Modification of the pore structure of metal oxide and mixed metal oxide supports for catalysts synthesis
    1.
    发明申请
    Modification of the pore structure of metal oxide and mixed metal oxide supports for catalysts synthesis 有权
    用于催化剂合成的金属氧化物和混合金属氧化物载体的孔结构的改性

    公开(公告)号:US20040092392A1

    公开(公告)日:2004-05-13

    申请号:US10293825

    申请日:2002-11-13

    Applicant: Conoco Inc.

    Abstract: A porous catalyst support having an increased average pore size is produced from a mixed metal oxide material. In accordance with one embodiment, a method for preparing a mixed metal oxide material includes providing a mixed metal oxide precursor containing at least two metals, calcining the mixed metal oxide precursor at a temperature sufficient to form a thermally and mechanically stable mixed metal oxide material, and leaching the mixed metal oxide material in a leach solution with a constituent that dissolves one metal oxide. Preferably, the calcination temperature is approximately between 300null C. and 1300null C. The leaching constituent may be chosen from the group including acidic solutions of HCl, HNO3, H2SO4, H3PO3, and their combinations, or basic solutions of NH3, NaOH, KOH, and their combinations.

    Abstract translation: 具有增加的平均孔径的多孔催化剂载体由混合金属氧化物材料制成。 根据一个实施方案,制备混合金属氧化物材料的方法包括提供含有至少两种金属的混合金属氧化物前体,在足以形成热和机械稳定的混合金属氧化物材料的温度下煅烧所述混合金属氧化物前体, 并且将所述混合金属氧化物材料浸出在溶解有一种金属氧化物的成分的浸出溶液中。 优选地,煅烧温度约为300℃至1300℃。浸出组分可以选自HCl,HNO 3,H 2 SO 4,H 3 PO 3及其组合的酸性溶液或NH 3,NaOH, KOH及其组合。

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