9.
    发明专利
    未知

    公开(公告)号:DE3868731D1

    公开(公告)日:1992-04-09

    申请号:DE3868731

    申请日:1988-05-25

    Applicant: DEGUSSA

    Abstract: Prodn. of HCN under the conditions of the 'HCN-CH4-NH3' process, involves reacting 1-4 C aliphatic hydrocarbons (I) with NH3 in the presence of a catalyst (II). The novel features are that : (a) reaction is carried out initially with a catalyst precursor (IIA), consisting of alumina mouldings with Al ions and very small amts. of noble metal, pref. Pt ions applied to the surface from soln.; (b) (IIA) is dried and reduced with H2 before use; (c) (IIA) is placed in the HCN reactor, which is heated to 1000-1350 deg.C and charged with the usual mixt. of NH3 and (I) for this reaction, which is initiated by (IIA); and (d) after a short time, reaction is continued with the Al nitride film formed in situ on the surface of (IIA). Pref. (I) is CH4. (II) is a pref. tubular moulding prepd. from alpha-alumina by impregnation with H2PtCl6 soln. (pref. contg. 0.5-5 wt.% Pt ions) and an AlCl3, Al(NO3)3 or Al2(SO4)3 soln., pref. using a noble metal (Pt):Al molar ratio of 0.001-0.1:1, esp. 0.01-0.1:1.

Patent Agency Ranking