-06-15

Applicant: BASELL POLIOLEFINE ITALIA S.R.L. ,  MIGNOGNA, Alessandro ,  BALBONI, Davide ,  CRISTOFORI, Antonio ,  GUIDOTTI, Simona ,  MORINI, Giampiero ,  PATER, Joachim, T. M.

Inventor： MIGNOGNA, Alessandro ,  BALBONI, Davide ,  CRISTOFORI, Antonio ,  GUIDOTTI, Simona ,  MORINI, Giampiero ,  PATER, Joachim, T. M.

IPC: C08F10/00 ,  C08F4/651

CPC classification number: C08F4/50 ,  C08F4/16 ,  C08F10/00 ,  C08F110/06 ,  C08F4/651 ,  C08F2500/12 ,  C08F4/6541

Abstract: Catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor compound of the following formula (I) In which R 1 to R 4 groups, equal to or different from each other, are hydrogen, C 1 -C 15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, P, S, N and S i ,, R 6 group is selected from C 1 -C 15 hydrocarbon groups optionally containing an heteroatom selected from halogen, P, S, N and Si, and R 5 is selected from phenyl groups mono or poly substituted with halogens, said groups R 1 -R 4 being also optionally linked to form a saturated or unsaturated mono or poly cycle.

Abstract translation: 包含Mg，Ti和下式（I）的电子给体化合物的烯烃聚合的催化剂组分，其中相同或不同的R 1至R 4基团为氢，任选地含有 选自卤素，P，S，N和Si，R 6基团的杂原子选自任选含有选自卤素，P，S，N和Si的杂原子的C 1 -C 15烃基，R 5选自苯基单或多 被卤素取代，所述基团R 1 -R 4也任选地连接形成饱和或不饱和的单或多环。

公开(公告)号：WO2012017040A1

公开(公告)日：2012-02-09

申请号：PCT/EP2011/063450

申请日：2011-08-04

Applicant: BASELL POLIOLEFINE ITALIA S.R.L. ,  MORINI, Giampiero ,  BALBONI, Davide ,  CRISTOFORI, Antonio ,  GUIDOTTI, Simona ,  MIGNOGNA, Alessandro ,  Pater, Jochem, T., M.

Inventor： MORINI, Giampiero ,  BALBONI, Davide ,  CRISTOFORI, Antonio ,  GUIDOTTI, Simona ,  MIGNOGNA, Alessandro ,  Pater, Jochem, T., M.

IPC: C08F10/06 ,  C08F4/651 ,  C08F4/646 ,  C08F4/654

CPC classification number: C08F4/6494 ,  C08F10/06 ,  C08F4/6465 ,  C08F4/651 ,  C08F4/6543

Abstract: A catalyst component for the polymerization of olefins comprising Mg, Ti and at least two electron donor compounds, one of which (A) belonging to specific diolesters and the other electron donor compound (B) being selected from aromatic monoesters of the following formula (B) in which R groups equal to or different from each other, are selected from C 1 -C 15 hydrocarbon groups which can be also linked to form one or more cycles, m is an integer from 1 to 5 and R 5 is a C 1 -C 15 alkyl group, said electron donors A and B being in amounts such that the A/B molar ratio is lower than 20.

Abstract translation: 一种用于烯烃聚合的催化剂组分，包括Mg，Ti和至少两种电子给体化合物，其中一种（A）属于特定二极体，另一种电子给体化合物（B）选自下式的芳族单酯（B ）其中R基彼此相同或不同，选自可以连接形成一个或多个周期的C 1 -C 15烃基，m是1至5的整数，R 5是C 1 -C 15烷基 所述电子给体A和B的量使得A / B摩尔比低于20。

公开(公告)号：WO2009115402A1

公开(公告)日：2009-09-24

申请号：PCT/EP2009/052364

申请日：2009-02-27

Applicant: BASELL POLIOLEFINE ITALIA S.R.L. ,  RESCONI, Luigi ,  BALBONI, Davide ,  ESPOSITO, Simona

Inventor： RESCONI, Luigi ,  BALBONI, Davide ,  ESPOSITO, Simona

IPC: C08F210/08 ,  C08F210/14 ,  C08F210/16

CPC classification number: C08F210/16 ,  C08F4/65912 ,  C08F210/08 ,  C08F210/14 ,  C08F2420/05 ,  C08F4/65927 ,  C08F2500/15 ,  C08F2500/17 ,  C08F2500/20

