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    Silicone polyether surfactant
    1.
    发明专利
    Silicone polyether surfactant 审中-公开
    硅胶聚合物表面活性剂

    公开(公告)号：JP2006283039A

    公开(公告)日：2006-10-19

    申请号：JP2006203655

    申请日：2006-07-26

    Applicant: Dow Corning Corp ,  ダウ・コ−ニング・コ−ポレ−ションDow Corning Corporation

    Inventor： STANGA MICHAEL ALLEN ,  STEVENS ROBERT EDWARD ,  WIESE KEVIN DALE ,  RAUSCHER WANDA WELLS ,  WHITMARSH ROBERT H ,  COBB VICKY SUE

    IPC: C08G77/46 ,  C08L83/12 ,  C08G18/48

    CPC classification number: C08G77/46 ,  C08G18/4837 ,  C08G2101/0008 ,  C08G2101/0083 ,  Y10S516/906

    Abstract: PROBLEM TO BE SOLVED: To provide a surfactant for stabilizing polyurethane foams.
    SOLUTION: This surfactant comprises a siloxane-oxyalkylene copolymer and has the formula, MD
    x D'
    y M [wherein M represents (CH
    3 )
    3 SiO
    1/2 or R(CH
    3 )
    2 SiO
    1/2 ; D represents (CH
    3 )
    2 SiO
    2/2 ; D' represents (CH
    3 )RSiO
    2/2 ; the value of (x+y) is 48-220, and the ratio x/y is from 5 to 15; in the above formulae for M and D', R is a polyether-containing substituent selected from the group consisting of (1) -C
    n H
    2n O(C
    2 H
    4 O)
    a (C
    3 H
    6 O)
    b R' having a weight average molecular weight of 2,300-3,400 and (2) -C
    m H
    2m O(C
    2 H
    4 O)
    c (C
    3 H
    6 O)
    d R' having the weight average molecular weight of 750-1,400, and n, m, a, b, c, d and R' are as explained in the present specification; the blend average molecular weight of the overall R in the composition is from 1,500 to 2,200; and the overall EO/PO molar ratio is from 0.65 to 1.2].
    COPYRIGHT: (C)2007,JPO&INPIT

    Abstract translation: 要解决的问题：提供用于稳定聚氨酯泡沫的表面活性剂。 解决方案：该表面活性剂包含硅氧烷 - 氧化烯共聚物，具有下式：其中M表示（CH 3 SB>） 3 SiO 1/2 或R（CH 3 ）SB < ; D表示（CH 3 SB 3）SB 2 SiO 2 SB 2/2 / SB。 D'表示（CH 3 ）RSiO 2/2 ; （x + y）的值为48-220，x / y为5〜15; 在上述M和D'的式中，R是含有取代基的取代基，选自（1）-C（S）-C（S） > 2 ħ 4 O）一（C 3 ħ 6 O） b 重均分子量为2300-3,400和（2）-C H 2m O（C 2 ħ 4 O） C （C 3 ħ 6 O）ð R” 重均分子量为750-1,400，n，m，a，b，c，d和R'如本说明书所述; 组合物中总体R的共混物平均分子量为1500-2200; 并且总EO / PO摩尔比为0.65-1.2]。 版权所有（C）2007，JPO＆INPIT

    HIGH-PURITY OXYALKYLENE-MODIFIED ORGANOPOLYSILOXANE
    2.
    发明专利
    HIGH-PURITY OXYALKYLENE-MODIFIED ORGANOPOLYSILOXANE 失效

    公开(公告)号：JP2000128992A

    公开(公告)日：2000-05-09

    申请号：JP29975099

    申请日：1999-10-21

    Applicant: DOW CORNING

    Inventor： PETROFF LENIN JAMES ,  STANGA MICHAEL ALLEN ,  RAUSCHER WANDA WELLS ,  WHITMARSH ROBERT H ,  HUPFIELD PETER CHESHIRE

    IPC: C08L83/05 ,  C08G77/06 ,  C08G77/42 ,  C08G77/46 ,  C08L83/12

    Abstract: PROBLEM TO BE SOLVED: To obtain the subject compound free from offensive odor and an excess of polyoxyalkylene compounds by reaction of a mixture comprising a specific vinyloxypolyoxyalkylene compound, organohydrogensiloxane compound and platinum metal-contg. catalyst. SOLUTION: This compound is obtained by reaction of a mixture comprising (A) a vinyloxypolyoxyalkylene compound selected from those of the formulas: CH2=CHOR(OC2H4)aOR1, CH2=CHOR(OC3H6)bOR1, CH2=CHOR(OC4H8)cOR1, CH2=CHOR(OC2H4)a(OC3H6)b(OC4H8)cOR1, CH2=CHOR(OC2H4)a(OC3H6)bOR1, CH2=CHOR(OC2H4)a(OC4H8)cOR1 and the like (R is an alkylene having at least two carbon atoms; R1 is H, an alkyl or the like; (a), (b) and (c) are each 1-150), (B) an organohydrogensiloxane compound [e.g. bis(trimethylsiloxy) dimethyldisiloxane], and (C) a platinum metal-contg. catalyst.

