公开(公告)号：US20040023797A1

公开(公告)日：2004-02-05

申请号：US10210353

申请日：2002-08-01

Applicant: Conoco Inc.

Inventor： Daxiang Wang ,  Tianyan Niu ,  Gloria I. Starguzzi ,  Harold A. Wright

IPC: B01J037/12

CPC classification number: B01J23/40 ,  B01J21/06 ,  B01J21/066 ,  B01J23/63 ,  B01J23/74 ,  B01J35/002 ,  B01J35/10 ,  B01J35/1009 ,  B01J35/1014 ,  B01J35/1038 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/0205 ,  B01J37/10 ,  C01B3/386 ,  C01B3/40 ,  C01B2203/0261 ,  C01B2203/1047 ,  C01B2203/1082 ,  Y02P20/52

Abstract: A pretreatment method for increasing the average pore size of a catalyst support is disclosed which increases the diffusivity and effectiveness factor null. The pretreatment method includes calcining the support in moisturized air at an elevated temperature sufficient to increase the average pore size. In some embodiments, the support may be treated with an acidic/basic solution prior to the calcination step. Alternatively, the calcination step may occur in a gas mixture including water/air/acidic (or basic) gases.

Abstract translation: 公开了一种用于增加催化剂载体的平均孔径的预处理方法，其增加了扩散系数和有效因子η。 预处理方法包括在足以增加平均孔径的高温下煅烧保湿空气中的载体。 在一些实施方案中，可以在煅烧步骤之前用酸性/碱性溶液处理载体。 或者，煅烧步骤可以在包括水/空气/酸性（或碱性）气体的气体混合物中发生。

公开(公告)号：US20030198592A1

公开(公告)日：2003-10-23

申请号：US10126395

申请日：2002-04-19

Applicant: Conoco Inc.

Inventor： Joe D. Allison ,  Sriram Ramani ,  Daxiang Wang ,  Tianyan Niu ,  Yaming Jin ,  Gloria I. Straguzzi

IPC: C01B003/26

CPC classification number: C01B3/382 ,  B01J23/002 ,  B01J23/63 ,  B01J23/8993 ,  B01J35/0006 ,  C01B3/48 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/0261 ,  C01B2203/0283 ,  C01B2203/1011 ,  C01B2203/1041 ,  C01B2203/1064 ,  C01B2203/1082 ,  C01B2203/141 ,  C01B2203/142 ,  C01B2203/143 ,  C01B2203/82 ,  Y02P20/142 ,  Y02P20/52

Abstract: Embodiments include a method and apparatus for converting a hydrocarbon and oxygen feed stream to a product stream such as syngas, including multiple serially aligned reaction zones and multiple hydrocarbon feeds. The first reaction zone catalyzes the net partial oxidation of the feed hydrocarbon. The subsequent zones catalyze reactions such as the stream or dry reforming of hydrocarbons or the water gas shift reaction, depending on the stream composition in the vicinity of the zone, and the desired product stream composition.

Abstract translation: 实施方案包括用于将烃和氧进料流转化为产物流如合成气的方法和装置，包括多个连续排列的反应区和多个烃进料。 第一反应区催化进料碳的净部分氧化。 随后的区域根据区域附近的流组成以及所需的产物流组合物催化烃类或水煤气变换反应的反应如烃或干重整。

公开(公告)号：US20030045423A1

公开(公告)日：2003-03-06

申请号：US10162056

申请日：2002-06-04

Applicant: Conoco Inc.

Inventor： Hasan Dindi ,  William H. Manogue ,  Norman Herron ,  Tianyan Niu ,  Daxiang Wang ,  David M. Minahan

IPC: C01B003/26

CPC classification number: C01B3/40 ,  B01J23/002 ,  B01J23/56 ,  B01J23/63 ,  B01J23/894 ,  B01J35/04 ,  B01J37/0201 ,  B01J37/0236 ,  B01J2523/00 ,  C01B3/386 ,  C01B2203/0261 ,  C01B2203/1017 ,  C01B2203/1047 ,  C01B2203/1052 ,  C01B2203/1064 ,  C01B2203/1076 ,  C01B2203/1082 ,  C01B2203/1241 ,  Y02P20/52 ,  B01J2523/22 ,  B01J2523/3706 ,  B01J2523/822 ,  B01J2523/3787

Abstract: A family of supported hexagonal phase mixed metal oxide catalysts are disclosed that have the general formula M2.5LnRh6O13 (expressed as atomic ratios), wherein M refers to Group II elements such as Mg, Ca, Ba, Sr and Be or a Group VIII transition metal that can exist in a null2 oxidation state, such as Ti, V, Mn, Fe, Co, Ni, Cu, Zn, Nb, Pd, Cd and Ta. Ln refers to the rare earth lanthanide group of elements, such as La, Yb, Sm and Ce. This family of catalysts demonstrate unexpected activity for efficiently catalyzing the net partial oxidation of methane in a short contact time reactor, with high selectivities for H2 product.

