公开(公告)号：WO2004086539B1

公开(公告)日：2004-12-29

申请号：PCT/JP2004004071

申请日：2004-03-24

Applicant: CANON KK ,  KAWAKAMI SOICHIRO ,  ASAO MASAYA ,  SUZUKI NOBUYUKI ,  YAMADA YASUHIRO ,  OGURA TAKAO

Inventor： KAWAKAMI SOICHIRO ,  ASAO MASAYA ,  SUZUKI NOBUYUKI ,  YAMADA YASUHIRO ,  OGURA TAKAO

IPC: H01M4/38 ,  H01M10/052 ,  H01M10/36 ,  H01M4/02 ,  H01M10/40

CPC classification number: H01M10/052 ,  H01M4/386 ,  Y02T10/7011

Abstract: The electrode material for a lithium secondary battery according to the present invention includes particles of a solid state alloy having silicon as a main component, wherein the particles of the solid state alloy have a microcrystal or amorphous material including an element other than silicon, dispersed in microcrystalline silicon or amorphized silicon. The solid state alloy preferably contains a pure metal or a solid solution. The composition of the alloy preferably has an element composition in which the alloy is completely mixed in a melted liquid state, whereby the alloy has a single phase in a melted liquid state without pressure of two or more phases. The element composition can be determined by the kind of elements constituting the alloy and an atomic ratio of the elements.

公开(公告)号：US5728482B1

公开(公告)日：1999-11-09

申请号：US77080296

申请日：1996-12-20

Applicant: CANON KK

Inventor： KAWAKAMI SOICHIRO ,  KOBAYASHI NAOYA ,  ASAO MASAYA

IPC: H01M10/05 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/24 ,  H01M10/42 ,  H01M4/62

CPC classification number: H01M10/42 ,  H01M10/05 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/24 ,  Y10T29/49108

公开(公告)号：EP0809314A3

公开(公告)日：1998-10-14

申请号：EP97200434

申请日：1993-11-30

Applicant: CANON KK

Inventor： KAWAKAMI SOICHIRO ,  KOBAYASHI NAOYA

IPC: H01M2/14 ,  H01M2/16 ,  H01M4/02 ,  H01M4/04 ,  H01M4/13 ,  H01M4/131 ,  H01M4/133 ,  H01M4/134 ,  H01M4/139 ,  H01M4/1391 ,  H01M4/24 ,  H01M4/36 ,  H01M4/40 ,  H01M4/42 ,  H01M4/48 ,  H01M4/485 ,  H01M4/50 ,  H01M4/505 ,  H01M4/52 ,  H01M4/525 ,  H01M4/58 ,  H01M4/62 ,  H01M4/74 ,  H01M4/80 ,  H01M10/05 ,  H01M10/052 ,  H01M10/056 ,  H01M10/058 ,  H01M10/0585 ,  H01M10/0587 ,  H01M10/24 ,  H01M10/36 ,  H01M10/40

CPC classification number: H01M10/05 ,  H01M2/14 ,  H01M2/1673 ,  H01M4/02 ,  H01M4/04 ,  H01M4/0402 ,  H01M4/0404 ,  H01M4/0409 ,  H01M4/0414 ,  H01M4/0416 ,  H01M4/0419 ,  H01M4/0421 ,  H01M4/0426 ,  H01M4/0428 ,  H01M4/043 ,  H01M4/0435 ,  H01M4/0438 ,  H01M4/045 ,  H01M4/0452 ,  H01M4/0466 ,  H01M4/0471 ,  H01M4/13 ,  H01M4/131 ,  H01M4/133 ,  H01M4/134 ,  H01M4/139 ,  H01M4/1391 ,  H01M4/24 ,  H01M4/244 ,  H01M4/36 ,  H01M4/366 ,  H01M4/38 ,  H01M4/40 ,  H01M4/42 ,  H01M4/48 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/58 ,  H01M4/581 ,  H01M4/582 ,  H01M4/62 ,  H01M4/621 ,  H01M4/622 ,  H01M4/623 ,  H01M4/625 ,  H01M4/74 ,  H01M4/742 ,  H01M4/808 ,  H01M10/052 ,  H01M10/056 ,  H01M10/058 ,  H01M10/0585 ,  H01M10/0587 ,  H01M10/24 ,  H01M10/30 ,  H01M12/08 ,  H01M2004/027 ,  Y02E60/128 ,  Y10T29/49108

