公开(公告)号：JP2012082424A

公开(公告)日：2012-04-26

申请号：JP2011252527

申请日：2011-11-18

Applicant: Dow Global Technologies Llc ,  ダウ グローバル テクノロジーズ エルエルシー

Inventor： ARRIOLA DANIEL J ,  CARNAHAN EDMUND M ,  CHEUNG YUNWA W ,  DEVORE DAVID D ,  GRAF DAVID D ,  HUSTAD PHILLIP D ,  KUHLMAN ROGER L ,  LI PI SHAN COLIN ,  POON BENJAMIN C ,  ROOF GORDON R ,  STEVENS JAMES C ,  STIRN PAMELA J ,  WENZEL TIMOTHY T

IPC: C08F4/659 ,  C08F2/38 ,  C08F4/6592 ,  C08F10/00 ,  C08F110/02 ,  C08F210/02 ,  C08F210/16 ,  C08F295/00 ,  C08F297/08

CPC classification number: C08F10/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65925 ,  C08F4/65927 ,  C08F110/02 ,  C08F210/16 ,  C08F297/08 ,  C08F2420/02 ,  C08L23/06 ,  C08L23/0815 ,  C08L23/0853 ,  Y02P20/52 ,  Y10T428/24942 ,  Y10T428/24992 ,  Y10T428/2826 ,  Y10T428/31573 ,  Y10T428/31587 ,  C08F2/38 ,  C08F4/65904 ,  C08L2666/06 ,  C08F2500/09 ,  C08F2500/03 ,  C08F210/14 ,  C08F2500/08 ,  C08F4/64048 ,  C08F4/6411 ,  C08F4/64193 ,  C08F4/64113 ,  C08F4/64144 ,  C08F4/64148

Abstract: PROBLEM TO BE SOLVED: To provide a catalyst composition for use in forming a multi-block copolymer, the copolymer containing therein two or more segments or blocks differing in chemical or physical properties, and to provide a polymerization process using the same.SOLUTION: The composition comprises the admixture or reaction product resulting from combining: (A) a first olefin polymerization catalyst; (B) a second olefin polymerization catalyst capable of preparing polymers differing in chemical or physical properties from the polymer prepared by catalyst (A) under equivalent polymerization conditions; and (C) a chain shuttling agent.

Abstract translation: 要解决的问题：为了提供用于形成多嵌段共聚物的催化剂组合物，该共聚物中含有两个或更多个化学或物理性质不同的链段或嵌段，并提供使用其的聚合方法。 组合物包含由以下组合得到的混合物或反应产物：（A）第一种烯烃聚合催化剂; （B）能够在等效的聚合条件下制备由催化剂（A）制备的聚合物在化学或物理性质上不同的聚合物的第二种烯烃聚合催化剂; 和（C）链式穿梭剂。 版权所有（C）2012，JPO＆INPIT

公开(公告)号：JP2014111770A

公开(公告)日：2014-06-19

申请号：JP2013265463

申请日：2013-12-24

Applicant: Dow Global Technologies Llc ,  ダウ グローバル テクノロジーズ エルエルシー

Inventor： ARRIOLA DANIEL J ,  MARILYN BOKOTA ,  EDMUND M CARNAHAN ,  PHILLIP D HUSTAD ,  KUHLMAN ROGER L ,  STIRN PAMELA J ,  TIMOTHY T WENZEL

IPC: C08F110/02 ,  C08F2/00 ,  C08F4/646 ,  C08F110/04

CPC classification number: C08F10/00 ,  C08F4/659 ,  C08F4/65908 ,  C08F4/6592 ,  C08F4/65927 ,  C08F210/06 ,  C08F210/16 ,  C08F297/06 ,  C08F297/08 ,  C08F297/083 ,  C08F2410/01 ,  C08L23/10 ,  C08L23/16 ,  C08L2308/00 ,  C08F4/65912 ,  C08F4/6465 ,  C08F2/38 ,  C08L2666/06 ,  C08F2500/17 ,  C08F2500/08 ,  C08F2500/20 ,  C08F2500/03 ,  C08F4/64048 ,  C08F4/64193 ,  C08F4/64144

Abstract: PROBLEM TO BE SOLVED: To produce a block copolymer catalytically, namely by a method for producing two or more polymer molecules per molecule of a concomitantly used catalyst or initiator.SOLUTION: The provided method is a method for forming a copolymer including multiple regions or segments having differentiated polymer compositions or characteristics by polymerizing at least one type of addition-polymerizable monomer and comprises a step of contacting the addition-polymerizable monomer or a mixture of the corresponding monomers with a composition including at least one type of olefin polymerization catalyst, a cocatalyst, and a reversible chain shuttling agent under addition polymerization conditions so as to form at least several growable polymer chains in a state where two or more blocks or segments formed within at least several of the produced polymers can be chemically or physically discriminated under differentiated process conditions.

