公开(公告)号：WO2004086539B1

公开(公告)日：2004-12-29

申请号：PCT/JP2004004071

申请日：2004-03-24

Applicant: CANON KK ,  KAWAKAMI SOICHIRO ,  ASAO MASAYA ,  SUZUKI NOBUYUKI ,  YAMADA YASUHIRO ,  OGURA TAKAO

Inventor： KAWAKAMI SOICHIRO ,  ASAO MASAYA ,  SUZUKI NOBUYUKI ,  YAMADA YASUHIRO ,  OGURA TAKAO

IPC: H01M4/38 ,  H01M10/052 ,  H01M10/36 ,  H01M4/02 ,  H01M10/40

CPC classification number: H01M10/052 ,  H01M4/386 ,  Y02T10/7011

Abstract: The electrode material for a lithium secondary battery according to the present invention includes particles of a solid state alloy having silicon as a main component, wherein the particles of the solid state alloy have a microcrystal or amorphous material including an element other than silicon, dispersed in microcrystalline silicon or amorphized silicon. The solid state alloy preferably contains a pure metal or a solid solution. The composition of the alloy preferably has an element composition in which the alloy is completely mixed in a melted liquid state, whereby the alloy has a single phase in a melted liquid state without pressure of two or more phases. The element composition can be determined by the kind of elements constituting the alloy and an atomic ratio of the elements.

公开(公告)号：US5728482B1

公开(公告)日：1999-11-09

申请号：US77080296

申请日：1996-12-20

Applicant: CANON KK

Inventor： KAWAKAMI SOICHIRO ,  KOBAYASHI NAOYA ,  ASAO MASAYA

IPC: H01M10/05 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/24 ,  H01M10/42 ,  H01M4/62

CPC classification number: H01M10/42 ,  H01M10/05 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/24 ,  Y10T29/49108

公开(公告)号：EP2227510A4

公开(公告)日：2014-03-05

申请号：EP08867699

申请日：2008-12-25

Applicant: CANON KK

Inventor： ASAO MASAYA ,  NAKAJIMA KENJI ,  SUGAMA SADAYUKI ,  YOSHINO HITOSHI ,  NAGASHIMA AKIRA

IPC: C09D17/00 ,  B41J2/01 ,  B41M5/00 ,  B41M5/50 ,  B41M5/52 ,  C09C1/00 ,  C09C1/40 ,  C09C3/06

CPC classification number: B41M5/5218 ,  B82Y30/00 ,  C01P2002/88 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2006/12 ,  C01P2006/22 ,  C09C1/30 ,  C09C1/3045 ,  C09C1/407

公开(公告)号：EP1039568A4

公开(公告)日：2004-09-01

申请号：EP99943402

申请日：1999-09-17

Applicant: CANON KK

Inventor： KAWAKAMI SOICHIRO ,  ASAO MASAYA

IPC: C22C13/00 ,  C22C45/00 ,  H01M4/134 ,  H01M4/1395 ,  H01M4/38 ,  H01M4/40 ,  H01M4/62 ,  H01M4/66 ,  H01M10/05 ,  H01M10/052 ,  H01M10/058 ,  H01M10/36 ,  H01M4/58 ,  H01M4/02

CPC classification number: H01M4/40 ,  C22C13/00 ,  C22C45/00 ,  H01M4/02 ,  H01M4/0404 ,  H01M4/134 ,  H01M4/1395 ,  H01M4/38 ,  H01M4/386 ,  H01M4/387 ,  H01M4/405 ,  H01M4/66 ,  H01M10/052 ,  H01M2004/021 ,  H01M2004/027

Abstract: An electrode material for a negative pole of a lithium secondary battery containing particles which comprises an amorphous Sn.A.X alloy having a substantially non-stoichiometric composition, wherein A represents at least one element selected from the transition metal elements, X is an optional component and represents at least one element selected from the group consiting of O, F, N, Mg, Ba, Sr, Ca, La, Ce, Si, Ge, C, P, B, Bi, Sb, Al, In, and Zn, and the content of the component Sn [Sn/(Sn+A+X)] is 20 to 80 atomic %. An electrode structure for a lithium secondary cell composed of the aforementioned electrode material for a negative electrode and a collector comprising a material which forms no alloy with lithium in an electrochemical reaction, and a lithium secondary cel having a negative pole comprising the electrode structure.

Abstract translation: 的电极材料上的阳极的可充电锂电池，含有粒状包含无定形的Sn·A·具有基本为非化学计量比组合物X合金。 在式的Sn·A·X中，A表示选自过渡金属元素的铬，锰，铁，钴，镍，铜，钼，锝，钌，铑，钯，银，铱，铂中选择的至少一种元素， 金，钛，钒，钇，钪，锆，铌，铪，钽，和W，X表示从一组选自N，李，S，Pb中O或F之中的至少一种元素和任选的至少一种元素 ，铋，铝，镓，铟，铊，锌，铍，镁，钙，锶，镧，铈，镨，钕，钐，铕，钆，铽，镝，钬，铒，铥，镱，路，B 有C，Si，P，锗，砷，硒，锑，和Te。 的构成元件，在所述的Sn的Sn·A·X合金的含量为Sn /（Sn的+ A + X）= 20〜80原子％。％，在5％的所述合金大小限制元件O和F的量 按重量计每，但至少0.05％重量的元素的0或F存在，任何O或F被主要位于所述合金颗粒的表面上。 的电极结构体用于可再充电锂电池，包括：用于在所述阳极电极材料和集电体，其包括材料不能与在电化学反应锂合金化，并且具有阳极的可充电锂电池，其包括所说的电极结构体。