Abstract translation: 公开了具有通式M2.5LnRh6O13（表示为原子比）的负载六方相混合金属氧化物催化剂族，其中M是指II族元素如Mg，Ca，Ba，Sr和Be或VIII族过渡 可以存在于+2氧化态的金属，例如Ti，V，Mn，Fe，Co，Ni，Cu，Zn，Nb，Pd，Cd和Ta。 Ln是指稀土镧系元素，如La，Yb，Sm和Ce。 这种催化剂系列显示出意想不到的活性，用于在短接触时间反应器中有效催化甲烷的净部分氧化，对于H 2产物具有高选择性。

公开(公告)号：US20040101473A1

公开(公告)日：2004-05-27

申请号：US10303606

申请日：2002-11-25

Applicant: Conoco Inc.

Inventor： Daxiang Wang ,  Barbara A. Belt ,  Vincent H. Melquist ,  Steve R. Landis

IPC: C01B003/26

CPC classification number: C01B3/386 ,  C01B3/48 ,  C01B2203/0261 ,  C01B2203/0283 ,  C01B2203/0288 ,  C01B2203/0475 ,  C01B2203/061 ,  C01B2203/062

Abstract: The present invention is directed towards a process that allows for the adjustment of hydrogen concentration in a syngas product or Fischer-Tropsch feedstock stream. In particular, the invention is identified as an improved process for producing syngas comprising a secondary chemical reaction, preferably a water gas shift reaction, that allows for the adjustment of the hydrogen concentration in a syngas product stream. Ultimately, the present invention is for an improved process for converting hydrocarbon-containing gas to liquid hydrocarbons.

Abstract translation: 本发明涉及允许调节合成气产物或费 - 托原料流中的氢浓度的方法。 特别地，本发明被确定为用于生产合成气的改进方法，其包括允许调节合成气产物流中的氢浓度的次级化学反应，优选水煤气变换反应。 最终，本发明是用于将含烃气体转化为液态烃的改进方法。

公开(公告)号：US20040002422A1

公开(公告)日：2004-01-01

申请号：US10184473

申请日：2002-06-27

Applicant: Conoco Inc.

Inventor： Daxiang Wang ,  Yaming Jin ,  Harold A. Wright ,  Carl Johnston JR.

IPC: F28D001/00

CPC classification number: B01J23/63 ,  B01J23/464 ,  B01J35/006 ,  B01J35/1061 ,  B01J37/03 ,  B01J37/088

Abstract: A process and system for producing industrial-scale quantities of highly dispersed, thermally stable catalysts is disclosed. The process, which may be continuous production or batch production, includes mixing together the desired catalyst precursor materials, a combustible organic material and a solvent; evaporating the solvent, combusting the catalyst intermediate; and shaping final catalyst.

Abstract translation: 公开了一种用于生产工业规模量的高分散，热稳定的催化剂的方法和系统。 可以连续生产或批量生产的方法包括将所需的催化剂前体材料，可燃有机材料和溶剂混合在一起; 蒸发溶剂，燃烧催化剂中间体; 并成型最终催化剂。

公开(公告)号：US20030180215A1

公开(公告)日：2003-09-25

申请号：US10299879

申请日：2002-11-19

Applicant: Conoco, Inc.

Inventor： Tianyan Niu ,  Daxiang Wang ,  David M. Minahan ,  Harold A. Wright ,  Gloria I. Straguzzi

IPC: C01B003/26 ,  B01J023/10

CPC classification number: C01B3/40 ,  B01J21/04 ,  B01J21/06 ,  B01J21/066 ,  B01J23/40 ,  B01J23/58 ,  B01J23/63 ,  B01J23/70 ,  B01J23/755 ,  B01J23/78 ,  B01J35/08 ,  B01J35/10 ,  B01J35/1009 ,  B01J35/1038 ,  B01J35/1061 ,  B01J35/1066 ,  B01J35/108 ,  B01J37/0205 ,  C01B3/386 ,  C01B2203/0261 ,  C01B2203/1005 ,  C01B2203/1011 ,  C01B2203/1041 ,  C01B2203/1047 ,  C01B2203/1241 ,  Y02P20/52

