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    SPIROTETRATHIOCARBAMATES AND SPIROOXOTHIOCARBAMATES
    3.
    发明申请
    SPIROTETRATHIOCARBAMATES AND SPIROOXOTHIOCARBAMATES 审中-公开
    SPIROTETRATHIOCARBAMATES和SPIROOXOTHIOCARBAMATES

    公开(公告)号：WO2004056879A8

    公开(公告)日：2004-11-11

    申请号：PCT/EP0315046

    申请日：2003-12-19

    Applicant: ESSILOR INT ,  JALLOULI AREF ,  RICKWOOD MARTIN ,  MORGAN KIMBERLY ,  WANIGATUNGA SIRISOMA

    Inventor： JALLOULI AREF ,  RICKWOOD MARTIN ,  MORGAN KIMBERLY ,  WANIGATUNGA SIRISOMA

    IPC: C07D495/10 ,  C07D497/10 ,  C07D513/00 ,  C07D519/00 ,  C08F20060101 ,  C08F2/00 ,  C08G75/08

    CPC classification number: C07D497/10 ,  C07D495/10

    Abstract: Spirotetrathiocarbamates (STOCs) or oxa substituted compounds (SOTOCs) of Formula (I): (Formula (I)) or bisSTOC or bisSOTOC compounds of Formula (II): (Formula (II)) wherein X , X , X , X , X , X , X , and X , are independently O or S; and preferably at least two and up to all four of X , X , X and X , and at least two and up to all four of X , X , X , and X are sulfur; Z is -CmR 2m wherein m = 1 to 4; -C(R )2SC(R )2-, C(R )2SSC(R )2-, or -C(R )2OC(R )2; n is from 0 to 4; M is selected from CH2C1, CH2SC(O)R , CH2SC(S)R , CH2S(CH2CH2S)qH wherein q is 0, 1 or 2; -CR =CH2, -CH2OC(O)CR =CH2, CH2N=C=S, CH2N=C=O, CH2NR H, CH2OH, CH2SCH2CH2CR =CH2, phenyl, C(R ) phenyl, furan, thiophene, halogen, C3-C6 cycloalkyl, C3-C6 heretocyclics, thiol, H, (III) or (IV) wherein A is S, O or phenyl; x is 0 or l; R is C1-C22 alkyl; and R is H or C1-C22 alkyl have excellent optical properties. Methods for preparing these compositions and optical lenses prepared from the compounds are also provided.

    Abstract translation: 式（I）：（式（I））的螺双四硫代氨基甲酸酯（STOC）或氧杂取代的化合物（SOTOC）或式（II）的双STOC或bisSOTOC化合物：其中X 1，X 2， X 3，X 4，X 5，X 6，X 7和X 8独立地为O或S; 并且优选X 1，X 2，X 3和X 4中的至少两个并且直到全部四个，并且X 5，X 6， X 7和X 8是硫; Z为-CmR 2 2 m，其中m = 1至4; （R 2）2 -C（R 2）2 - ，C（R 2）2 SSC（R 2）2 - 或-C（R 2）2 OC（R 2） ）2; n是0至4; M选自CH 2 Cl，CH 2 SC（O）R 1，CH 2 SC（S）R 1，CH 2 S（CH 2 CH 2 S）q H，其中q是0,1或2; -CR 2 = CH 2，-CH 2 OC（O）CR 2 = CH 2，CH 2 N = C = S，CH 2 N = C = O，CH 2 NR 2 H，CH 2 OH，CH 2 SCH 2 CH 2 CR 2 = CH 2， （R 2）苯基，呋喃，噻吩，卤素，C 3 -C 6环烷基，C 3 -C 6杂环，巯基，H，（III）或（IV）其中A是S，O或苯基; x是0或1; R 1是C 1 -C 22烷基; 并且R 2是H或C 1 -C 22烷基具有优异的光学性质。 还提供了用于制备这些组合物的方法和由这些化合物制备的光学镜片。

    SPIROTETRATHIOCARBAMATES AND SPIROOXOTHIOCARBAMATES
    4.
    发明申请
    SPIROTETRATHIOCARBAMATES AND SPIROOXOTHIOCARBAMATES 审中-公开
    螺旋石蜡和SPIROOOXOTOCOCBAMATES

