公开(公告)号：US20040072685A1

公开(公告)日：2004-04-15

申请号：US10269174

申请日：2002-10-11

Applicant: Conoco Inc.

Inventor： Zhen Y. Chen ,  Sriram Ramani ,  Lisa M. Carmichael ,  Joe D. Allison

IPC: C07C005/333 ,  C07C005/327

CPC classification number: C07C5/48 ,  C07C2523/76 ,  C07C2523/89 ,  C07C11/02

Abstract: A catalyst useful for the production of olefins from alkanes via oxidative dehydrogenation (ODH) is disclosed. In accordance with a preferred embodiment of the present invention, a catalyst for use in ODH processes includes a MCrAlY support. M is preferably a base metal, or combination of base metals. A base metal is herein defined as a non-Group VIII metal, with the exception of iron, cobalt and nickel. Suitable base metals include Group IB-VIIB metals, Group IIIA-VA metals, Lanthanide metals, iron, cobalt and nickel. In a preferred embodiment, M is iron. Additionally, the catalyst may optionally include a Group VIII promoter. Suitable Group VIII promoters include Ru, Rh, Pd, Os, Ir, and Pt. In another preferred embodiment, M is a combination of a Lanthanide metal and iron with a front-loaded Group VIII promoter.

Abstract translation: 公开了一种可用于通过氧化脱氢（ODH）从烷烃生产烯烃的催化剂。 根据本发明的优选实施方案，用于ODH方法的催化剂包括MCrAlY载体。 M优选为贱金属或贱金属的组合。 本文将贱金属定义为非Ⅷ族金属，铁，钴和镍除外。 合适的贱金属包括IB-VIIB族金属，IIIA-VA族金属，镧系金属，铁，钴和镍。 在优选的实施方案中，M是铁。 另外，催化剂可任选地包括VIII族促进剂。 合适的VIII族促进剂包括Ru，Rh，Pd，Os，Ir和Pt。 在另一个优选的实施方案中，M是镧系金属和铁与前负载的VIII族促进剂的组合。

公开(公告)号：US20040068148A1

公开(公告)日：2004-04-08

申请号：US10266404

申请日：2002-10-08

Applicant: Conoco Inc.

Inventor： Joe D. Allison ,  Sriram Ramani ,  Zhen Chen ,  Lisa M. Carmichael ,  Shang Y. Chen ,  Steve R. McDonald ,  Anne Gaffney

IPC: C07C005/333 ,  C07C005/327 ,  C07C005/373

CPC classification number: B01J23/56 ,  B01J23/42 ,  B01J23/44 ,  C07C5/48 ,  C07C2523/26 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/745 ,  C07C11/02

Abstract: Catalysts and methods useful for the production of olefins from alkanes via oxidative dehydrogenation (ODH) are disclosed. The ODH catalysts are comprised of a Group VIII promoter metal present at trace levels. The Group VIII promoter metal is preferably platinum, palladium or a combination thereof and is preferably present at a promoter metal loading of between about 0.005 and about 0.1 weight percent. Optionally, the ODH catalysts include a base metal, metal oxide, or combination thereof. The optional base metal is selected from the group consisting of Group IB-IIB metals, Group IVB-VIIB metals, Group IIA-VA metals, scandium, yttrium, actinium, iron, cobalt, nickel, their oxides, and combinations thereof. The base metal is more preferably selected from the group consisting copper, tin, chromium, gold, manganese and their respective oxides and any combinations thereof. The base metal loading is preferably between about 0.5 and about 10 weight percent. Optionally, the promoter metal can be supported on a refractory material. The refractory support is preferably comprised of a material selected from group consisting of zirconia, stabilized zirconias, alumina, stabilized aluminas, and combinations thereof.

Abstract translation: 公开了可用于通过氧化脱氢（ODH）从烷烃生产烯烃的催化剂和方法。 ODH催化剂由痕量存在的VIII族助催化剂金属组成。 VIII族助催化剂金属优选为铂，钯或其组合，优选以约0.005至约0.1重量％的助催化剂金属负载存在。 任选地，ODH催化剂包括贱金属，金属氧化物或其组合。 可选择的贱金属选自IB-IIB族金属，IVB-VIIB族金属，IIA-VA族金属，钪，钇，锕，铁，钴，镍，它们的氧化物及其组合。 贱金属更优选选自铜，锡，铬，金，锰及其各自的氧化物及其任何组合。 贱金属负载量优选为约0.5至约10重量％。 任选地，促进剂金属可以负载在耐火材料上。 耐火载体优选由选自氧化锆，稳定化氧化锆，氧化铝，稳定化氧化铝及其组合的材料组成。

公开(公告)号：US20040082670A1

公开(公告)日：2004-04-29

申请号：US10278634

申请日：2002-10-23

Applicant: Conoco Inc.