    SILICONE GEL COMPOSITION AND PRODUCED SILICONE GEL
    3.
    发明专利
    SILICONE GEL COMPOSITION AND PRODUCED SILICONE GEL 失效

    公开(公告)号：JP2000309711A

    公开(公告)日：2000-11-07

    申请号：JP2000003879

    申请日：2000-01-12

    Applicant: DOW CORNING

    Inventor： ALVAREZ KHRISTOPHER EDWARD ,  BERRY PAUL ANTHONY ,  STANGA MICHAEL ALLEN ,  STRONG MICHAEL R

    IPC: C08L83/07 ,  C08L83/04 ,  C08L83/05

    Abstract: PROBLEM TO BE SOLVED: To provide a silicone gel composition having excellent tack. SOLUTION: The composition contains (A) 100 pts.wt. polydiorganosiloxane containing at least two alkenyl groups on average bonded to a silicon atom in the molecule and having a viscosity at 25 deg.C of 0.2-10 Pa.sec; (B) at least 0.5 pt.wt. polydiorganosiloxane containing at least two alkenyl groups on average bonded to a silicon atom in the molecule and having a viscosity (at 25 deg.C) at least 4 times that of component A; (C) an organohydrogensiloxane represented by the formula: R7Si(OSiR82H)3 (wherei n R7 is aryl or a 1-18C alkyl; and R8 is alkyl), in an amount sufficient to provide 0.1-1.5 hydrogen atoms bonded to a silicon atom for total alkenyl groups of component A and component B; and (D) a hydrosilylation catalyst in an amount sufficient to cure the composition.

    4.
    发明专利
    未知

    公开(公告)号：DE60001676T2

    公开(公告)日：2003-12-18

    申请号：DE60001676

    申请日：2000-01-11

    Applicant: DOW CORNING

    Inventor： ALVAREZ KHRISTOPHER EDWARD ,  BERRY PAUL ANTHONY ,  STANGA MICHAEL ALLEN ,  STRONG MICHAEL RAYMOND

    IPC: C08L83/07 ,  C08L83/04 ,  C08L83/05

    Abstract: A silicone gel composition, (A) 100 parts by weight of a first polydiorganosiloxane containing an average of at least two silicon-bonded alkenyl groups per molecule and having a viscosity of from 0.2 to 10 Pa.s at 25 DEG C.; (B) at least 0.5 part by weight of a second polydiorgano-siloxane containing an average of at least two silicon-bonded alkenyl groups per molecule, wherein the second polydiorganosiloxane has a viscosity at 25 DEG C. of at least four times the viscosity of the first polydiorgano-siloxane at 25 DEG C.; (C) an organohydrogensiloxane having the average formula R Si(OSiR 2H)3 wherein R is an alkyl group having 1 to 18 carbon atoms or aryl, R is an alkyl group having 1 to 4 carbon atoms, in an amount to provide from 0.1 to 1.5 silicon-bonded hydrogen atoms per alkenyl group in components (A) and (B) combined; and (D) a hydrosilylation catalyst in an amount sufficient to cure the composition. A silicone gel comprising a reaction product of the silicone gel composition. A kit for preparing a silicone gel composition.

    7.
    发明专利
    未知

    公开(公告)号：DE69925792D1

    公开(公告)日：2005-07-21

    申请号：DE69925792

    申请日：1999-10-20

    Applicant: DOW CORNING

    Inventor： PETROFF LENIN JAMES ,  STANGA MICHAEL ALLEN ,  RAUSCHER WANDA WELLS ,  WHITMARSH ROBERT H ,  UPFIELD PETER CHESHIRE

    IPC: C08L83/05 ,  C08G77/06 ,  C08G77/42 ,  C08G77/46 ,  C08L83/12

    Abstract: This invention relates to a method of making high purity oxyalkylene-modified organopolysiloxanes comprising reacting a mixture comprising a vinyloxy polyoxyalkylene compound, an organohydrogensiloxane compound and a platinum group metal-containing catalyst. The resulting oxyalkylene-modified organopolysiloxanes are free from unwanted odor and do not contain excess polyoxyalkylene compound since the vinyloxy polyoxyalkylene compounds are not prone to isomerization during the reaction. The oxyalkylene-modified organopolysiloxanes of this invention are particularly useful in hair care formulations, skin care formulations, cosmetics, silicone emulsions and in polyurethane foams.