公开(公告)号：EP1033767A4

公开(公告)日：2004-09-01

申请号：EP99943403

申请日：1999-09-17

Applicant: CANON KK

Inventor： KAWAKAMI SOICHIRO ,  ASAO MASAYA

IPC: C22C45/00 ,  H01M4/134 ,  H01M4/1395 ,  H01M4/38 ,  H01M4/40 ,  H01M4/485 ,  H01M4/66 ,  H01M10/05 ,  H01M10/052 ,  H01M4/58

CPC classification number: H01M4/13 ,  C22C45/00 ,  H01M4/02 ,  H01M4/38 ,  H01M4/386 ,  H01M4/40 ,  H01M4/66 ,  H01M10/0525 ,  H01M2004/027

Abstract: An electrode material for a negative pole of a lithium secondary battery containing particles which comprises and amorphous M•A•X alloy having a substantially non-stoichiometric composition, wherein M represents at least one element selected from the group consisting of Si, Ge, and Mg, A represents at least one element selected from the transition metal elements, X is an optional component and represents at least one element selected from the group consisting of O, F, N, Ba, Sr, Ca, La, Ce, C, P, S, Se, Te, B, Bi, Sb, Al, In, and Zn, and the content of the component M [M/(M+A+X)] is 20 to 80 atomic %. An electrode structure for a lithium secondary cell composed of the aforementioned electrode material for a negative electrode and a collector comprising a material which forms no alloy with lithium in an electrochemical reaction. A lithium secondary cell having a negative pole comprising the electrode structure.

公开(公告)号：EP2227509A4

公开(公告)日：2012-04-18

申请号：EP08866156

申请日：2008-12-25

Applicant: CANON KK

Inventor： NAGASHIMA AKIRA ,  NAKAJIMA KENJI ,  SUGAMA SADAYUKI ,  YOSHINO HITOSHI ,  ASAO MASAYA

IPC: C09C3/06 ,  B41J2/01 ,  B41M5/00 ,  B41M5/382 ,  B41M5/50 ,  B41M5/52 ,  C09C1/00 ,  C09C1/40 ,  C09D7/12 ,  C09D11/00 ,  C09D17/00 ,  D21H17/69 ,  D21H19/00

CPC classification number: B41M5/5218 ,  C01P2002/72 ,  C01P2002/85 ,  C01P2002/88 ,  C01P2004/54 ,  C01P2006/12 ,  C08K3/22 ,  C08K7/24 ,  C08K9/02 ,  C09C1/0081 ,  C09C1/407 ,  C09D7/62 ,  C09D11/322 ,  D21H17/69 ,  D21H21/28 ,  Y10T428/24802 ,  Y10T428/256

Abstract: The invention relates to a surface-modified inorganic pigment which has an inorganic pigment having acid function and an amorphous body located on the surface of the inorganic pigment having acid function and formed by at least a divalent or higher-valent metal and an anion component in a state where the inorganic pigment and the amorphous body do not chemically bond to each other, and which does not exhibit acid function.

公开(公告)号：EP1604415A4

公开(公告)日：2009-01-28

申请号：EP04723041

申请日：2004-03-24

Applicant: CANON KK

Inventor： KAWAKAMI SOICHIRO ,  ASAO MASAYA ,  SUZUKI NOBUYUKI ,  YAMADA YASUHIRO ,  OGURA TAKAO

IPC: H01M4/38 ,  H01M10/052 ,  H01M10/36 ,  H01M4/02 ,  H01M10/40

CPC classification number: H01M10/052 ,  H01M4/386 ,  Y02T10/7011

公开(公告)号：DE69532555T2

公开(公告)日：2005-01-05

申请号：DE69532555

申请日：1995-11-30

Applicant: CANON KK

Inventor： KAWAKAMI SOICHIRO ,  MISHINA SHINYA ,  KOBAYASHI NAOYA ,  ASAO MASAYA

IPC: H01M10/05 ,  H01M4/13 ,  H01M4/139 ,  H01M4/36 ,  H01M4/48 ,  H01M4/66 ,  H01M4/02 ,  H01M4/04 ,  H01M10/40

公开(公告)号：DE69532555D1

公开(公告)日：2004-03-18

申请号：DE69532555

申请日：1995-11-30

Applicant: CANON KK

Inventor： KAWAKAMI SOICHIRO ,  MISHINA SHINYA ,  KOBAYASHI NAOYA ,  ASAO MASAYA

IPC: H01M10/05 ,  H01M4/13 ,  H01M4/139 ,  H01M4/36 ,  H01M4/48 ,  H01M4/66 ,  H01M4/02 ,  H01M4/04 ,  H01M10/40

公开(公告)号：DE69511483D1

公开(公告)日：1999-09-23

申请号：DE69511483

申请日：1995-05-30

Applicant: CANON KK

Inventor： KAWAKAMI SOICHIRO ,  MISHINA SHINYA ,  KOBAYASHI NAOYA ,  ASAO MASAYA

IPC: H01M4/02 ,  H01M4/134 ,  H01M4/24 ,  H01M10/04 ,  H01M10/052 ,  H01M10/24 ,  H01M10/36 ,  H01M12/08 ,  H01M10/40

Abstract: A highly reliable rechargeable battery comprising an anode, a separator, a cathode, an electrolyte or an electrolyte solution, and a housing, characterized in that said anode is structured to have a size which is greater than that of said cathode. The rechargeable battery provides an increased energy density and has a prolonged charging and discharging cycle life, in which a dendrite causing a reduction in the battery performance, which is generated upon operating charging in the conventional rechargeable battery, is effectively prevented from generating or from growing in the case where it should be generated.