公开(公告)号：US20030065043A1

公开(公告)日：2003-04-03

申请号：US10230496

申请日：2002-08-29

Applicant: Conoco Inc.

Inventor： Olga P. Ionkina ,  Kamel M. Makar ,  Leo E. Manzer ,  Munirpallam A. Subramanian

IPC: C07C027/06

CPC classification number: B01J23/882 ,  B01J23/80 ,  B01J23/825 ,  B01J23/835 ,  B01J23/883 ,  C10G2/332

Abstract: A process is disclosed for producing hydrocarbons. The process involves contacting a feed stream comprising hydrogen and carbon monoxide with a catalyst in a reaction zone maintained at conversion-promoting conditions effective to produce an effluent stream comprising hydrocarbons. In accordance with this invention, the catalyst used in the process includes at least a Fischer-Tropsch metal and a promoter selected from the group consisting of molybdenum, tin, gallium, and zinc. The Fischer-Tropsch metal preferably includes cobalt. The catalyst may also include a support material selected from the group including silica, titania, titania/alumina, zirconia, alumina, silica-alumina, aluminum fluoride, and fluorided aluminas.

Abstract translation: 公开了一种用于生产烃的方法。 该方法包括将包含氢气和一氧化碳的进料流与催化剂接触，所述反应区域保持在有效产生包含烃的流出物流的转化促进条件下。 根据本发明，用于该方法的催化剂包括至少一种费 - 托金属和一种选自钼，锡，镓和锌的助催化剂。 费 - 托金属优选包括钴。 催化剂还可以包括选自二氧化硅，二氧化钛，二氧化钛/氧化铝，氧化锆，氧化铝，二氧化硅 - 氧化铝，氟化铝和氟化氧化铝的载体材料。

公开(公告)号：US20020173555A1

公开(公告)日：2002-11-21

申请号：US10047231

申请日：2002-01-14

Applicant: Conoco Inc.

Inventor： Olga Ionkina ,  Wenchun Chao ,  Munirpallam A. Subramanian ,  Leo E. Manzer ,  Kamel M. Makar ,  Ajoy P. Raje

IPC: B01J021/02 ,  C07C027/06

CPC classification number: C10G2/332 ,  B01J21/02 ,  B01J23/74 ,  B01J23/75 ,  B01J23/89 ,  B01J23/8913 ,  C10G2/333

Abstract: A process is disclosed for producing hydrocarbons. The process involves contacting a feed stream comprising hydrogen and carbon monoxide with a catalyst in a reaction zone maintained at conversion-promoting conditions effective to produce an effluent stream comprising hydrocarbons. In accordance with this invention, the catalyst used in the process includes at least a Fischer-Tropsch metal and boron. The Fischer-Tropsch metal preferably includes cobalt and optionally ruthenium or platinum. The catalyst may also comprise a support material selected from the group including silica, titania, titania/alumina, zirconia, alumina, aluminum fluoride, and fluorided aluminas.

Abstract translation: 公开了一种用于生产烃的方法。 该方法包括将包含氢气和一氧化碳的进料流与催化剂接触，所述反应区域保持在有效产生包含烃的流出物流的转化促进条件下。 根据本发明，用于该方法的催化剂至少包括费 - 托金属和硼。 费 - 托金属优选包括钴和任选的钌或铂。 催化剂还可以包含选自包括二氧化硅，二氧化钛，二氧化钛/氧化铝，氧化锆，氧化铝，氟化铝和氟化氧化铝的载体材料。