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公开(公告)号:AT73111T
公开(公告)日:1992-03-15
申请号:AT88108299
申请日:1988-05-25
Applicant: DEGUSSA
Inventor: WITZEL MICHAEL DR , KLEINSCHMIT PETER DR , PFEIFER WOLF-DIETER DR , VOIGT CARL DR , ALBERS PETER DR
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公开(公告)号:DE3868731D1
公开(公告)日:1992-04-09
申请号:DE3868731
申请日:1988-05-25
Applicant: DEGUSSA
Inventor: WITZEL MICHAEL DR , KLEINSCHMIT PETER DR , PFEIFER WOLF-DIETER DR , VOIGT CARL DR , ALBERS PETER DR
Abstract: Prodn. of HCN under the conditions of the 'HCN-CH4-NH3' process, involves reacting 1-4 C aliphatic hydrocarbons (I) with NH3 in the presence of a catalyst (II). The novel features are that : (a) reaction is carried out initially with a catalyst precursor (IIA), consisting of alumina mouldings with Al ions and very small amts. of noble metal, pref. Pt ions applied to the surface from soln.; (b) (IIA) is dried and reduced with H2 before use; (c) (IIA) is placed in the HCN reactor, which is heated to 1000-1350 deg.C and charged with the usual mixt. of NH3 and (I) for this reaction, which is initiated by (IIA); and (d) after a short time, reaction is continued with the Al nitride film formed in situ on the surface of (IIA). Pref. (I) is CH4. (II) is a pref. tubular moulding prepd. from alpha-alumina by impregnation with H2PtCl6 soln. (pref. contg. 0.5-5 wt.% Pt ions) and an AlCl3, Al(NO3)3 or Al2(SO4)3 soln., pref. using a noble metal (Pt):Al molar ratio of 0.001-0.1:1, esp. 0.01-0.1:1.
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公开(公告)号:DE2254701A1
公开(公告)日:1974-05-16
申请号:DE2254701
申请日:1972-11-09
Applicant: DEGUSSA
Inventor: ASINGER FRIEDRICH PROF DR ING , PFEIFER WOLF-DIETER DR , OFFERMANNS HERIBERT DR , SCHERBERICH PAUL DR , SCHREYER GERD DR
IPC: C07D277/10 , C07D277/60 , C07D91/24
Abstract: 2 AND 5 SUBSTITUTED THIAZOLINE-(3) COMPOUNDS OF THE FORMULA: HC=N R1¦¦R3 ANGLE CC ANGLE (I) ANGLE R2SR4 in which R1, R2, and R3 and R4 are the same or different, R1 and R2 are straight or branched chain lower alkyl, alkenyl or aralkyl groups or together are a straight or branched chain alkylene or ethylenically unsaturated divalent aliphatic hydrocarbon group which joins with the adjacent carbon atom to form a ring and R3 and R4 are similarly defined except R3 can also be hydrogen by reaching a 2,2' dioxodisulfide of the formula OO C ANGLE C ANGLE H R1¦H¦R1 ANGLE C---S-S---C ANGLE (II) R2R2 with an oxo compound of the formula R3 ANGLE C=O R4 and with ammonia and hydrogen sulfide in the presence of an amine and an ammonium salt.
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公开(公告)号:AU1904188A
公开(公告)日:1989-01-19
申请号:AU1904188
申请日:1988-07-14
Applicant: DEGUSSA
Inventor: WITZEL MICHAEL DR , KLEINSCHMIT PETER DR , PFEIFER WOLF-DIETER DR , VOIGT CARL DR , ALBERS PETER DR
Abstract: A specific form of surface coating of Al2O3 catalysts, using additional amounts of aluminium ions and minimum amounts of platinum ions, made it possible to use Al2O3 as a catalyst for long-term operation (150 days and more) in the preparation of hydrogen cyanide from hydrocarbons and ammonia, preferably in the BMA process.
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公开(公告)号:CH597152A5
公开(公告)日:1978-03-31
申请号:CH966874
申请日:1974-07-12
Applicant: DEGUSSA
Inventor: SCHERBERICH PAUL DR , PFEIFER WOLF-DIETER DR
IPC: C07D295/08 , C07C67/00 , C07C231/00 , C07C231/02 , C07C233/03 , C07C233/05 , C07D211/32 , C07D233/20 , C07D239/10 , C07D239/74 , C07D277/04 , C07D277/06 , C07D277/20 , C07D277/44 , C07D277/46 , C07D277/60 , C07D295/10 , C07D295/18 , C07D295/182 , C07C102/00
Abstract: Organic basic nitrogen compounds are formylated in the presence of acetic anhydride by adding the nitrogen compound as a salt and carrying out the formylation with an alkali or ammonium formate in an organic solvent having limited miscibility with water.
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公开(公告)号:AU596900B2
公开(公告)日:1990-05-17
申请号:AU1904188
申请日:1988-07-14
Applicant: DEGUSSA
Inventor: WITZEL MICHAEL DR , KLEINSCHMIT PETER DR , PFEIFER WOLF-DIETER DR , VOIGT CARL DR , ALBERS PETER DR
Abstract: A specific form of surface coating of Al2O3 catalysts, using additional amounts of aluminium ions and minimum amounts of platinum ions, made it possible to use Al2O3 as a catalyst for long-term operation (150 days and more) in the preparation of hydrogen cyanide from hydrocarbons and ammonia, preferably in the BMA process.
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公开(公告)号:DE3723535A1
公开(公告)日:1989-01-26
申请号:DE3723535
申请日:1987-07-16
Applicant: DEGUSSA
Inventor: WITZEL MICHAEL DR , KLEINSCHMIT PETER DR , PFEIFER WOLF-DIETER DR , VOIGT CARL DR , ALBERS PETER DR
Abstract: A specific form of surface coating of Al2O3 catalysts, using additional amounts of aluminium ions and minimum amounts of platinum ions, made it possible to use Al2O3 as a catalyst for long-term operation (150 days and more) in the preparation of hydrogen cyanide from hydrocarbons and ammonia, preferably in the BMA process.
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公开(公告)号:DE2335990A1
公开(公告)日:1975-01-30
申请号:DE2335990
申请日:1973-07-14
Applicant: DEGUSSA
Inventor: SCHERBERICH PAUL DR , PFEIFER WOLF-DIETER DR
IPC: C07D295/08 , C07C67/00 , C07C231/00 , C07C231/02 , C07C233/03 , C07C233/05 , C07D211/32 , C07D233/20 , C07D239/10 , C07D239/74 , C07D277/04 , C07D277/06 , C07D277/20 , C07D277/44 , C07D277/46 , C07D277/60 , C07D295/10 , C07D295/18 , C07D295/182 , C07C102/00 , C07C103/34 , C07C103/36
Abstract: Organic basic nitrogen compounds are formylated in the presence of acetic anhydride by adding the nitrogen compound as a salt and carrying out the formylation with an alkali or ammonium formate in an organic solvent having limited miscibility with water.
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