Abstract translation: 要解决的问题：催化地制备嵌段共聚物，即通过每分子同时使用的催化剂或引发剂生产两种或更多种聚合物分子的方法。提供的方法是形成共聚物的方法，其包括多个区域或片段 通过聚合至少一种类型的可加成聚合单体而具有差异的聚合物组合物或特性，并且包括使可加成聚合单体或相应单体的混合物与包含至少一种类型的烯烃聚合催化剂，助催化剂 和可逆链穿梭剂在加成聚合条件下形成至少几种可生长的聚合物链，其状态是在至少几种所生产的聚合物内形成的两个或多个嵌段或链段可以在不同的工艺条件下化学或物理地鉴别 。

公开(公告)号：JP2014065920A

公开(公告)日：2014-04-17

申请号：JP2013259896

申请日：2013-12-17

Applicant: Dow Global Technologies Llc ,  ダウ グローバル テクノロジーズ エルエルシー

Inventor： ARRIOLA DANIEL J ,  CARNAHAN EDMUND M ,  CHEUNG YUNWA W ,  DEVORE DAVID D ,  GRAF DAVID D ,  HUSTAD PHILLIP D ,  KUHLMAN ROGER L ,  LI PI SHAN COLIN ,  POON BENJAMIN C ,  ROOF GORDON R ,  STEVENS JAMES C ,  STIRN PAMELA J ,  WENZEL TIMOTHY T

IPC: C08F4/612 ,  C08F2/38 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F110/02 ,  C08F210/16 ,  C08F297/06 ,  C08F297/08

CPC classification number: C08F10/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65925 ,  C08F4/65927 ,  C08F110/02 ,  C08F210/16 ,  C08F297/08 ,  C08F2420/02 ,  C08L23/06 ,  C08L23/0815 ,  C08L23/0853 ,  Y02P20/52 ,  Y10T428/24942 ,  Y10T428/24992 ,  Y10T428/2826 ,  Y10T428/31573 ,  Y10T428/31587 ,  C08F2/38 ,  C08F4/65904 ,  C08L2666/06 ,  C08F2500/09 ,  C08F2500/03 ,  C08F210/14 ,  C08F2500/08 ,  C08F4/64048 ,  C08F4/6411 ,  C08F4/64193 ,  C08F4/64113 ,  C08F4/64144 ,  C08F4/64148

Abstract: PROBLEM TO BE SOLVED: To provide: a composition for use in forming a multi-block copolymer produced in a continuous process without the need for sequential monomer addition, the copolymer containing two or more segments or blocks differing in chemical or physical properties; and a polymerization process using the same.SOLUTION: Provided are: an admixture or reaction product resulting from combining (A) a first olefin polymerization catalyst, (B) a second olefin polymerization catalyst capable of preparing polymers differing in chemical or physical properties from the polymer prepared by the catalyst (A) under equivalent polymerization conditions, and (C) a chain shuttling agent; and a polymerization process using the same.

Abstract translation: 要解决的问题：提供：用于形成连续方法制备的多嵌段共聚物而不需要顺序单体添加的组合物，所述共聚物含有两个或更多个化学或物理性质不同的链段或嵌段; 和（A）第一烯烃聚合催化剂，（B）第二种烯烃聚合催化剂，其能够制备具有不同化学或物理性质的聚合物的第二种烯烃聚合催化剂 在等同的聚合条件下由催化剂（A）制备的聚合物，和（C）链穿梭剂; 和使用其的聚合方法。

公开(公告)号：ES2430551T3

公开(公告)日：2013-11-21

申请号：ES06734048

申请日：2006-01-30

Applicant: DOW GLOBAL TECHNOLOGIES INC DOW GLOBAL TECHNOLOGIES LLC

Inventor： ARRIOLA DANIEL J ,  BOKOTA MARILYN ,  CARNAHAN EDMUND M ,  HUSTAD PHILLIP D ,  KUHLMAN ROGER L ,  STIRN PAMELA J ,  WENZEL TIMOTHY T

IPC: C08F297/08 ,  C08F2/38 ,  C08F4/646

Abstract: Un procedimiento continuo para la polimerización de uno o más monómeros polimerizables por adición paraformar un copolímero que comprende múltiples regiones o segmentos que tienen composiciones o propiedades depolímero distinguibles, comprendiendo dicho procedimiento poner en contacto un monómero polimerizable poradición o una mezcla de monómeros bajo condiciones de polimerización por adición con una composición quecomprende un catalizador de polimerización de olefinas sencillo, un cocatalizador y un agente de desplazamiento decadenas, estando dicho procedimiento caracterizado por la formación de al menos algunas de las cadenas depolímero en crecimiento bajo condiciones de procedimiento diferenciadas de manera que dos o más bloques osegmentos formados dentro de al menos algo del polímero resultante, son química o físicamente distinguibles.

公开(公告)号：HK1115891A1

公开(公告)日：2008-12-12

申请号：HK08106179

申请日：2008-06-03

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： ARRIOLA DANIEL J ,  BOKOTA MARILYN ,  CARNAHAN EDMUND M ,  HUSTAD PHILLIP D ,  KUHLMAN ROGER L ,  STIRN PAMELA J ,  WENZEL TIMOTHY T

IPC: C08F20060101

Abstract: A process for the polymerization of one or more addition polymerizable monomers to form a copolymer comprising multiple regions or segments of differentiated polymer composition or properties comprising contacting an addition polymerizable monomer or mixture of monomers under addition polymerization conditions with a composition comprising at least one olefin polymerization catalyst, a cocatalyst and a chain shuttling agent, said process being characterized by formation of at least some of the growing polymer chains under differentiated process conditions such that two or more blocks or segments formed within at least some of the resulting polymer are chemically or physically distinguishable.