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    9.
    发明专利
    未知

    公开(公告)号：DE1160830B

    公开(公告)日：1964-01-09

    申请号：DED0034335

    申请日：1960-09-23

    Applicant: DEGUSSA

    Inventor： KLOEPFER HARRY ,  KNORRE HELMUT ,  STEPHAN KARL

    IPC: C01B6/04

    Abstract: A hydride of lithium or an alkaline earth metal, e.g. calcium, is prepared by reacting an anhydrous halide, e.g. chloride, of lithium or the alkaline earth metal with sodium or potassium or alloys thereof in the presence of hydrogen at a temperature high enough to melt the mixture of halide and alkali metal under the reaction conditions but below the boiling point of the alkali metal and below the temperature for substantial decomposition of the product hydride, e.g. 725 DEG C. for Ca, 650 DEG C. for Li, the reaction being carried out in such a way to avoid layer formation. The reaction may be carried out a temperature at which the mixture of halide and metal is completely molten before the reaction starts and the product mixture is at least a stirrable suspension of solid in melt. The stirring action may be up and down or accomplished by vibration or the introduction of hydrogen, e.g. at 50-70 mm. Hg above atmospheric. The melting point of the reaction mixture may be lowered by the addition of an alkali or alkaline earth metal halide, e.g. NaCl or an excess of halide reactant. An excess of halide reactant is desirable for alkaline earth metal hydride production but for lithium hydride, stoichiometric proportions of reactants may be used. The Na/K halide formed in the reaction may be extracted with glycerine, propylene glycol or liquid ammonia. Specification 761,745 is referred to.

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