Abstract: Controlled pore structure catalysts are disclosed that are active for catalyzing the partial oxidation of methane to CO and H2 and, advantageously, are capable of initiating the reaction without the need for an additional ignition source. A preferred catalyst comprises rhodium and samarium supported on an alumina or modified alumina support having certain surface area, pore volume, pore size and metal dispersion characteristics that permit light-off of the reaction at temperatures below 500null C. and with little or no use of an ignition agent. A method of partially oxidizing a light hydrocarbon to form synthesis gas, and a method of enhancing low-temperature light-off of the process are also described.

Abstract translation: 公开了控制的孔结构催化剂，其有效催化将甲烷部分氧化成CO和H 2，并且有利地能够引发反应而不需要额外的点火源。 优选的催化剂包括负载在具有一定表面积，孔体积，孔径和金属分散特性的氧化铝或改性氧化铝载体上的铑和钐，其允许在低于500℃的温度和少量或不使用的温度下使反应点燃 的点火剂。 还描述了一种部分氧化轻烃以形成合成气的方法，以及提高该方法的低温点火的方法。

公开(公告)号：US20030153632A1

公开(公告)日：2003-08-14

申请号：US10219108

申请日：2002-08-15

Applicant: Conoco Inc.

Inventor： Daxiang Wang ,  Harold A. Wright ,  Beatrice C. Ortego ,  Sinh H. Trinh ,  Rafael L. Espinoza

IPC: C07C027/06

CPC classification number: C10G2/32 ,  C01B3/386 ,  C01B3/501 ,  C01B3/56 ,  C01B13/0251 ,  C01B2203/0261 ,  C01B2203/0405 ,  C01B2203/043 ,  C01B2203/0465 ,  C01B2203/062

Abstract: The present invention is an improvement in the preparation of liquid hydrocarbons from natural gas/methane, oxygen and/or steam. In particular, the present invention relates to processes for the production of synthesis gas, reducing the oxygen concentration from the synthesis gas, and the production of liquid hydrocarbons using the oxygen reduced synthesis gas as a feedstock. More particularly, the present invention described herein identifies catalyst compositions, apparatus and methods of using such catalysts and apparatus for preparing liquid hydrocarbons via oxygen reduced synthesis gas all in accordance with the present invention.

Abstract translation: 本发明是从天然气/甲烷，氧气和/或蒸汽制备液体烃的改进。 特别地，本发明涉及用于生产合成气的方法，降低来自合成气的氧浓度，以及使用氧还原合成气作为原料生产液体烃。 更具体地，本发明描述了根据本发明的催化剂组合物，使用这种催化剂的装置和方法以及通过氧还原合成气制备液体烃的装置。

公开(公告)号：US20030103892A1

公开(公告)日：2003-06-05

申请号：US10268632

申请日：2002-10-10

Applicant: Conoco Inc.

Inventor： Tianyan Niu ,  Bang C. Xu ,  Daxiang Wang

IPC: B01J023/10 ,  C01B003/26

CPC classification number: C01B3/40 ,  B01J23/864 ,  B01J23/8993 ,  C01B3/386 ,  C01B2203/0261 ,  C01B2203/1017 ,  C01B2203/1023 ,  C01B2203/1041 ,  C01B2203/1052 ,  C01B2203/1082 ,  C01B2203/1094 ,  C01B2203/1241 ,  Y02P20/52

Abstract: Catalysts comprising promoted cobalt-chromium oxide disposed on a lanthanide coated refractory support that are active for catalyzing the net partial oxidation of methane or natural gas to products containing CO and H2 are disclosed, along with short contact time processes employing the new catalysts for producing synthesis gas. Preferred promoters are rhodium and cerium, and a preferred lanthanide coating material is ytterbium.

Abstract translation: 公开了包含促进的钴 - 铬氧化物的催化剂，其被布置在包含镧系元素的耐火载体上，其活性物质用于催化甲烷或天然气对含CO和H 2的产物的净部分氧化，以及使用新的催化剂用于生产合成的短接触时间方法 加油站。 优选的助催化剂是铑和铈，优选的镧系元素涂料是镱。

公开(公告)号：US20030096880A1

公开(公告)日：2003-05-22

申请号：US10282382

申请日：2002-10-29

Applicant: Conoco Inc.

