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    SPIROTETRATHIOCARBAMATES AND SPIROOXOTHIOCARBAMATES
    2.
    发明申请
    SPIROTETRATHIOCARBAMATES AND SPIROOXOTHIOCARBAMATES 审中-公开
    SPIROTETRATHIOCARBAMATES和SPIROOXOTHIOCARBAMATES

    公开(公告)号：WO2004056879A8

    公开(公告)日：2004-11-11

    申请号：PCT/EP0315046

    申请日：2003-12-19

    Applicant: ESSILOR INT ,  JALLOULI AREF ,  RICKWOOD MARTIN ,  MORGAN KIMBERLY ,  WANIGATUNGA SIRISOMA

    Inventor： JALLOULI AREF ,  RICKWOOD MARTIN ,  MORGAN KIMBERLY ,  WANIGATUNGA SIRISOMA

    IPC: C07D495/10 ,  C07D497/10 ,  C07D513/00 ,  C07D519/00 ,  C08F20060101 ,  C08F2/00 ,  C08G75/08

    CPC classification number: C07D497/10 ,  C07D495/10

    Abstract: Spirotetrathiocarbamates (STOCs) or oxa substituted compounds (SOTOCs) of Formula (I): (Formula (I)) or bisSTOC or bisSOTOC compounds of Formula (II): (Formula (II)) wherein X , X , X , X , X , X , X , and X , are independently O or S; and preferably at least two and up to all four of X , X , X and X , and at least two and up to all four of X , X , X , and X are sulfur; Z is -CmR 2m wherein m = 1 to 4; -C(R )2SC(R )2-, C(R )2SSC(R )2-, or -C(R )2OC(R )2; n is from 0 to 4; M is selected from CH2C1, CH2SC(O)R , CH2SC(S)R , CH2S(CH2CH2S)qH wherein q is 0, 1 or 2; -CR =CH2, -CH2OC(O)CR =CH2, CH2N=C=S, CH2N=C=O, CH2NR H, CH2OH, CH2SCH2CH2CR =CH2, phenyl, C(R ) phenyl, furan, thiophene, halogen, C3-C6 cycloalkyl, C3-C6 heretocyclics, thiol, H, (III) or (IV) wherein A is S, O or phenyl; x is 0 or l; R is C1-C22 alkyl; and R is H or C1-C22 alkyl have excellent optical properties. Methods for preparing these compositions and optical lenses prepared from the compounds are also provided.

    Abstract translation: 式（I）：（式（I））的螺双四硫代氨基甲酸酯（STOC）或氧杂取代的化合物（SOTOC）或式（II）的双STOC或bisSOTOC化合物：其中X 1，X 2， X 3，X 4，X 5，X 6，X 7和X 8独立地为O或S; 并且优选X 1，X 2，X 3和X 4中的至少两个并且直到全部四个，并且X 5，X 6， X 7和X 8是硫; Z为-CmR 2 2 m，其中m = 1至4; （R 2）2 -C（R 2）2 - ，C（R 2）2 SSC（R 2）2 - 或-C（R 2）2 OC（R 2） ）2; n是0至4; M选自CH 2 Cl，CH 2 SC（O）R 1，CH 2 SC（S）R 1，CH 2 S（CH 2 CH 2 S）q H，其中q是0,1或2; -CR 2 = CH 2，-CH 2 OC（O）CR 2 = CH 2，CH 2 N = C = S，CH 2 N = C = O，CH 2 NR 2 H，CH 2 OH，CH 2 SCH 2 CH 2 CR 2 = CH 2， （R 2）苯基，呋喃，噻吩，卤素，C 3 -C 6环烷基，C 3 -C 6杂环，巯基，H，（III）或（IV）其中A是S，O或苯基; x是0或1; R 1是C 1 -C 22烷基; 并且R 2是H或C 1 -C 22烷基具有优异的光学性质。 还提供了用于制备这些组合物的方法和由这些化合物制备的光学镜片。

    COMPOUNDS THAT ABSORB ULTRAVIOLET LIGHT, METHODS OF THEIR PREPARATION AND OPTICAL LENSES CONTAINING THEM
    3.
    发明申请
    COMPOUNDS THAT ABSORB ULTRAVIOLET LIGHT, METHODS OF THEIR PREPARATION AND OPTICAL LENSES CONTAINING THEM 审中-公开
    吸收超紫外线的化合物，其制备方法和含有它们的光学透镜