Inventor： Robin G. Cnossen ,  Lisa M. Carmichael

IPC: C07C027/26

CPC classification number: C01B3/386 ,  B01J23/90 ,  B01J23/96 ,  B01J38/04 ,  B01J2219/00006 ,  C01B3/40 ,  C01B2203/0261 ,  C01B2203/062 ,  C01B2203/10 ,  Y02P20/125 ,  Y02P20/52 ,  Y02P20/584

Abstract: The present invention relates to a process for the preparation of synthesis gas (i.e., a mixture of carbon monoxide and hydrogen), typically labeled syngas. More particularly, the present invention relates to a regeneration method for a syngas catalyst. Still more particularly, the present invention relates to the regeneration of syngas catalysts using a re-dispersion technique. The re-dispersion technique involves the formation and removal of carbonyls with the active metals. The carbonyl formation and removal effectively re-disperses the catalyst metal.

Abstract translation: 本发明涉及通常标记为合成气的合成气（即，一氧化碳和氢气的混合物）的制备方法。 更具体地说，本发明涉及合成气催化剂的再生方法。 更具体地说，本发明涉及使用再分散技术再生合成气催化剂。 再分散技术涉及用活性金属形成和除去羰基。 羰基的形成和去除有效地重新分散催化剂金属。

公开(公告)号：US20040102531A1

公开(公告)日：2004-05-27

申请号：US10301370

申请日：2002-11-21

Applicant: Conoco Inc.

Inventor： Stephen R. Landis ,  Lisa M. Carmichael ,  Kevin L. Ricketson ,  Thomas R. Ruddy II

IPC: C07C027/26

CPC classification number: C10G2/32 ,  C01B3/386 ,  C01B2203/0261 ,  C01B2203/062 ,  C01B2203/1205 ,  C01B2203/1235 ,  Y02P20/52

Abstract: Embodiments include a method and apparatus for producing synthesis gas in a catalytic partial oxidation reactor by adding hydrogen to the reactor feed stream.

Abstract translation: 实施方案包括通过向反应器进料流中加入氢气在催化部分氧化反应器中生产合成气的方法和装置。

公开(公告)号：US20040068153A1

公开(公告)日：2004-04-08

申请号：US10266405

申请日：2002-10-08

Applicant: Conoco Inc.

Inventor： Joe D. Allison ,  Sriram Ramani ,  Zhen Chen ,  Lisa M. Carmichael ,  Shang Y. Chen ,  Steve R. McDonald ,  Anne Gaffney

IPC: C07C005/333 ,  B01J023/10 ,  C07C005/373 ,  C07C005/327 ,  C07C009/00

CPC classification number: C07C5/48 ,  B01J23/10 ,  B01J23/63 ,  C07C2523/10 ,  C07C2523/56 ,  Y02P20/52 ,  C07C11/02 ,  C07C11/04

Abstract: Catalysts and methods useful for the production of olefins from alkanes via oxidative dehydrogenation (ODH) are disclosed. The ODH catalysts include a base metal selected from the group consisting of lanthanide metals, their oxides, and combinations thereof. The base metal is more preferably selected from the group consisting of samarium, cerium, praseodymium, terbium, their corresponding oxides and combinations thereof. The base metal loading is preferably between about 0.5 and about 20 weight percent and more preferably between about 2 and about 10 weight percent. Optionally, the ODH catalysts are further comprised of a Group VIII promoter metal present at trace levels. The Group VIII promoter metal is preferably platinum, palladium or a combination thereof and is preferably present at a promoter metal loading of between about 0.005 and about 0.1 weight percent. Optionally, the ODH catalyst is supported on a refractory support.

公开(公告)号：US20030129121A1

公开(公告)日：2003-07-10

申请号：US10263324

申请日：2002-10-01

Applicant: Conoco Inc.

Inventor： Joe D. Allison ,  Lisa M. Carmichael ,  Larry M. Meyer ,  Kenneth M. York ,  Sriram Ramani

IPC: D01F009/12

CPC classification number: B82Y30/00 ,  D01F9/1271 ,  D01F9/1273

Abstract: The present invention includes an integrated process for the production of carbon filaments, comprising converting a portion of hydrocarbons to alkenes via oxidative dehydrogenation and further converting a portion of the alkenes to carbon filaments via contact with a metal catalyst. A portion of unconverted hydrocarbons remaining after oxidative dehydrogenation may also be further converted to carbon filaments via contact with the metal catalyst. The conversion of hydrocarbons to alkenes via oxidative dehydrogenation and further conversion of the alkenes and unconverted hydrocarbons to carbon filaments via contact with a metal catalyst may be carried out in the same or separate reactor vessels. A plurality of reactor vessels arranged in parallel may be used for the conversion of the alkenes and unconverted hydrocarbons to carbon filaments.

Abstract translation: 本发明包括用于生产碳丝的一体化方法，包括通过氧化脱氢将一部分烃转化为烯烃，并通过与金属催化剂接触进一步将一部分烯烃转化为碳长丝。 在氧化脱氢后残留的一部分未转化的烃还可以通过与金属催化剂的接触进一步转化为碳长丝。 通过氧化脱氢将烃转化为烯烃，并通过与金属催化剂接触将烯烃和未转化的烃进一步转化成碳长丝，可以在相同或分开的反应器容器中进行。 平行布置的多个反应器容器可用于将烯烃和未转化的烃转化为碳丝。