    8.
    发明专利
    未知

    公开(公告)号：BR9606155A

    公开(公告)日：1998-09-01

    申请号：BR9606155

    申请日：1996-12-23

    Applicant: DOW CORNING

    Inventor： WHITMARSH ROBERT H ,  RAUSCHER WANDA WELLS ,  WIESE KEVIN DALE ,  STEVENS ROBERT EDWARD ,  STANGA MICHAEL ALLEN ,  COBB VICKY SUE

    IPC: C08G18/48 ,  C08G77/46 ,  C08J9/00 ,  C08G18/28 ,  C08G18/61

    Abstract: A siloxane-oxyalkylene copolymer surfactant having the generalized average formula MDxD0yM wherein M represents (CH3)3SiO1/2 or R(CH3)2SiO1/2; D represents (CH3)2SiO2/2; D' represents (CH3)RsiO2/2; and x + y is between 48 and 220, and the ratio x/y is from 5 to 15 inclusive. In the above formulae for M and D', is a polyether containing substituent derived from a CnH2n -initiated polyether and is selected from the group consisting of: (1) -CnH2nO(C2H4O)a(C3H6O)bR' moieties having weight average molecular weights in the range 2300 - 3400 and wherein n is 3-4; the ratio a/b us from 0.5 to 1.3 inclusive; R' represents hydrogen, an alkyl group 1-4 carbon atoms or -C(O)CH3; and (2) -Cn'H2n'O(C2H4O)a'(C3H6O)b'R' moieties having weight average molecular weights in the range750 - 1400 and wherein n' is 3-4; a' is a number such that the ethylene oxide residues constitute 30-100 percent by weight of the alkylene oxide residues of the polyether; b' is a number suchtaht the propylene oxide residues constitute 0-70 percent by weight of the alkylene oxide residues of the polyether; R' represents hydrogen, an alkyl group of 1-4 carbon atoms or-C(O)CH3; and the blend average molecular weight of the overall CnH2n - initiated polyethers is in the range from 1600 to 2400 and the overall EO/P ratio ranges from 0.8 to 1.2. Such siloxane-oxyalkylene copolymer surfactants are useful in the manufacture if flexible polyurethane slabstock foams.

    10.
    发明专利
    未知

    公开(公告)号：DE69626368T2

    公开(公告)日：2003-10-16

    申请号：DE69626368

    申请日：1996-12-20

    Applicant: DOW CORNING

    Inventor： STANGA MICHAEL ALLEN ,  RAUSCHER WANDA WELLS ,  STEVENS ROBERT EDWART ,  WHITMARSH ROBERT H ,  WIESE KEVIN DALE ,  COBB VICKY SUE

    IPC: C08G18/48 ,  C08G77/46 ,  C08J9/00 ,  C08L83/12 ,  C09K23/00

    Abstract: There is disclosed herein a siloxane-oxyalkylene copolymer surfactant having the formula MDxD'yM wherein M represents (CH3)3SiO1/2 or R(CH3)2SiO1/2, D represents (CH3)2SiO2/2, D' represents (CH3)RSiO2/2, and the value of x+y is from 48 and 220, and the ratio x/y is from 5 to 15 inclusive. In the above formulae for M and D', R is a polyether-containing substituent selected from the group consisting of (1) -CnH2nO(C2H4O)a(C3H6O)bR' moieties having weight average molecular weights in the range 2300-3400 and wherein n is 3-4, the ratio a/b is from 0.5 to 1.3 inclusive, R' represents hydrogen, an alkyl group of 1-4 carbon atoms or -C(O)CH3 and (2) -Cn'H2n'O(C2H4O)a'(C3H6O)b'R' moieties having weight average molecular weights in the range 750-1400 and wherein n' is 3-4, a' is a number such that the ethylene oxide residues constitute 30-100% by weight of the alkylene oxide residues of the polyether, b' is a number such that the propylene oxide residues constitute 0-70% by weight of the alkylene oxide residues of the polyether, R' represents hydrogen, an alkyl group of 1-4 carbon atoms or -C(O)CH3, and the blend average molecular weight of the overall polyether-containing substituents R in the compositions is in the range from 1500 to 2200 and the overall EO/PO molar ratio ranges from 0.65 to 1.2. The surfactants are useful in producing flexible polyurethane slabstock foams.

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