Abstract: A secondary battery exhibiting a long cycle life and comprising a negative pole activating material made of lithium or zinc is provided, the battery at least having a negative pole made of lithium or zinc serving as the negative pole activating material, an electrolyte (electrolytic solution), a separator, a positive pole made of a positive pole activating material, a collecting electrode and a battery case, wherein at least the surface of the negative pole is covered with a film having a structure which allows ions relating to the battery reactions to pass through. Since growth of dendrite of lithium or zinc at the time of the charge can be prevented, short circuit between the negative pole and the positive pole can be prevented. Therefore, the charge/discharge cycle life can significantly be lengthened. As a result, a lithium secondary battery, a nickel-zinc secondary battery, an air-zinc secondary battery, a bromine-zinc secondary battery and a silver oxide-zinc secondary battery of the long cycle life can be manufactured.

公开(公告)号：EP1039568A4

公开(公告)日：2004-09-01

申请号：EP99943402

申请日：1999-09-17

Applicant: CANON KK

Inventor： KAWAKAMI SOICHIRO ,  ASAO MASAYA

IPC: C22C13/00 ,  C22C45/00 ,  H01M4/134 ,  H01M4/1395 ,  H01M4/38 ,  H01M4/40 ,  H01M4/62 ,  H01M4/66 ,  H01M10/05 ,  H01M10/052 ,  H01M10/058 ,  H01M10/36 ,  H01M4/58 ,  H01M4/02

CPC classification number: H01M4/40 ,  C22C13/00 ,  C22C45/00 ,  H01M4/02 ,  H01M4/0404 ,  H01M4/134 ,  H01M4/1395 ,  H01M4/38 ,  H01M4/386 ,  H01M4/387 ,  H01M4/405 ,  H01M4/66 ,  H01M10/052 ,  H01M2004/021 ,  H01M2004/027

Abstract: An electrode material for a negative pole of a lithium secondary battery containing particles which comprises an amorphous Sn.A.X alloy having a substantially non-stoichiometric composition, wherein A represents at least one element selected from the transition metal elements, X is an optional component and represents at least one element selected from the group consiting of O, F, N, Mg, Ba, Sr, Ca, La, Ce, Si, Ge, C, P, B, Bi, Sb, Al, In, and Zn, and the content of the component Sn [Sn/(Sn+A+X)] is 20 to 80 atomic %. An electrode structure for a lithium secondary cell composed of the aforementioned electrode material for a negative electrode and a collector comprising a material which forms no alloy with lithium in an electrochemical reaction, and a lithium secondary cel having a negative pole comprising the electrode structure.

Abstract translation: 的电极材料上的阳极的可充电锂电池，含有粒状包含无定形的Sn·A·具有基本为非化学计量比组合物X合金。 在式的Sn·A·X中，A表示选自过渡金属元素的铬，锰，铁，钴，镍，铜，钼，锝，钌，铑，钯，银，铱，铂中选择的至少一种元素， 金，钛，钒，钇，钪，锆，铌，铪，钽，和W，X表示从一组选自N，李，S，Pb中O或F之中的至少一种元素和任选的至少一种元素 ，铋，铝，镓，铟，铊，锌，铍，镁，钙，锶，镧，铈，镨，钕，钐，铕，钆，铽，镝，钬，铒，铥，镱，路，B 有C，Si，P，锗，砷，硒，锑，和Te。 的构成元件，在所述的Sn的Sn·A·X合金的含量为Sn /（Sn的+ A + X）= 20〜80原子％。％，在5％的所述合金大小限制元件O和F的量 按重量计每，但至少0.05％重量的元素的0或F存在，任何O或F被主要位于所述合金颗粒的表面上。 的电极结构体用于可再充电锂电池，包括：用于在所述阳极电极材料和集电体，其包括材料不能与在电化学反应锂合金化，并且具有阳极的可充电锂电池，其包括所说的电极结构体。

