公开(公告)号：WO2004056879A8

公开(公告)日：2004-11-11

申请号：PCT/EP0315046

申请日：2003-12-19

Applicant: ESSILOR INT ,  JALLOULI AREF ,  RICKWOOD MARTIN ,  MORGAN KIMBERLY ,  WANIGATUNGA SIRISOMA

Inventor： JALLOULI AREF ,  RICKWOOD MARTIN ,  MORGAN KIMBERLY ,  WANIGATUNGA SIRISOMA

IPC: C07D495/10 ,  C07D497/10 ,  C07D513/00 ,  C07D519/00 ,  C08F20060101 ,  C08F2/00 ,  C08G75/08

CPC classification number: C07D497/10 ,  C07D495/10

Abstract: Spirotetrathiocarbamates (STOCs) or oxa substituted compounds (SOTOCs) of Formula (I): (Formula (I)) or bisSTOC or bisSOTOC compounds of Formula (II): (Formula (II)) wherein X , X , X , X , X , X , X , and X , are independently O or S; and preferably at least two and up to all four of X , X , X and X , and at least two and up to all four of X , X , X , and X are sulfur; Z is -CmR 2m wherein m = 1 to 4; -C(R )2SC(R )2-, C(R )2SSC(R )2-, or -C(R )2OC(R )2; n is from 0 to 4; M is selected from CH2C1, CH2SC(O)R , CH2SC(S)R , CH2S(CH2CH2S)qH wherein q is 0, 1 or 2; -CR =CH2, -CH2OC(O)CR =CH2, CH2N=C=S, CH2N=C=O, CH2NR H, CH2OH, CH2SCH2CH2CR =CH2, phenyl, C(R ) phenyl, furan, thiophene, halogen, C3-C6 cycloalkyl, C3-C6 heretocyclics, thiol, H, (III) or (IV) wherein A is S, O or phenyl; x is 0 or l; R is C1-C22 alkyl; and R is H or C1-C22 alkyl have excellent optical properties. Methods for preparing these compositions and optical lenses prepared from the compounds are also provided.

Abstract translation: 式（I）：（式（I））的螺双四硫代氨基甲酸酯（STOC）或氧杂取代的化合物（SOTOC）或式（II）的双STOC或bisSOTOC化合物：其中X 1，X 2， X 3，X 4，X 5，X 6，X 7和X 8独立地为O或S; 并且优选X 1，X 2，X 3和X 4中的至少两个并且直到全部四个，并且X 5，X 6， X 7和X 8是硫; Z为-CmR 2 2 m，其中m = 1至4; （R 2）2 -C（R 2）2 - ，C（R 2）2 SSC（R 2）2 - 或-C（R 2）2 OC（R 2） ）2; n是0至4; M选自CH 2 Cl，CH 2 SC（O）R 1，CH 2 SC（S）R 1，CH 2 S（CH 2 CH 2 S）q H，其中q是0,1或2; -CR 2 = CH 2，-CH 2 OC（O）CR 2 = CH 2，CH 2 N = C = S，CH 2 N = C = O，CH 2 NR 2 H，CH 2 OH，CH 2 SCH 2 CH 2 CR 2 = CH 2， （R 2）苯基，呋喃，噻吩，卤素，C 3 -C 6环烷基，C 3 -C 6杂环，巯基，H，（III）或（IV）其中A是S，O或苯基; x是0或1; R 1是C 1 -C 22烷基; 并且R 2是H或C 1 -C 22烷基具有优异的光学性质。 还提供了用于制备这些组合物的方法和由这些化合物制备的光学镜片。

公开(公告)号：WO2004056879A3

公开(公告)日：2004-10-21

申请号：PCT/EP0315046

申请日：2003-12-19

Applicant: ESSILOR INT ,  JALLOULI AREF ,  RICKWOOD MARTIN ,  MORGAN KIMBERLY ,  WANIGATUNGA SIRISOMA

Inventor： JALLOULI AREF ,  RICKWOOD MARTIN ,  MORGAN KIMBERLY ,  WANIGATUNGA SIRISOMA

IPC: C07D495/10 ,  C07D497/10 ,  C07D513/00 ,  C07D519/00 ,  C08F20060101 ,  C08F2/00 ,  C08G75/08

CPC classification number: C07D497/10 ,  C07D495/10

Abstract: Spirotetrathiocarbamates (STOCs) or oxa substituted compounds (SOTOCs) of Formula (I): (Formula (I)) or bisSTOC or bisSOTOC compounds of Formula (II): (Formula (II)) wherein X , X , X , X , X , X , X , and X , are independently O or S; and preferably at least two and up to all four of X , X , X and X , and at least two and up to all four of X , X , X , and X are sulfur; Z is -CmR 2m wherein m = 1 to 4; -C(R )2SC(R )2-, C(R )2SSC(R )2-, or -C(R )2OC(R )2; n is from 0 to 4; M is selected from CH2C1, CH2SC(O)R , CH2SC(S)R , CH2S(CH2CH2S)qH wherein q is 0, 1 or 2; -CR =CH2, -CH2OC(O)CR =CH2, CH2N=C=S, CH2N=C=O, CH2NR H, CH2OH, CH2SCH2CH2CR =CH2, phenyl, C(R ) phenyl, furan, thiophene, halogen, C3-C6 cycloalkyl, C3-C6 heretocyclics, thiol, H, (III) or (IV) wherein A is S, O or phenyl; x is 0 or l; R is C1-C22 alkyl; and R is H or C1-C22 alkyl have excellent optical properties. Methods for preparing these compositions and optical lenses prepared from the compounds are also provided.