    公开(公告)号：WO2006069811B1

    公开(公告)日：2007-02-08

    申请号：PCT/EP2005014202

    申请日：2005-12-30

    Applicant: ESSILOR INT ,  KAUFFMAN JOEL ,  LITAK PETER T ,  RICKWOOD MARTIN

    Inventor： KAUFFMAN JOEL ,  LITAK PETER T ,  RICKWOOD MARTIN

    IPC: C07D263/56 ,  C08L69/00 ,  G02B1/04

    CPC classification number: G02B1/041 ,  C07D263/57 ,  C08K5/353

    Abstract: Compounds of Formula (4) or (5) that absorb ultraviolet light 380 nm to 400 nm range but avoid absorption in the blue light range, thereby imparting yellowness, i.e., 410-420 nm: have suitable refractive characteristics useful in the preparation of optical resins or plastics suitable, for example, for the manufacture of ophthalmic lenses. Methods for making the compounds, optic lenses containing the compounds, and methods for making these are also described.

    Abstract translation: 吸收380nm至400nm范围内的紫外光，但避免在蓝光范围内的吸收，从而赋予黄度（即410-420nm）的式（4）或（5）的化合物具有在制备光学中有用的合适的折射特性 适用于例如用于制造眼科镜片的树脂或塑料。 还描述了制备化合物的方法，含有这些化合物的光学镜片及其制备方法。

    SPIROTETRATHIOCARBAMATES AND SPIROOXOTHIOCARBAMATES
    4.
    发明申请
    SPIROTETRATHIOCARBAMATES AND SPIROOXOTHIOCARBAMATES 审中-公开
    螺旋石蜡和SPIROOOXOTOCOCBAMATES

    公开(公告)号：WO2004056879A3

    公开(公告)日：2004-10-21

    申请号：PCT/EP0315046

    申请日：2003-12-19

    Applicant: ESSILOR INT ,  JALLOULI AREF ,  RICKWOOD MARTIN ,  MORGAN KIMBERLY ,  WANIGATUNGA SIRISOMA

    Inventor： JALLOULI AREF ,  RICKWOOD MARTIN ,  MORGAN KIMBERLY ,  WANIGATUNGA SIRISOMA

    IPC: C07D495/10 ,  C07D497/10 ,  C07D513/00 ,  C07D519/00 ,  C08F20060101 ,  C08F2/00 ,  C08G75/08

    CPC classification number: C07D497/10 ,  C07D495/10

    Abstract: Spirotetrathiocarbamates (STOCs) or oxa substituted compounds (SOTOCs) of Formula (I): (Formula (I)) or bisSTOC or bisSOTOC compounds of Formula (II): (Formula (II)) wherein X , X , X , X , X , X , X , and X , are independently O or S; and preferably at least two and up to all four of X , X , X and X , and at least two and up to all four of X , X , X , and X are sulfur; Z is -CmR 2m wherein m = 1 to 4; -C(R )2SC(R )2-, C(R )2SSC(R )2-, or -C(R )2OC(R )2; n is from 0 to 4; M is selected from CH2C1, CH2SC(O)R , CH2SC(S)R , CH2S(CH2CH2S)qH wherein q is 0, 1 or 2; -CR =CH2, -CH2OC(O)CR =CH2, CH2N=C=S, CH2N=C=O, CH2NR H, CH2OH, CH2SCH2CH2CR =CH2, phenyl, C(R ) phenyl, furan, thiophene, halogen, C3-C6 cycloalkyl, C3-C6 heretocyclics, thiol, H, (III) or (IV) wherein A is S, O or phenyl; x is 0 or l; R is C1-C22 alkyl; and R is H or C1-C22 alkyl have excellent optical properties. Methods for preparing these compositions and optical lenses prepared from the compounds are also provided.