公开(公告)号：EP1033767A4

公开(公告)日：2004-09-01

申请号：EP99943403

申请日：1999-09-17

Applicant: CANON KK

Inventor： KAWAKAMI SOICHIRO ,  ASAO MASAYA

IPC: C22C45/00 ,  H01M4/134 ,  H01M4/1395 ,  H01M4/38 ,  H01M4/40 ,  H01M4/485 ,  H01M4/66 ,  H01M10/05 ,  H01M10/052 ,  H01M4/58

CPC classification number: H01M4/13 ,  C22C45/00 ,  H01M4/02 ,  H01M4/38 ,  H01M4/386 ,  H01M4/40 ,  H01M4/66 ,  H01M10/0525 ,  H01M2004/027

Abstract: An electrode material for a negative pole of a lithium secondary battery containing particles which comprises and amorphous M•A•X alloy having a substantially non-stoichiometric composition, wherein M represents at least one element selected from the group consisting of Si, Ge, and Mg, A represents at least one element selected from the transition metal elements, X is an optional component and represents at least one element selected from the group consisting of O, F, N, Ba, Sr, Ca, La, Ce, C, P, S, Se, Te, B, Bi, Sb, Al, In, and Zn, and the content of the component M [M/(M+A+X)] is 20 to 80 atomic %. An electrode structure for a lithium secondary cell composed of the aforementioned electrode material for a negative electrode and a collector comprising a material which forms no alloy with lithium in an electrochemical reaction. A lithium secondary cell having a negative pole comprising the electrode structure.

公开(公告)号：EP2691424A4

公开(公告)日：2014-10-29

申请号：EP12765581

申请日：2012-03-27

Applicant: CANON KK

Inventor： INOUE KEI ,  MURAI YASUAKI ,  MURAYAMA RYUJI ,  SATO KAZUYUKI ,  KAWAKAMI SOICHIRO ,  HIROSE MASASHI

IPC: C08F12/14 ,  C07C311/29 ,  C08F20/58 ,  C08F20/60 ,  C08F212/14 ,  C08F220/58 ,  C08F220/60 ,  G03G9/087 ,  G03G9/097 ,  G03G15/08

CPC classification number: G03G9/09775 ,  C07C311/28 ,  C07C311/29 ,  C07C311/48 ,  C07C311/49 ,  C07C311/51 ,  C07C311/52 ,  C08F12/22 ,  C08F12/24 ,  C08F12/26 ,  C08F12/30 ,  C08F212/08 ,  C08F212/12 ,  C08F212/14 ,  C08F212/32 ,  C08F220/54 ,  C08F220/58 ,  C08F2220/585 ,  G03G9/08726 ,  G03G9/08728 ,  G03G9/08735 ,  G03G9/08795 ,  G03G9/08797 ,  C08F220/06 ,  C08F2220/1825

公开(公告)号：EP2204867A4

公开(公告)日：2012-06-06

申请号：EP08828936

申请日：2008-09-08

Applicant: CANON KK

Inventor： KAWAKAMI SOICHIRO ,  KAKEGAWA NORISHIGE ,  KASHIWAZAKI AKIO ,  AIBA TOSHIAKI ,  UENO RIE ,  SHIMADA MIKIO ,  OJIMA KAORU ,  NOMA TAKASHI

IPC: H01M4/38 ,  B82Y99/00 ,  H01G11/06 ,  H01G11/22 ,  H01G11/30 ,  H01M4/134 ,  H01M4/36 ,  H01M4/48 ,  H01M4/58 ,  H01M4/62 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/36

CPC classification number: H01M4/134 ,  H01G11/24 ,  H01G11/46 ,  H01G11/50 ,  H01M4/366 ,  H01M4/386 ,  H01M4/387 ,  H01M4/48 ,  H01M4/58 ,  H01M4/62 ,  H01M10/0525 ,  Y02E60/13 ,  Y10T428/259 ,  Y10T428/2927

Abstract: A method of producing a material capable of electrochemically storing and releasing a large amount of lithium ions is provided. The material is used as an electrode material for a negative electrode, and includes silicon or tin primary particles composed of crystal particles each having a specific diameter and an amorphous surface layer formed of at least a metal oxide, having a specific thickness. Gibbs free energy when the metal oxide is produced by oxidation of a metal is smaller than Gibbs free energy when silicon or tin is oxidized, and the metal oxide has higher thermodynamic stability than silicon oxide or tin oxide. The method of producing the electrode material includes reacting silicon or tin with a metal oxide, reacting a silicon oxide or a tin oxide with a metal, or reacting a silicon compound or a tin compound with a metal compound to react with each other.

