Abstract:
PROBLEM TO BE SOLVED: To provide a silicone composition for preparing a silicone adhesive having an excellent electroconductivity, in particular.SOLUTION: The prepared composition comprises: an organopolysiloxane including, on the average per molecule, at least two silicon-bonded alkenyl groups; an organohydrodiene polysiloxane including, on the average per molecule, at least two silicon-bonded hydrogen atoms at a concentration sufficient for curing the provided composition; an electroconductive filler at a quantitative ratio sufficient for conferring electroconductivity onto the silicone adhesive (the filler includes particles having outer surfaces constituted by a metal selected from the group consisting of silver, gold, platinum, palladium, and their alloys); an effective quantity of a hydroxy-functional organic compound having an upper limit molecular weight of 1000 and including at least one hydroxyl group per molecule, assuming that the compound in question includes no acetylenic hydroxyl groups and that the compound in question does not substantially hinder the curing of the composition; and a catalytic quantitative ratio of a hydrosilylation catalyst.
Abstract:
PROBLEM TO BE SOLVED: To provide a silicone composition having excellent characteristics. SOLUTION: This silicone composition comprises (A) an organopolysiloxane containing at least average 2 silicon-bound alkenyl groups per molecule, (B) an organohydrogenpolysiloxane containing at least average 2 silicon-bound hydrogen atoms per molecule at a concentration sufficient to cure the composition, (C) an effective amount of a transition metal compound and (D) a catalytic amount of a hydrosilylating catalyst.
Abstract:
PROBLEM TO BE SOLVED: To obtain a silicone composition having excellent properties. SOLUTION: The silicone composition is produced by blending together (A) 100 pts.mass of an organopolysiloxane, (B) an organohydrogenpolysiloxane with a concentration enough to cure the composition, (C) 0.5-50 pt(s).mass of a hydroxyfunctional organic compound, (D) 1-10 pt(s).mass of a titanium chelate compound and (E) a catalytic amount of a hydrosilylation catalyst.
Abstract:
PROBLEM TO BE SOLVED: To provide a silicone composition containing a conductive filler and a hydroxyl-functional organic compound. SOLUTION: This silicone composition, for preparing a cured silicone product, is prepared by mixing (A) an organopolysiloxane having, on average, at least two epoxy-functional organic groups per molecule, (B) a curing agent containing no phenolic hydroxyl group, in an amount enough to cure the composition, (C) a conductive filler containing particles having the surface coated with a metal selected from among silver, gold, platinum, palladium, and their alloys, in an amount enough to impart electric conductivity to the composition, and (D) an effective amount of a hydroxyl-functional organic compound having a mol.wt. of 1,000 or lower and at least one hydroxyl group per molecule (provided this compound does not substantially inhibit the curing of the composition).
Abstract:
PROBLEM TO BE SOLVED: To obtain a sticky polyolefin composition having improved adhesivity to various substrates by adding a specific adhesion accelerator to a polyolefin containing a curing agent. SOLUTION: This sticky polyolefin composition comprises (A) a polyolefin having at least two ethylenic unsaturated substituents capable of curing the polyolefin and (B) an adhesion accelerator comprising (i) an epoxide-containing compound (preferably 3-glycosidoxypropyltrimethoxysilane, etc.), selected from organic compounds and organic silicon compounds and (ii) a compound (preferably dihydrocarveol) having a substituent selected from a silanol (=SiOH), a hydrolyzable silanol precursor and a carbinol (=COH) and a substituent capable of reacting during the curing of the component A. The component B is added in a content of 1.5-7.5 wt.% based on the total weight of the composition. The component i is used in an amount of 10-90 wt.% based on the total amount of the components i and ii.
Abstract:
PROBLEM TO BE SOLVED: To provide an electrically conductive silicone composition the cured material of which is suitable for use as an adhesive for an electronic device and has low volume resistivity and/or rubber elasticity. SOLUTION: This electrically conductive silicone composition comprises an organopolysiloxane having two or more alkenyl groups per molecule, an organohydrogen polysiloxane having two or more silicon-bonded hydrogen atoms per molecule, a catalyst containing a platinum group metal, a finely-divided electrically conductive metal particle, a pre-crosslinked elastomeric silicone particle and a non-reactive volatile diluent. The electrically conductive silicone composition can be used for an electrically conductive adhesive or a coating applied to an electrical or electronic device. The cured electrically conductive silicone composition has a high electrical conductivity and rubber elasticity.
Abstract:
PROBLEM TO BE SOLVED: To obtain a silicone composition for preparing a silicone adhesive having excellent electric conductivity particularly. SOLUTION: In this invention, the objective composition comprises an organopolysiloxane bearing at least two alkenyl groups bonding to every silicon molecule on the average; an organohydrogenpolysiloxane bearing at least two hydrogen atoms bonding to every silicon molecule on the average in a concentration sufficient for curing the composition; an electroconductive filler (for example, including particles having at least the outer surfaces covered with a metal selected from silver, gold, platinum, palladium or their alloys) in an amount enough to impart the electric conductivity to the above silicone adhesive; an effective amount of a hydroxy-functional organic compound that has a molecular weight of 1,000 at maximum and bears at least one hydroxy group every molecule where the organic compound does not include an acetylenic hydroxy group and substantially does not inhibit the composition from being hardened; and a catalytic amount of a hydrosilylation catalyst.
Abstract:
PROBLEM TO BE SOLVED: To improve the electrical conductivity of a curable silicone composition for preparing silicone adhesives. SOLUTION: The silicone composition is prepared by mixing a catalytic amount of a condensation catalyst containing (A) an organopolysiloxane containing at least two silicon-bound hydroxyl groups per molecule on average, (B) a crosslinking agent comprising at least one silane of the formula: R2nSiX4-n (R2 is a 1-8C monovalent hydrocarbon or a monovalent hydrocarbon halide group; n is 0 or 1; and X is -OR2 or -OCH2CH2OR2) or its partial hydrolysate, (C) an electrically conductive filler containing a particle of which at least the outer surface comprises silver, gold, platinum, palladium or their alloys, (D) a hydroxyl-functional organic compound having a molecular weight of
Abstract:
PROBLEM TO BE SOLVED: To obtain a poluolefin composition capable of exhibiting storing binding forces to various substrates by mixing a polyolefin with a specific organic silicon compound as an adhesive-accelerating agent. SOLUTION: This polyolefin composition comprises (A) at least one polyolefin which contains repeating units derived from at least one olefin and functional groups capable of cross-linking the polyolefin, and (B) an effective amount of an adhesive-accelerating agent. The component B is the reaction product of a polyhydric alcohol of formula I [R1 is a m-valiant hydrocarbon containing no ethylenic unsaturated group or the like; and (m) is an integer of at least 2] with a silane of formula II [R2 is a non-substituted hydrocarbon or the like; (n) is 0 or 1; and X is a hydrolyzable group] or a bissilylalkane of formula III (R3 is an alkylene). The composition shows adhesivity to inorganic and organic substrates.
Abstract:
PROBLEM TO BE SOLVED: To obtain a conductive silicone adhesive having superior electric characteristics. SOLUTION: The silicone composition contains (A) a polydiorganosiloxane of 10 to 50 pts.mass; (B) an organopolysiloxane resin of 50 to 90 pts.mass constituting of R 3 SiO1/2 siloxane unit and SiO4/2 siloxane unit; (C) an organo hydrodienepolysiloxane having silicon bound hydrogen atom of at least average two per one molecule with a sufficient quantity to curing the composition; (D) a conductive filler of a sufficient quantity to give conductivity to the composition and (E) a hydrosilyl catalyst of a catalytic quantity.