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    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS
    1.
    发明申请
    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开

    公开(公告)号：WO2021001232A1

    公开(公告)日：2021-01-07

    申请号：PCT/EP2020/067640

    申请日：2020-06-24

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

    Inventor： MIGNOGNA, Alessandro ,  LIGUORI, Dario ,  MORINI, Giampiero

    IPC: C08F4/651 ,  C08F110/06 ,  C08F4/654

    Abstract: A solid catalyst component for the polymerization of olefins comprising Mg, Ti and a an electron donor of formula (I) where the R 1 and R 5 groups, equal to or different from each other, are selected from C 1 -C 15 hydrocarbon groups, R 2 group is selected from C 2 -C 10 hydrocarbon groups, R 3 to R 4 groups, independently, are selected from hydrogen or C 1 -C 20 hydrocarbon groups, optionally fused together to form one or more cycles, with the proviso that at least one of R 3 to R 4 groups is a C 1 -C 20 alkyl group. The catalyst system based on the solid catalyst component is endowed with high activity and stereospecificity.

    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS
    2.
    发明申请
    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
    用于烯烃聚合的催化组分

    公开(公告)号：WO2015032939A1

    公开(公告)日：2015-03-12

    申请号：PCT/EP2014/069056

    申请日：2014-09-08

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

    Inventor： MIGNOGNA, Alessandro ,  CHEVALIER, Reynald ,  MORINI, Giampiero ,  SCHNEIDER, Martin

    IPC: C08F4/651 ,  C08F110/06 ,  C07C271/12 ,  C08F4/654

    CPC classification number: C08F110/06 ,  C07C271/12 ,  C08F4/651 ,  C08F2500/12

    Abstract: A solid catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor of formula (I), where R 1 is selected from C 1 -C 15 hydrocarbon groups, R 2 groups, equal to or different from each other, are hydrogen or R 1 groups which can be fused together to form one or more cycles and A is a bivalent bridging group. The said catalyst components exhibit high activity and stereo specificity in the polymerization of olefins.

    Abstract translation: 包含Mg，Ti和式（I）的电子给体的烯烃聚合的固体催化剂组分为氢或R 1基团，其中R 1选自C 1 -C 15烃基，R 2基团彼此相同或不同 其可以融合在一起以形成一个或多个循环，并且A是二价桥连基团。 所述催化剂组分在烯烃聚合中表现出高活性和立体特异性。

    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS
    3.
    发明申请
    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
    用于烯烃聚合的催化剂组分

    公开(公告)号：WO2013131912A2

    公开(公告)日：2013-09-12

    申请号：PCT/EP2013/054399

    申请日：2013-03-05

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

    Inventor： MIGNOGNA, Alessandro ,  GUIDOTTI, Simona ,  MORINI, Giampiero ,  PATER, Joachim T. M.

    CPC classification number: C08F4/6494 ,  C07C69/96 ,  C07C2603/18 ,  C08F4/6543 ,  C08F110/06 ,  C08F4/651 ,  C08F2500/12

    Abstract: Catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor compound of the following formula (I) in which R1 groups are selected from C 1 -C 15 hydrocarbon groups, R 8 groups, equal or different to each other, are selected from hydrogen, halogen and C 1 -C 15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, O, P, S, N and Si and L is a divalent hydrocarbon group optionally containing heteroatoms selected from halogen, O, P, S, N and Si.

    Abstract translation: 用于烯烃聚合的催化剂组分包含Mg，Ti和下式（I）的电子给体化合物，其中R 1基团选自C 1 -C 4烷基， 15个烃基，R 8基团彼此相同或不同，选自氢，卤素和C 1 -C 15 烃基，任选地含有选自卤素，O，P，S，N和Si的杂原子，并且L是任选地含有选自卤素，O，P，S，N和Si的杂原子的二价烃基。 p>

    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS
    7.
    发明申请
    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
    用于烯烃聚合的催化组分

    公开(公告)号：WO2016156473A1

    公开(公告)日：2016-10-06

    申请号：PCT/EP2016/057031

    申请日：2016-03-31

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

    Inventor： MIGNOGNA, Alessandro ,  KASHULIN, Igor ,  MORINI, Giampiero ,  NIFANT'EV, Ilya

    IPC: C08F110/06 ,  C08F4/651 ,  C08F4/654

    CPC classification number: C08F110/06 ,  C08F4/6455 ,  C08F4/6457 ,  C08F4/649 ,  C08F4/6495 ,  C08F4/6498 ,  C08F4/654 ,  C08F4/655 ,  C08F2410/01 ,  C08F2500/12 ,  C08F2500/15 ,  C08F4/651 ,  C08F4/6543 ,  C08F4/6465

    Abstract: Catalyst component for the polymerization of olefins comprising Mg. Ti and an electron donor belonging to mercaptoester derivatives of specific formula (I) in which Z is selected from C, Si, O, N, S or P with the proviso that the atoms O, S, P and N are not directly linked to either the carboxylic group or the sulphur atom of formula (I), the R 2 groups, equal to or different from each other, are hydrogen or a C 1 -C 20 hydrocarbon radicals, optionally containing a heteroatom selected from halogen, P, S, N,O and Si, which can be fused together to form one or more cycles, m is a number satisfying the valences of Z and n is an integer ranging from 1 to 10, X is O or S, Y is -OR 3 , -NR 4 R 5 ) or R 6 groups in which R 1 and R 3 are selected from C 1 -C 15 hydrocarbon groups, optionally containing a heteroatom selected from halogen, P, S, N,O, and Si, R 4 -R 5 groups, independently, are hydrogen or R 1 groups and R 6 groups have the same meaning as R 1 groups.