    Abstract translation: 式（I）：（式（I））的二硫代氨基甲酸酯（STOC）或氧杂取代的化合物（SOTOC）或式（II）的bisSTOC或bisSOTOC化合物：（式（II））其中X 1，X 2， X 3，X 4，X 5，X 6，X 7和X 8独立地为O或S; 并且优选X 1，X 2，X 3和X 4中的至少两个和至多全部四个，X 5，X 6中的至少两个和至多四个， X 7，X 8为硫; Z是-CmR 2 m，其中m = 1-4; -C（R 2）2SC（R 2）2 - ，C（R 2）2SCSC（R 2）2 - 或-C（R 2）2 OC（R 2） ）2; n为0〜4; M选自CH 2 Cl，CH 2 SC（O）R 1，CH 2 SC（S）R 1，CH 2 S（CH 2 CH 2 S）q H，其中q是0,1或2; -CR 2 = CH 2，-CH 2 OC（O）CR 2 = CH 2，CH 2 N = C = S，CH 2 N = C = O，CH 2 NR 2 H，CH 2 OH，CH 2 SCH 2 CH 2 CR 2 = CH 2，苯基，C （R 2）苯基，呋喃，噻吩，卤素，C 3 -C 6环烷基，C 3 -C 6亚环烷基，硫醇，H，（III）或（Ⅳ）其中A为S，O或苯基; x为0或1; R 1是C 1 -C 22烷基; 且R 2为H或C 1 -C 22烷基具有优异的光学性质。 还提供了由化合物制备这些组合物和光学透镜的方法。

    6.
    发明专利
    未知

    公开(公告)号：DE602004012537D1

    公开(公告)日：2008-04-30

    申请号：DE602004012537

    申请日：2004-03-24

    Applicant: ESSILOR INT

    Inventor： JALLOULI AREF ,  TURSHANI YASSIN ,  WANIGATUNGA SIRISOMA ,  RICKWOOD MARTIN

    IPC: C08L81/04 ,  C07F9/50 ,  C07F9/53 ,  C08F26/06 ,  C08G75/08 ,  C08G79/02 ,  G02B1/04

    Abstract: Disclosed is a thiophosphine compound of formula: wherein X represents with R 1 being H or -CH 3 , R and R' represent, independently from each other, an alkyl radical, an alkoxy radical, an aryl radical or a phenyl radical which may be substituted with one or more alkyl and/or alkoxy groups, n is an integer from 0 to 4, n' is an integer from 0 to 5, x is an integer from 0 to 2, y is an integer from 1 to 5 with the proviso that y+n is an integer from 1 to 5. The compounds can be used to make optically transparent articles such as ophthalmic lenses.

    Spirotetrathiocarbamates and spirooxothiocarbamates
    7.
    发明专利
    Spirotetrathiocarbamates and spirooxothiocarbamates 未知

    公开(公告)号：AU2003302173A8

    公开(公告)日：2004-07-14

    申请号：AU2003302173

    申请日：2003-12-19

    Applicant: ESSILOR INT

    Inventor： RICKWOOD MARTIN ,  MORGAN KIMBERLY ,  JALLOULI AREF ,  WANIGATUNGA SIRISOMA

    IPC: C07D495/10 ,  C07D497/10 ,  C07D513/00 ,  C07D519/00 ,  C08F20060101 ,  C08F2/00 ,  C08G75/08

    Abstract: Spirotetrathiocarbamates (STOCs) or oxa substituted compounds (SOTOCs) of Formula I: Formula (I) or bisSTOC or bisSOTOC compounds of Formula II: Formula (II) wherein X1, X2, X3, X4, X5, X6, X7, and X8, are independently O or S; and preferably at least two and up to all four of X1, X2, X3 and X4, and at least two and up to all four of X5, X6, X7, and X8 are sulfur; Z is —CmR22m wherein m=1 to 4; —C(R2)2SC(R2)2—, C(R2)2SSC(R2)2—, or —C(R2)OC(R2)2; n is from 0 to 4; M is selected from CH2Cl, CH2SC(O)R1, CH2SC(S)R1, CH2S(CH2CH2S)qH wherein q is 0, 1 or 2; —CR2═CH2, —CH2OC(O)CR2═CH2, CH2N═C═S, CH2N═C═O, CH2NR2H, CH2OH, CH2SCH2CH2CR2═CH2, phenyl, C(R2)phenyl, furan, thiophene, halogen, C3-C6 cycloalkyl, C3-C6 heretocyclics, thiol, H, (III) or (IV) wherein A is S, O or phenyl; x is 0 or 1; R1 is C1-C22 alkyl; and R2 is H or C1-C22 alkyl have excellent optical properties. Methods for preparing these compositions and optical lenses prepared from the compounds are also provided.