Abstract translation: 提供了一种生产能电化学储存的材料和释放大量锂离子的方法。 所述材料被用作电极材料上的负电极，并且包括结晶颗粒各自具有特定的直径和形成的至少一个金属氧化物的无定形表面层上，具有特定厚度的由硅或锡的初级粒子。 吉布斯自由能当金属氧化物是由金属的氧化生成比吉布斯自由能小于将硅或锡氧化，并且该金属氧化物具有高于硅氧化物或锡氧化物的热力学稳定性。 制造电极材料的方法，包括使硅或锡与金属氧化物，与金属反应的氧化硅或氧化锡，或反应的硅化合物或与金属化合物与海誓山盟反应的锡化合物。

公开(公告)号：EP1604415A4

公开(公告)日：2009-01-28

申请号：EP04723041

申请日：2004-03-24

Applicant: CANON KK

Inventor： KAWAKAMI SOICHIRO ,  ASAO MASAYA ,  SUZUKI NOBUYUKI ,  YAMADA YASUHIRO ,  OGURA TAKAO

IPC: H01M4/38 ,  H01M10/052 ,  H01M10/36 ,  H01M4/02 ,  H01M10/40

CPC classification number: H01M10/052 ,  H01M4/386 ,  Y02T10/7011

公开(公告)号：EP0814531A2

公开(公告)日：1997-12-29

申请号：EP97114299

申请日：1994-03-29

Applicant: CANON KK

Inventor： KAWAKAMI SOICHIRO

IPC: H01M2/16 ,  H01M6/16 ,  H01M6/50 ,  H01M10/052 ,  H01M10/0565 ,  H01M10/0567 ,  H01M10/36 ,  H01M10/42 ,  H01M10/40

CPC classification number: H01M10/052 ,  H01M2/1666 ,  H01M2/1673 ,  H01M2/1686 ,  H01M6/164 ,  H01M6/168 ,  H01M10/0565 ,  H01M10/0567 ,  H01M10/4235 ,  H01M2200/00 ,  H01M2200/10 ,  H01M2300/0034

Abstract: A purpose of the present invention is to provide a secondary battery of high safety and high energy density. The battery of the present invention is a microcapsule containing lithium secondary battery at least formed of negative electrode active material, a separator, positive electrode active material, electrolytic solution (electrolyte), a collector and a battery case, characterized in that microcapsules are dispersed within the electrolytic solution or separator, said microcapsules discharging the chemical substance having hydroxyl group or chemical substance which is polymerization initiator, when the temperature within battery rises.

Abstract translation: 本发明的目的是提供一种高安全性和高能量密度的二次电池。 本发明的电池是含有至少由负极活性物质，隔膜，正极活性物质，电解液（电解质），集电体和电池壳体形成的锂二次电池的微胶囊，其特征在于微胶囊分散在 当电池内的温度升高时，所述电解溶液或分离器，所述微胶囊释放具有羟基的化学物质或作为聚合引发剂的化学物质。

公开(公告)号：AT489757T

公开(公告)日：2010-12-15

申请号：AT02011957

申请日：2002-05-29

Applicant: CANON KK

Inventor： KAWAKAMI SOICHIRO ,  DEGURA YASUSABURO

IPC: H02J7/00 ,  G01R31/02 ,  G01R31/36 ,  H01M10/44 ,  H01M10/48

Abstract: A detecting method for detecting internal information of an inspective rechargeable battery when said inspective rechargeable battery is charged by a constant current-constant voltage charging regime, comprising at least a step (A) of measuring an elapse of time (t) from the time when a constant current charging mode at a constant current value I0 is shifted to a constant voltage charging mode at a constant voltage Vmax and measuring a charge current value I in the constant voltage charging mode, a step (B) of obtaining a period of time from said shift time to the constant voltage charging in the constant voltage charging mode until the time when said charge current value I0 in the constant voltage charging mode reaches a given current value IM, and a step (C) of obtaining an electricity quantity charged in the constant voltage charging mode with respect to the inspective rechargeable battery.