Abstract: A terpolymer of 1-butene, ethylene and a at least a C 8 -C 12 alpha-olefin derived units, containing from 0.1 % to 5 % by mole of ethylene derived units and from 1 from 20% by mol of C 8 -C 12 alpha-olefin derived units, endowed with the following properties : i) isotactic pentad mmmm higher than or equal to 90%; pentads (mmrr+mrrm) lower than 4 and pentad rmmr not detectable by 13 C NMR. ii) intrinsic viscosity (IV) measured in tetrahydronaphthalene at 135°C comprised between 0.8 and 5.0 dL/g; iii) the melting point measured by DSC (TmI) and the C 8 -C 12 alpha-olefin content fulfil the following relationship: TmI -0.3 wherein C is the molar content of C 8 -C 12 alpha-olefin derived units and TmI is the highest melting peak in the first melting transition measured by DSC otherwise the melting point TmI is not detectable.

Abstract translation: 1-丁烯，乙烯和至少一种C 8 -C 12α-烯烃衍生单元的三元共聚物，其含有0.1％至5％（摩尔）的乙烯衍生单元，和1％为20％（摩尔）的C 8 -C 12α-烯烃 具有以下性质：i）等于或等于90％的全同立构五单元mmmm; 低于4的五元组（mmrr + mrrm）和13C NMR不能检测到的五元组。 ii）在135℃的四氢化萘中测得的特性粘度（Ⅳ）为0.8至5.0dL / g; iii）通过DSC（TmI）和C8-C12α-烯烃含量测量的熔点满足以下关系：TmI -0.3其中C是C8-C12α-烯烃衍生单元的摩尔含量，TmI是最高的熔融峰 在通过DSC测量的第一熔融转变中，不能检测到熔点Tm1。

公开(公告)号：WO2010009955A1

公开(公告)日：2010-01-28

申请号：PCT/EP2009/058108

申请日：2009-06-29

Applicant: BASELL POLIOLEFINE ITALIA S.R.L. ,  RESCONI, Luigi ,  BALBONI, Davide ,  MOSCARDI, Gilberto ,  ESPOSITO, Simona

Inventor： RESCONI, Luigi ,  BALBONI, Davide ,  MOSCARDI, Gilberto ,  ESPOSITO, Simona

IPC: C08F210/08 ,  C08F4/6592

CPC classification number: C08F210/08 ,  C08F4/65912 ,  C08F4/65927 ,  C08F2420/05 ,  C08F210/14 ,  C08F2500/15 ,  C08F2500/17 ,  C08F2500/20

Abstract: A crosslinked copolymer of 1-butene and 1-octene or 1-decene; containing from 3.0% to 20.0% by mole of 1-octene or 1-decene derived units;

Abstract translation: 1-丁烯和1-辛烯或1-癸烯的交联共聚物; 含有3.0％至20.0％摩尔的1-辛烯或1-癸烯衍生的单元;

公开(公告)号：EP2723780A1

公开(公告)日：2014-04-30

申请号：EP12728505.4

申请日：2012-06-15

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： MIGNOGNA, Alessandro ,  BALBONI, Davide ,  CRISTOFORI, Antonio ,  GUIDOTTI, Simona ,  MORINI, Giampiero ,  PATER, Joachim, T. M.

IPC: C08F10/00 ,  C08F4/651

CPC classification number: C08F4/50 ,  C08F4/16 ,  C08F10/00 ,  C08F110/06 ,  C08F4/651 ,  C08F2500/12 ,  C08F4/6541

Abstract: Catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor compound of the following formula (I) In which R
1 to R
4 groups, equal to or different from each other, are hydrogen, C
1 -C
15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, P, S, N and S
i ,, R
6 group is selected from C
1 -C
15 hydrocarbon groups optionally containing an heteroatom selected from halogen, P, S, N and Si, and R
5 is selected from phenyl groups mono or poly substituted with halogens, said groups R
1 -R
4 being also optionally linked to form a saturated or unsaturated mono or poly cycle.

公开(公告)号：EP2254946A1

公开(公告)日：2010-12-01

申请号：EP09721344.1

申请日：2009-02-26

Applicant: Basell Poliolefine Italia S.R.L.