    8.
    发明专利
    未知

    公开(公告)号：DE602004012537T2

    公开(公告)日：2008-11-27

    申请号：DE602004012537

    申请日：2004-03-24

    Applicant: ESSILOR INT

    Inventor： JALLOULI AREF ,  TURSHANI YASSIN ,  WANIGATUNGA SIRISOMA ,  RICKWOOD MARTIN

    IPC: C08L81/04 ,  C07F9/50 ,  C07F9/53 ,  C08F26/06 ,  C08G75/08 ,  C08G79/02 ,  G02B1/04

    Abstract: Disclosed is a thiophosphine compound of formula: wherein X represents with R 1 being H or -CH 3 , R and R' represent, independently from each other, an alkyl radical, an alkoxy radical, an aryl radical or a phenyl radical which may be substituted with one or more alkyl and/or alkoxy groups, n is an integer from 0 to 4, n' is an integer from 0 to 5, x is an integer from 0 to 2, y is an integer from 1 to 5 with the proviso that y+n is an integer from 1 to 5. The compounds can be used to make optically transparent articles such as ophthalmic lenses.

    SPIROTETRATHIOCARBAMATES AND SPIROOXOTHIOCARBAMATES
    9.
    发明专利
    SPIROTETRATHIOCARBAMATES AND SPIROOXOTHIOCARBAMATES 未知

    公开(公告)号：AU2003302173A1

    公开(公告)日：2004-07-14

    申请号：AU2003302173

    申请日：2003-12-19

    Applicant: ESSILOR INT

    Inventor： JALLOULI AREF ,  RICKWOOD MARTIN ,  MORGAN KIMBERLY ,  WANIGATUNGA SIRISOMA

    IPC: C07D495/10 ,  C07D497/10 ,  C07D513/00 ,  C07D519/00 ,  C08F20060101 ,  C08F2/00 ,  C08G75/08

    Abstract: Spirotetrathiocarbamates (STOCs) or oxa substituted compounds (SOTOCs) of Formula I: Formula (I) or bisSTOC or bisSOTOC compounds of Formula II: Formula (II) wherein X1, X2, X3, X4, X5, X6, X7, and X8, are independently O or S; and preferably at least two and up to all four of X1, X2, X3 and X4, and at least two and up to all four of X5, X6, X7, and X8 are sulfur; Z is —CmR22m wherein m=1 to 4; —C(R2)2SC(R2)2—, C(R2)2SSC(R2)2—, or —C(R2)OC(R2)2; n is from 0 to 4; M is selected from CH2Cl, CH2SC(O)R1, CH2SC(S)R1, CH2S(CH2CH2S)qH wherein q is 0, 1 or 2; —CR2═CH2, —CH2OC(O)CR2═CH2, CH2N═C═S, CH2N═C═O, CH2NR2H, CH2OH, CH2SCH2CH2CR2═CH2, phenyl, C(R2)phenyl, furan, thiophene, halogen, C3-C6 cycloalkyl, C3-C6 heretocyclics, thiol, H, (III) or (IV) wherein A is S, O or phenyl; x is 0 or 1; R1 is C1-C22 alkyl; and R2 is H or C1-C22 alkyl have excellent optical properties. Methods for preparing these compositions and optical lenses prepared from the compounds are also provided.

    10.
    发明专利
    未知

    公开(公告)号：AT389694T

    公开(公告)日：2008-04-15

    申请号：AT04722844

    申请日：2004-03-24

    Applicant: ESSILOR INT

    Inventor： JALLOULI AREF ,  TURSHANI YASSIN ,  WANIGATUNGA SIRISOMA ,  RICKWOOD MARTIN

    IPC: C08L81/04 ,  C07F9/50 ,  C07F9/53 ,  C08F26/06 ,  C08G75/08 ,  C08G79/02 ,  G02B1/04

    Abstract: Disclosed is a thiophosphine compound of formula: wherein X represents with R 1 being H or -CH 3 , R and R' represent, independently from each other, an alkyl radical, an alkoxy radical, an aryl radical or a phenyl radical which may be substituted with one or more alkyl and/or alkoxy groups, n is an integer from 0 to 4, n' is an integer from 0 to 5, x is an integer from 0 to 2, y is an integer from 1 to 5 with the proviso that y+n is an integer from 1 to 5. The compounds can be used to make optically transparent articles such as ophthalmic lenses.

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