    公开(公告)号：WO2004056879A3

    公开(公告)日：2004-10-21

    申请号：PCT/EP0315046

    申请日：2003-12-19

    Applicant: ESSILOR INT ,  JALLOULI AREF ,  RICKWOOD MARTIN ,  MORGAN KIMBERLY ,  WANIGATUNGA SIRISOMA

    Inventor： JALLOULI AREF ,  RICKWOOD MARTIN ,  MORGAN KIMBERLY ,  WANIGATUNGA SIRISOMA

    IPC: C07D495/10 ,  C07D497/10 ,  C07D513/00 ,  C07D519/00 ,  C08F20060101 ,  C08F2/00 ,  C08G75/08

    CPC classification number: C07D497/10 ,  C07D495/10

    Abstract: Spirotetrathiocarbamates (STOCs) or oxa substituted compounds (SOTOCs) of Formula (I): (Formula (I)) or bisSTOC or bisSOTOC compounds of Formula (II): (Formula (II)) wherein X , X , X , X , X , X , X , and X , are independently O or S; and preferably at least two and up to all four of X , X , X and X , and at least two and up to all four of X , X , X , and X are sulfur; Z is -CmR 2m wherein m = 1 to 4; -C(R )2SC(R )2-, C(R )2SSC(R )2-, or -C(R )2OC(R )2; n is from 0 to 4; M is selected from CH2C1, CH2SC(O)R , CH2SC(S)R , CH2S(CH2CH2S)qH wherein q is 0, 1 or 2; -CR =CH2, -CH2OC(O)CR =CH2, CH2N=C=S, CH2N=C=O, CH2NR H, CH2OH, CH2SCH2CH2CR =CH2, phenyl, C(R ) phenyl, furan, thiophene, halogen, C3-C6 cycloalkyl, C3-C6 heretocyclics, thiol, H, (III) or (IV) wherein A is S, O or phenyl; x is 0 or l; R is C1-C22 alkyl; and R is H or C1-C22 alkyl have excellent optical properties. Methods for preparing these compositions and optical lenses prepared from the compounds are also provided.

    Abstract translation: 式（I）：（式（I））的二硫代氨基甲酸酯（STOC）或氧杂取代的化合物（SOTOC）或式（II）的bisSTOC或bisSOTOC化合物：（式（II））其中X 1，X 2， X 3，X 4，X 5，X 6，X 7和X 8独立地为O或S; 并且优选X 1，X 2，X 3和X 4中的至少两个和至多全部四个，X 5，X 6中的至少两个和至多四个， X 7，X 8为硫; Z是-CmR 2 m，其中m = 1-4; -C（R 2）2SC（R 2）2 - ，C（R 2）2SCSC（R 2）2 - 或-C（R 2）2 OC（R 2） ）2; n为0〜4; M选自CH 2 Cl，CH 2 SC（O）R 1，CH 2 SC（S）R 1，CH 2 S（CH 2 CH 2 S）q H，其中q是0,1或2; -CR 2 = CH 2，-CH 2 OC（O）CR 2 = CH 2，CH 2 N = C = S，CH 2 N = C = O，CH 2 NR 2 H，CH 2 OH，CH 2 SCH 2 CH 2 CR 2 = CH 2，苯基，C （R 2）苯基，呋喃，噻吩，卤素，C 3 -C 6环烷基，C 3 -C 6亚环烷基，硫醇，H，（III）或（Ⅳ）其中A为S，O或苯基; x为0或1; R 1是C 1 -C 22烷基; 且R 2为H或C 1 -C 22烷基具有优异的光学性质。 还提供了由化合物制备这些组合物和光学透镜的方法。

    Método de produção de aditivo para lente oftálmica transparente
    5.
    发明专利
    Método de produção de aditivo para lente oftálmica transparente 未知

    公开(公告)号：BR112016000897B1

    公开(公告)日：2022-04-26

    申请号：BR112016000897

    申请日：2013-07-31

    Applicant: ESSILOR INT ,  ESSILOR INT

    Inventor： JALLOULI AREF ,  HABASSI CHEFIK ,  KEITA GABRIEL ,  RONALD A BERZON

    IPC: G02B3/00 ,  B29C67/00 ,  B29D11/00 ,  G02C7/02

    Abstract: processos de produção de aditivo para lente oftálmica transparente. apresenta-se no presente documento um método para a produção de uma lente oftálmica tridimensional com o uso da produção de aditivo. o método inclui constituir voxels de uma ou mais composições, em que pelo menos uma das composições compreende um ou mais pré-polímeros ou polímeros, e induzir a conectividade entre os voxels criando, desse modo, um ou mais elementos incrementais, repetir as etapas de constituição, e realizar um pós-tratamento final. também é apresentada no presente documento uma lente oftálmica obtida por este método. a lente tem boa homogeneidade e claridade óptica, encolhimento reduzido e precisão geométrica aprimorada e propriedades termomecânicas.

    9.
    发明专利
    未知

    公开(公告)号：DE602004012537D1

    公开(公告)日：2008-04-30

    申请号：DE602004012537

    申请日：2004-03-24

    Applicant: ESSILOR INT

    Inventor： JALLOULI AREF ,  TURSHANI YASSIN ,  WANIGATUNGA SIRISOMA ,  RICKWOOD MARTIN

    IPC: C08L81/04 ,  C07F9/50 ,  C07F9/53 ,  C08F26/06 ,  C08G75/08 ,  C08G79/02 ,  G02B1/04

    Abstract: Disclosed is a thiophosphine compound of formula: wherein X represents with R 1 being H or -CH 3 , R and R' represent, independently from each other, an alkyl radical, an alkoxy radical, an aryl radical or a phenyl radical which may be substituted with one or more alkyl and/or alkoxy groups, n is an integer from 0 to 4, n' is an integer from 0 to 5, x is an integer from 0 to 2, y is an integer from 1 to 5 with the proviso that y+n is an integer from 1 to 5. The compounds can be used to make optically transparent articles such as ophthalmic lenses.

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