公开(公告)号：US20030027874A1

公开(公告)日：2003-02-06

申请号：US10184472

申请日：2002-06-27

Applicant: Conoco Inc.

Inventor： Norman Herron ,  Kostantinos Kourtakis ,  Munirpallam A. Subramanian ,  Olga Ionkina ,  Nithya Srinivasan

IPC: C07C027/06

CPC classification number: C10G2/331

Abstract: A catalyst and process for producing hydrocarbons using the catalyst is provided. The process involves contacting a feed stream comprising hydrogen and carbon monoxide with the catalyst in a reaction zone maintained at conversion-promoting conditions effective to produce an effluent stream comprising hydrocarbons. In accordance with this invention the catalyst used in the process includes at least one catalytic metal for Fischer-Tropsch reactions, preferably cobalt. The catalyst further includes a structural component, preferably a support, that includes a metal selected from the group consisting of oxides of Group 2 metals, Group 3 metals, Group 6 metals, Group 8 metals, Group 12 metals, Group 15 metals, and combinations thereof, preferably as the oxide.

Abstract translation: 提供了使用该催化剂生产烃的催化剂和方法。 该方法包括使包含氢气和一氧化碳的进料流与催化剂在保持在有效产生包含烃的流出物流的转化促进条件的反应区中接触。 根据本发明，用于该方法的催化剂包括至少一种用于费 - 托反应的催化金属，优选为钴。 催化剂还包括结构组分，优选载体，其包括选自第2族金属，第3族金属，第6族金属，第8族金属，第12族金属，第15族金属和组合的金属的金属 优选作为氧化物。

公开(公告)号：US20020173555A1

公开(公告)日：2002-11-21

申请号：US10047231

申请日：2002-01-14

Applicant: Conoco Inc.

Inventor： Olga Ionkina ,  Wenchun Chao ,  Munirpallam A. Subramanian ,  Leo E. Manzer ,  Kamel M. Makar ,  Ajoy P. Raje

IPC: B01J021/02 ,  C07C027/06

CPC classification number: C10G2/332 ,  B01J21/02 ,  B01J23/74 ,  B01J23/75 ,  B01J23/89 ,  B01J23/8913 ,  C10G2/333

Abstract: A process is disclosed for producing hydrocarbons. The process involves contacting a feed stream comprising hydrogen and carbon monoxide with a catalyst in a reaction zone maintained at conversion-promoting conditions effective to produce an effluent stream comprising hydrocarbons. In accordance with this invention, the catalyst used in the process includes at least a Fischer-Tropsch metal and boron. The Fischer-Tropsch metal preferably includes cobalt and optionally ruthenium or platinum. The catalyst may also comprise a support material selected from the group including silica, titania, titania/alumina, zirconia, alumina, aluminum fluoride, and fluorided aluminas.

Abstract translation: 公开了一种用于生产烃的方法。 该方法包括将包含氢气和一氧化碳的进料流与催化剂接触，所述反应区域保持在有效产生包含烃的流出物流的转化促进条件下。 根据本发明，用于该方法的催化剂至少包括费 - 托金属和硼。 费 - 托金属优选包括钴和任选的钌或铂。 催化剂还可以包含选自包括二氧化硅，二氧化钛，二氧化钛/氧化铝，氧化锆，氧化铝，氟化铝和氟化氧化铝的载体材料。