    Abstract translation: 包含Mg的烯烃聚合的催化剂组分。 Ti和属于特定式（I）的巯基酯衍生物的电子给体，其中Z选自C，Si，O，N，S或P，条件是原子O，S，P和N不直接连接到 式（I）的羧基或硫原子，相同或不同的R 2基团是氢或C 1 -C 20烃基，任选地含有选自卤素，P，S，N， O和Si，其可以融合在一起形成一个或多个循环，m是满足Z的化合价的数，n是1至10的整数，X是O或S，Y是-OR 3，-NR 4 R 5） 或R6基团，其中R 1和R 3选自C 1 -C 15烃基，任选地含有选自卤素，P，S，N，O和Si的杂原子，R 4 -R 5基团独立地为氢或R 1基团，R 6 组与R1组具有相同的含义。

    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS
    8.
    发明申请
    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
    用于烯烃聚合的催化组分

    公开(公告)号：WO2013182585A1

    公开(公告)日：2013-12-12

    申请号：PCT/EP2013/061546

    申请日：2013-06-05

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

    Inventor： MIGNOGNA, Alessandro ,  GUIDOTTI, Simona ,  KASHULIN, Igor ,  MORINI, Giampiero ,  NIFANT'EV, Ilya ,  PATER, Joachim T. M.

    IPC: C08F4/651 ,  C08F110/06

    CPC classification number: C08F4/52 ,  C08F4/10 ,  C08F4/16 ,  C08F110/08 ,  C08F4/651 ,  C08F2500/15 ,  C08F2500/17 ,  C08F110/06 ,  C08F2500/12

    Abstract: A catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor compound of the following formula (I) in which the R groups equal to or different from each other, are C 1 -C 15 hydrocarbon groups, the R 1 -R 2 groups, equal to or different from each other, are hydrogen, halogen or C 1 -C 15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, P, S, N and Si, which can be fused together to form one or more cycles; n and m are integer from 0 to 3 with the proviso that at least one of them is different from 0 and that diisobutyl o-phenylenediacetate is excluded.

    Abstract translation: 包含Mg，Ti和其中R基彼此相同或不同的下式（I）的电子给体化合物的烯烃聚合催化剂组分是C 1 -C 15烃基，R 1 -R 2基， 相同或不同的是氢，卤素或C 1 -C 15烃基，任选地含有选自卤素，P，S，N和Si的杂原子，其可以一起稠合形成一个或多个循环; n和m是0-3的整数，条件是它们中的至少一个不同于0，并且排除邻苯二乙酸二异丁酯。

    CATALYST COMPONENTS FOR THE POLYMERIZATION OF BUTENE-1
    9.
    发明申请
    CATALYST COMPONENTS FOR THE POLYMERIZATION OF BUTENE-1 审中-公开
    催化剂组分对于BUTENE-1的聚合

    公开(公告)号：WO2013182474A1

    公开(公告)日：2013-12-12

    申请号：PCT/EP2013/061158

    申请日：2013-05-30

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

    Inventor： MIGNOGNA, Alessandro ,  ESPOSITO, Simona ,  GUIDOTTI, Simona ,  MORINI, Giampiero ,  PATER, Joachim T. M. ,  PIEMONTESI, Fabrizio ,  VITALE, Gianni

    IPC: C08F110/08 ,  C08F4/651

    CPC classification number: C08F4/52 ,  C08F4/10 ,  C08F4/16 ,  C08F110/08 ,  C08F4/651 ,  C08F2500/15 ,  C08F2500/17 ,  C08F110/06 ,  C08F2500/12

    Abstract: Process for the polymerization of butene-1 carried out in the presence of a catalyst comprising (a) a solid catalyst component comprising Mg, Ti and an electron donor compound of the following formula (I), In which the R groups equal to or different from each other, are C 1 -C 15 hydrocarbon groups, the R 1 -R 2 groups, equal to or different from each other, are hydrogen, halogen or C 1 -C 15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, P, S, N and Si, n and m are integer from 0 to 3 with the proviso that at least one of them is different from 0; (b) An aluminium alkyl cocatalyst and (c) an external electron donor

    Abstract translation: 在催化剂存在下进行的丁烯-1的聚合方法，包括（a）包含Mg，Ti和下式（I）的电子给体化合物的固体催化剂组分，其中R基团等于或不同 彼此相同的是C 1 -C 15烃基，R 1 -R 2基彼此相同或不同，是氢，卤素或C 1 -C 15烃基，任选地含有选自卤素，P，S，N的杂原子和 Si，n和m为0-3的整数，条件是它们中的至少一个不同于0; （b）烷基铝助催化剂和（c）外电子给体

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