Abstract translation: 式（I）：（式（I））的二硫代氨基甲酸酯（STOC）或氧杂取代的化合物（SOTOC）或式（II）的bisSTOC或bisSOTOC化合物：（式（II））其中X 1，X 2， X 3，X 4，X 5，X 6，X 7和X 8独立地为O或S; 并且优选X 1，X 2，X 3和X 4中的至少两个和至多全部四个，X 5，X 6中的至少两个和至多四个， X 7，X 8为硫; Z是-CmR 2 m，其中m = 1-4; -C（R 2）2SC（R 2）2 - ，C（R 2）2SCSC（R 2）2 - 或-C（R 2）2 OC（R 2） ）2; n为0〜4; M选自CH 2 Cl，CH 2 SC（O）R 1，CH 2 SC（S）R 1，CH 2 S（CH 2 CH 2 S）q H，其中q是0,1或2; -CR 2 = CH 2，-CH 2 OC（O）CR 2 = CH 2，CH 2 N = C = S，CH 2 N = C = O，CH 2 NR 2 H，CH 2 OH，CH 2 SCH 2 CH 2 CR 2 = CH 2，苯基，C （R 2）苯基，呋喃，噻吩，卤素，C 3 -C 6环烷基，C 3 -C 6亚环烷基，硫醇，H，（III）或（Ⅳ）其中A为S，O或苯基; x为0或1; R 1是C 1 -C 22烷基; 且R 2为H或C 1 -C 22烷基具有优异的光学性质。 还提供了由化合物制备这些组合物和光学透镜的方法。

公开(公告)号：AU2003302173A1

公开(公告)日：2004-07-14

申请号：AU2003302173

申请日：2003-12-19

Applicant: ESSILOR INT

Inventor： JALLOULI AREF ,  RICKWOOD MARTIN ,  MORGAN KIMBERLY ,  WANIGATUNGA SIRISOMA

IPC: C07D495/10 ,  C07D497/10 ,  C07D513/00 ,  C07D519/00 ,  C08F20060101 ,  C08F2/00 ,  C08G75/08

Abstract: Spirotetrathiocarbamates (STOCs) or oxa substituted compounds (SOTOCs) of Formula I: Formula (I) or bisSTOC or bisSOTOC compounds of Formula II: Formula (II) wherein X1, X2, X3, X4, X5, X6, X7, and X8, are independently O or S; and preferably at least two and up to all four of X1, X2, X3 and X4, and at least two and up to all four of X5, X6, X7, and X8 are sulfur; Z is —CmR22m wherein m=1 to 4; —C(R2)2SC(R2)2—, C(R2)2SSC(R2)2—, or —C(R2)OC(R2)2; n is from 0 to 4; M is selected from CH2Cl, CH2SC(O)R1, CH2SC(S)R1, CH2S(CH2CH2S)qH wherein q is 0, 1 or 2; —CR2═CH2, —CH2OC(O)CR2═CH2, CH2N═C═S, CH2N═C═O, CH2NR2H, CH2OH, CH2SCH2CH2CR2═CH2, phenyl, C(R2)phenyl, furan, thiophene, halogen, C3-C6 cycloalkyl, C3-C6 heretocyclics, thiol, H, (III) or (IV) wherein A is S, O or phenyl; x is 0 or 1; R1 is C1-C22 alkyl; and R2 is H or C1-C22 alkyl have excellent optical properties. Methods for preparing these compositions and optical lenses prepared from the compounds are also provided.

公开(公告)号：AU2003302173A8

公开(公告)日：2004-07-14

申请号：AU2003302173

申请日：2003-12-19

Applicant: ESSILOR INT

Inventor： RICKWOOD MARTIN ,  MORGAN KIMBERLY ,  JALLOULI AREF ,  WANIGATUNGA SIRISOMA

IPC: C07D495/10 ,  C07D497/10 ,  C07D513/00 ,  C07D519/00 ,  C08F20060101 ,  C08F2/00 ,  C08G75/08

Abstract: Spirotetrathiocarbamates (STOCs) or oxa substituted compounds (SOTOCs) of Formula I: Formula (I) or bisSTOC or bisSOTOC compounds of Formula II: Formula (II) wherein X1, X2, X3, X4, X5, X6, X7, and X8, are independently O or S; and preferably at least two and up to all four of X1, X2, X3 and X4, and at least two and up to all four of X5, X6, X7, and X8 are sulfur; Z is —CmR22m wherein m=1 to 4; —C(R2)2SC(R2)2—, C(R2)2SSC(R2)2—, or —C(R2)OC(R2)2; n is from 0 to 4; M is selected from CH2Cl, CH2SC(O)R1, CH2SC(S)R1, CH2S(CH2CH2S)qH wherein q is 0, 1 or 2; —CR2═CH2, —CH2OC(O)CR2═CH2, CH2N═C═S, CH2N═C═O, CH2NR2H, CH2OH, CH2SCH2CH2CR2═CH2, phenyl, C(R2)phenyl, furan, thiophene, halogen, C3-C6 cycloalkyl, C3-C6 heretocyclics, thiol, H, (III) or (IV) wherein A is S, O or phenyl; x is 0 or 1; R1 is C1-C22 alkyl; and R2 is H or C1-C22 alkyl have excellent optical properties. Methods for preparing these compositions and optical lenses prepared from the compounds are also provided.