Inventor： Daxiang Wang ,  Yaming Jin ,  Harold A. Wright ,  Rafael L. Espinoza

IPC: B01J031/00 ,  C07C027/06 ,  B01J023/00

CPC classification number: C01B3/40 ,  B01J21/04 ,  B01J23/40 ,  B01J23/42 ,  B01J23/464 ,  B01J23/58 ,  B01J23/63 ,  B01J23/755 ,  B01J35/0013 ,  B01J35/002 ,  B01J35/006 ,  B01J35/10 ,  B01J35/1014 ,  B01J35/1061 ,  B01J35/1066 ,  B01J35/108 ,  B01J37/0203 ,  B01J37/08 ,  B01J37/084 ,  B01J37/088 ,  B01J37/18 ,  C01B3/386 ,  C01B2203/0261 ,  C01B2203/062 ,  C01B2203/066 ,  C01B2203/1011 ,  C01B2203/1041 ,  C01B2203/1052 ,  C01B2203/1064 ,  C01B2203/107 ,  C01B2203/1082 ,  C01B2203/1094 ,  C01B2203/1241 ,  C01B2203/1276 ,  C01B2203/1604 ,  Y02P20/52

Abstract: Combustion dispersed metal-metal oxide catalysts that are highly active for catalyzing the net partial oxidation of methane to CO and H2 are disclosed, along with their manner of making and processes for producing synthesis gas employing the new catalysts. A preferred catalyst comprises rhodium nanoparticles, with or without a rare earth promoter, that is deposited on null-alumina by combusting a mixture of catalyst precursor materials and a flammable organic compound. In a preferred syngas production process a stream of reactant gas mixture containing methane and O2 is passed over the catalyst in a short contact time reactor to efficiently produce a mixture of carbon monoxide and hydrogen at superatmospheric pressures.

Abstract translation: 公开了用于催化甲烷到CO和H 2的净部分氧化的高活性的燃烧分散的金属 - 金属氧化物催化剂及其制备方法和使用新催化剂生产合成气的方法。 优选的催化剂包括具有或不具有稀土助催化剂的铑纳米颗粒，其通过燃烧催化剂前体材料和易燃有机化合物的混合物而沉积在α-氧化铝上。 在优选的合成气生产过程中，含有甲烷和O 2的反应气体混合物流在短接触时间反应器中通过催化剂，以在超大气压下有效地产生一氧化碳和氢气的混合物。

公开(公告)号：US20040092392A1

公开(公告)日：2004-05-13

申请号：US10293825

申请日：2002-11-13

Applicant: Conoco Inc.

Inventor： Daxiang Wang ,  Shuibo Xie

IPC: C01F007/04

CPC classification number: C01B13/18 ,  B01J37/0018 ,  B01J37/06 ,  C01B3/386 ,  C01B3/40 ,  C01B13/14 ,  C01B2203/0261 ,  C01B2203/1047 ,  C01B2203/1082 ,  C01G1/02 ,  C01G25/00 ,  C01G25/02 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C01P2006/17 ,  Y02P20/52

Abstract: A porous catalyst support having an increased average pore size is produced from a mixed metal oxide material. In accordance with one embodiment, a method for preparing a mixed metal oxide material includes providing a mixed metal oxide precursor containing at least two metals, calcining the mixed metal oxide precursor at a temperature sufficient to form a thermally and mechanically stable mixed metal oxide material, and leaching the mixed metal oxide material in a leach solution with a constituent that dissolves one metal oxide. Preferably, the calcination temperature is approximately between 300null C. and 1300null C. The leaching constituent may be chosen from the group including acidic solutions of HCl, HNO3, H2SO4, H3PO3, and their combinations, or basic solutions of NH3, NaOH, KOH, and their combinations.

Abstract translation: 具有增加的平均孔径的多孔催化剂载体由混合金属氧化物材料制成。 根据一个实施方案，制备混合金属氧化物材料的方法包括提供含有至少两种金属的混合金属氧化物前体，在足以形成热和机械稳定的混合金属氧化物材料的温度下煅烧所述混合金属氧化物前体， 并且将所述混合金属氧化物材料浸出在溶解有一种金属氧化物的成分的浸出溶液中。 优选地，煅烧温度约为300℃至1300℃。浸出组分可以选自HCl，HNO 3，H 2 SO 4，H 3 PO 3及其组合的酸性溶液或NH 3，NaOH， KOH及其组合。