Abstract:
An apparatus and method for determining an approximation to a measure of the volatility of fuel on-board a vehicle having an internal combustion engine. The method includes the steps of measuring at least one characteristic of the fuel (14) corresponding to a temperature of the fuel, a volume of the fuel, and a concentration of oxygenates within the fuel; determining an approximation of the a measure of the volatility of the sample volume of fuel (18, 20, 22, 24, 26, 28, 30) using a linear function based on the at least one measured characteristic of the fuel corresponding to temperature, volume, and concentration of oxygenates of the fuel. Preferably, at least one temperature measurement is associated with a predetermined volume of the sample as the sample is evaluated. The method can include determining whether a fuel contains ethanol (18), and if not, whether the fuel is a winter blend of fuel (26) or a summer blend of fuel (30). The method to determine whether ethanol is present can include the steps of bringing the fuel into contact with a sensing element (18A); measuring a characteristic of the fuel corresponding to concentration of oxygenates (18B), such as the change in capacitance or resistance of the sensing element; and calculating the dielectric constant or the conductivity of the sample respectively (18C). The method to determine the type of non-ethanol containing fuel can be based on two temperature measurements taken at two predetermined volumes during the evaporation process (16, 18, 22, 24, 26, 28).
Abstract:
An SOFC structure having segmentation of the mixed layer on a cathode electrode to allow a higher fraction of ionic phase in a mixed layer, resulting in improved microstructure that provides higher specific surface area for electrochemical reaction. This is accomplished by using a mixed ionic and electronic conductor (MIEC) layer (14) over the segmented layer (116) that supplies electrons laterally and vertically through the thickness of the mixed layer. Adequate connectivity between the cathode current collector (130) and electrolyte (20) for electrons is established, assuring efficient charge transfer and improved activity of the electrocatalyst in the porous cathode. Cell resistance is reduced and power output is improved. Further, the invention can efficiently incorporate a variety of functional layers on the anode electrode to improve protection from poisons and certain fuel mixtures that degrade cell performance, and can reduce stresses between fuel cell components while maintaining adequate connectivity with the anode current collector and electrolyte via an Ni-YSZ anode.
Abstract:
An SOFC structure having segmentation of the mixed layer on a cathode electrode to allow a higher fraction of ionic phase in a mixed layer, resulting in improved microstructure that provides higher specific surface area for electrochemical reaction. This is accomplished by using a mixed ionic and electronic conductor (MIEC) layer (14) over the segmented layer (116) that supplies electrons laterally and vertically through the thickness of the mixed layer. Adequate connectivity between the cathode current collector (130) and electrolyte (20) for electrons is established, assuring efficient charge transfer and improved activity of the electrocatalyst in the porous cathode. Cell resistance is reduced and power output is improved. Further, the invention can efficiently incorporate a variety of functional layers on the anode electrode to improve protection from poisons and certain fuel mixtures that degrade cell performance, and can reduce stresses between fuel cell components while maintaining adequate connectivity with the anode current collector and electrolyte via an Ni-YSZ anode.
Abstract:
Disclosed are an electrode (18), and a method of forming such an electrode, the electrode comprising an upper layer, a lower layer, with the potential for a plurality of compliant members (30) providing electrical communication between the upper layer and the lower layer. A surface of the upper layer may be in direct contact with a surface of the lower layer to provide a further electrical path between the upper layer and the lower layer.
Abstract:
Disclosed are an electrode (18), and a method of forming such an electrode, the electrode comprising an upper layer, a lower layer, with the potential for a plurality of compliant members (30) providing electrical communication between the upper layer and the lower layer. A surface of the upper layer may be in direct contact with a surface of the lower layer to provide a further electrical path between the upper layer and the lower layer.
Abstract:
An anode for use in an anode-supported planar solid oxide fuel cell (SOFC) is formed from a Ni-YSZ cermet composition that includes a sintering aid selected from the group consisting of an oxide, a carbonate, and mixtures thereof of at least one metal of Group 2 of the Periodic Table.
Abstract:
An apparatus and method for determining an approximation to a measure of the volatility of fuel on-board a vehicle having an internal combustion engine. The method includes the steps of measuring at least one characteristic of the fuel (14) corresponding to a temperature of the fuel, a volume of the fuel, and a concentration of oxygenates within the fuel; determining an approximation of the a measure of the volatility of the sample volume of fuel (18, 20, 22, 24, 26, 28, 30) using a linear function based on the at least one measured characteristic of the fuel corresponding to temperature, volume, and concentration of oxygenates of the fuel. Preferably, at least one temperature measurement is associated with a predetermined volume of the sample as the sample is evaluated. The method can include determining whether a fuel contains ethanol (18), and if not, whether the fuel is a winter blend of fuel (26) or a summer blend of fuel (30). The method to determine whether ethanol is present can include the steps of bringing the fuel into contact with a sensing element (18A); measuring a characteristic of the fuel corresponding to concentration of oxygenates (18B), such as the change in capacitance or resistance of the sensing element; and calculating the dielectric constant or the conductivity of the sample respectively (18C). The method to determine the type of non-ethanol containing fuel can be based on two temperature measurements taken at two predetermined volumes during the evaporation process (16, 18, 22, 24, 26, 28).