Inventor： RESCONI, Luigi ,  BALBONI, Davide

IPC: C08L23/20

CPC classification number: C08L23/20 ,  C08L2205/02 ,  C08L2666/06

Abstract: A 1-butene polymer composition comprising: a) from 10% to 90% by weight of an isotactic 1-butene polymer having the following features: i) isotactic pentad (mmmm) measured by
13 C-NMR, higher than 90%; ii) melting point (TmII) higher than 90°C; and iii) intrinsic viscosity (IV) measured in tetrahydronaphthalene (THN) at 135°C comprised between 0.5 dl/g and 5.0 dl/g. b) from 90% to 10% by weight of a copolymer of 1-butene and at least a C
8 -C
12 alpha- olefin derived units, containing from 0% to 10% by mole of propylene or pentene derived units, and/or containing from 0% to 5% by mole of ethylene derived units having a content of C
8 -C
12 alpha-olefin derived units higher than 4.0% by mol and lower than 20.0% by mol; endowed with the following features: i) isotactic pentad mmmm higher than or equal to 90 %; pentads (mmrr+mrrm) lower than 4 and pentad rmmr not detectable by C NMR. ii) intrinsic viscosity (IV) measured in tetrahydronaphthalene at 135°C comprised between 0.8 and 5.0 dL/g; iii) the melting point measured by DSC (TmI) and the C
8 -C
12 alpha-olefin content fulfil the following relationship: TmI -0.3 wherein C is the molar content of C
8 -C
12 alpha-olefin derived units and TmI is the highest melting peak in the first melting transition; otherwise the melting point TmI is not detectable;

公开(公告)号：EP2601223A1

公开(公告)日：2013-06-12

申请号：EP11739079.9

申请日：2011-08-04

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： MIGNOGNA, Alessandro ,  BALBONI, Davide ,  CRISTOFORI, Antonio ,  GUIDOTTI, Simona ,  MORINI, Giampiero ,  PATER, Jochem T. M.

IPC: C08F10/06 ,  C08F4/651 ,  C08F4/646

CPC classification number: C08F10/06 ,  C08F110/06 ,  C08F4/651 ,  C08F2500/12 ,  C08F2500/15 ,  C08F4/6545

Abstract: Catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor of Formula (I) in which R, R1 and R4 groups, equal to or different from each other, are C1-C15 hydrocarbon groups and the R groups can be linked to form a cycle, R2-R3 groups, equal to or different from each other, are selected from hydrogen and C1-C15 hydrocarbon groups, the R1-R4 groups can optionally contain an heteroatom selected from halogen, P, S, N, O and Si, n is an integer from 0 to 5 and said electron donor and Ti atoms being present in an amount such that their molar ratio is equal to, or lower than, 0.65.

公开(公告)号：EP2254946B1

公开(公告)日：2012-02-01

申请号：EP09721344.1

申请日：2009-02-26

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： RESCONI, Luigi ,  BALBONI, Davide

IPC: C08L23/20

CPC classification number: C08L23/20 ,  C08L2205/02 ,  C08L2666/06

Abstract: A 1-butene polymer composition comprising: a) from 10% to 90% by weight of an isotactic 1-butene polymer having the following features: i) isotactic pentad (mmmm) measured by
13 C-NMR, higher than 90%; ii) melting point (TmII) higher than 90°C; and iii) intrinsic viscosity (IV) measured in tetrahydronaphthalene (THN) at 135°C comprised between 0.5 dl/g and 5.0 dl/g. b) from 90% to 10% by weight of a copolymer of 1-butene and at least a C
8 -C
12 alpha- olefin derived units, containing from 0% to 10% by mole of propylene or pentene derived units, and/or containing from 0% to 5% by mole of ethylene derived units having a content of C
8 -C
12 alpha-olefin derived units higher than 4.0% by mol and lower than 20.0% by mol; endowed with the following features: i) isotactic pentad mmmm higher than or equal to 90 %; pentads (mmrr+mrrm) lower than 4 and pentad rmmr not detectable by C NMR. ii) intrinsic viscosity (IV) measured in tetrahydronaphthalene at 135°C comprised between 0.8 and 5.0 dL/g; iii) the melting point measured by DSC (TmI) and the C
8 -C
12 alpha-olefin content fulfil the following relationship: TmI -0.3 wherein C is the molar content of C
8 -C
12 alpha-olefin derived units and TmI is the highest melting peak in the first melting transition; otherwise the melting point TmI is not detectable;