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公开(公告)号:DE59801737D1
公开(公告)日:2001-11-22
申请号:DE59801737
申请日:1998-03-27
Applicant: EMTEC MAGNETICS GMBH
Inventor: BAUER DR , BRONSTERT DR , BURKHARDT UWE , WEINGART DR , KESSLER THOMAS , MOEHWALD DR , HENNENBERGER FLORIAN
IPC: H01G9/025 , B29C47/00 , B29C47/10 , B32B27/00 , B32B27/18 , C08K3/10 , H01B1/12 , H01G9/028 , H01M2/16 , H01M4/02 , H01M4/04 , H01M4/58 , H01M10/40
Abstract: Production of moulded products, especially film includes the following stage (I): compounding and melt-extrusion of a mixture (I) containing 1-100 wt% of a mixture (II) comprising (a) 1-95 wt% pigment(s) (III) with a primary particle size of 5 nm to 20 microns, selected from an electrochemically inert solid (IIIa), a compound (IIIb) which is able to release lithium ions on charging, a compound (IIIc) which is able to take up Li ions on charging, and a mixture of (IIIa) with (IIIb) or (IIIc), (b) 5-99 wt% copolymer(s) (IV) of vinylidene fluoride (VDF) and hexafluoropropylene (HFP) with an HFP content of 8-25 wt% and (c) 1-200 wt% (based on a + b) of a plasticiser (V) selected from dibutyl, dimethyl or diethyl phthalate, tris-(butoxyethyl) phosphate, propylene or ethylene carbonate, trimethyl trimellitate, or a mixture of two or more of these. Also claimed are: (i) a process for the production of composite products comprising (I) forming first layer(s) by compounding and melt-extruding mixture (I) as above, (II) forming second layer(s) by compounding a mixture (I) containing a mixture (II) which contains a solid (IIIa) but not (IIIb) or (IIIc), and then (III) combining these layers by a conventional coating process; (ii) moulded products, especially film, obtained by process stage I; (iii) composite products obtained by the complete process as in (i); (iv) separators, solid electrolytes, electrodes, sensors, electrochromic windows, displays, condensers or ion-conducting film containing moulded products or composites as above; and (v) electrochemical cells containing a separator, solid electrolyte or electrode as in (iv), or a combination of two or more of these.