Abstract:
A fire retardant article has a wood-based material with a polyisocyanurate foam article attached thereto, where the polyisocyanurate foam article covers 90% or more of the exposed portion of the wood-based material, has a thickness greater than 1.8 centimeters, a foam core having a density of 28-128 kg/m 3 , a trimer concentration characterized by at least one of (i) a trimer level in a range of 12-25 weight-percent and (ii) a molar ratio of trimer to sum of urethane and urea in a range of 1-8, a phosphorous concentration of at least 0.3 wt%, a combined concentration of phosphorous and bromine of at least 0.5 wt%, and a vapor permeable and non-combustible facer on at least one primary surface of the foam core.
Abstract:
A formulation system contains: (a) a pre-polymer reaction product of a polymeric isocyanate and a polyether polyol, where: (i) the polymeric isocyanate contains five weight-percent or more methylene diphenyl diisocyanate; (ii) the polymeric isocyanate has a functionality of 3.0 or less; (iii) the polyether polyol is present in the pre-polymer at a concentration of one to 25 weight-percent; (iv) the polyol has an equivalent weight of 50 to 500 grams per equivalent; (v) the -NCO concentration of the pre-polymer is 15 to 31 weight-percent; (vi) the pre-polymer is free of isocyanate trimers; (b) a polyester polyol component containing 10 to 25 weight-percent of free glycol; and (c) a blowing agent that contains less than five weight-percent water; where the ratio of pre-polymer and polyester result in foam having a trimer content of 12 to 22 weight-percent, and an -NCO index of more than 300 and less than 700.
Abstract:
A one component spray polyurethane foam formulation containing a polymeric isocyanate with nominal functionality of 2.5 to 3.5, a polyol component that is at least 85 percent aliphatic and having a mole ratio of polyol with three or more functionality to total polyol of 0.2 to 0.75, 15-30 wt% of a plasticizer, 1.5-3.5 wt% phosphorous, 5.5 to 11.5 halogen and 1.5 to 5 millimoles of blowing agent per gram of formulation and that is free of expandable graphite achieves a B2 rating in DIN 4102 testing.
Abstract:
A formulation system contains: (a) a pre-polymer reaction product of a polymeric isocyanate and a polyether polyol, where: (i) the polymeric isocyanate contains five weight-percent or more methylene diphenyl diisocyanate; (ii) the polymeric isocyanate has a functionality of 3.0 or less; (iii) the polyether polyol is present in the pre-polymer at a concentration of one to 25 weight-percent; (iv) the polyol has an equivalent weight of 50 to 500 grams per equivalent; (v) the —NCO concentration of the pre-polymer is 15 to 31 weight-percent; (vi) the pre-polymer is free of isocyanate trimers; (b) a polyester polyol component containing 10 to 25 weight-percent of free glycol; and (c) a blowing agent that contains less than five weight-percent water; where the ratio of pre-polymer and polyester result in foam having a trimer content of 12 to 22 weight-percent, and an —NCO index of more than 300 and less than 700.
Abstract:
A one component spray polyurethane foam formulation containing a polymeric isocyanate with nominal functionality of 2.5 to 3.5, a polyol component that is at least 85 percent aliphatic and having a mole ratio of polyol with three or more functionality to total polyol of 0.2 to 0.75, 15-30 wt % of a plasticizer, 1.5-3.5 wt % phosphorous, 5.5 to 11.5 halogen and 1.5 to 5 millimoles of blowing agent per gram of formulation and that is free of expandable graphite achieves a B2 rating in DIN 4102 testing.
Abstract:
A one component spray polyurethane foam formulation containing a polymeric isocyanate with nominal functionality of 2.5 to 3.5, a polyol component that is at least 85 percent aliphatic and having a mole ratio of polyol with three or more functionality to total polyol of 0.2 to 0.75, 15-30 wt % of a plasticizer, 1.5-3.5 wt % phosphorous, 5.5 to 11.5 halogen and 1.5 to 5 millimoles of blowing agent per gram of formulation and that is free of expandable graphite achieves a B2 rating in DIN 4102 testing.