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公开(公告)号:US20250121316A1
公开(公告)日:2025-04-17
申请号:US18915714
申请日:2024-10-15
Inventor: Corey J. KAMINSKY , Shabab A. Abedi , Hilda B. Vroman , Wesley Sattler
Abstract: Amine-functionalized organosilica materials are provided that have improved stability when exposed to oxidizing/oxygen-containing environments during cycling of temperature, such as the cycling of temperature that occurs when using a material as a sorbent during successive adsorption/desorption cycles. Methods of performing CO2 sorption/desorption with improved stability of the organosilica sorbent material are also provided. The improved stability is achieved in part by using amine-functionalized organosilica materials where the amine-functionalization is provided by functional groups that include primary amines but do not include secondary amines. Still further improvements in stability can be achieved when the functionalization is provided by a functional group that includes a primary amine while also not having any hydrogens on a carbon atom that is in the beta position relative to the primary amine.
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公开(公告)号:US20250091887A1
公开(公告)日:2025-03-20
申请号:US18886225
申请日:2024-09-16
Inventor: Trong D. Pham , Hilda B. Vroman , Eugene A. Terefenko
IPC: C01B39/48
Abstract: The present disclosure relates to a method of making zeolites of BOG framework type, in particular a direct synthesis method for the preparation of aluminosilicate zeolites of BOG framework type using 5-azaindolium cations as structure directing agents. The present disclosure also relates to small crystal forms of aluminosilicate zeolites of BOG framework type and uses thereof.
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公开(公告)号:US20250011177A1
公开(公告)日:2025-01-09
申请号:US18570389
申请日:2022-06-08
Inventor: Allen W. Burton , Stuart L. Soled , Hilda B. Vroman
IPC: C01B39/48 , B01J29/70 , B01J29/86 , B01J37/00 , B01J37/03 , B01J37/04 , B01J37/10 , C01B39/12 , C07D221/04
Abstract: This disclosure relates to the use of 1-methyl-6,7-dihydro-5H-cyclopenta[b]pyridine-1-ium cation as structure directing agent (SDA) for the preparation of zeolites. This disclosure also relates to compositions of matter, designated as EMM-64 and EMM-65, obtainably by using this SDA, as well as a method of making the same and uses thereof. This disclosure further relates to a method of making an aluminosilicate molecular sieve of RTH framework type using said SDA, aluminosilicate molecular sieves of RTH framework type obtainable by said method, and uses thereof.
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公开(公告)号:US20240400400A1
公开(公告)日:2024-12-05
申请号:US18690620
申请日:2022-08-11
Inventor: Allen W. Burton , Hilda B. Vroman , Trong D. Pham , Eugene A. Terefenko
IPC: C01B39/48
Abstract: Various zeolites may be produced under hydrothermal synthesis conditions in the presence of a silicon atom source and a bis-pyridinium compound having a structure represented by formula (I). Q is an optionally substituted C1-C10 hydrocarbyl group and two Q may join to form a carbocyclic ring; n is an integer ranging from 0 to 5; m is an integer ranging from 0 to 5; n+m is greater than or equal to 1; and A is a spacer group containing 2 to about 10 atoms.
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公开(公告)号:US20240317594A1
公开(公告)日:2024-09-26
申请号:US18733491
申请日:2024-06-04
Inventor: Ross Mabon , Allen W. Burton , Hilda B. Vroman , Simon C. Weston
IPC: C01B39/48 , C07C211/09
CPC classification number: C01B39/48 , C07C211/09 , C01P2002/72
Abstract: A method can include heating an aqueous reaction mixture comprising a silicon source and a boron source and/or an aluminum source in the presence of a quaternary structure directing agent to a temperature of at least 75° C. to produce a zeolite. A composition can include a borosilicate zeolite, an aluminosilicate zeolite, or an aluminoborosilicate zeolite having a framework symmetry of C2/m and a unit cell with measurements of a of 3.5 Å to 4.5 Å, b of 20.1 Å to 21.1 Å, c of 15.5 to 16.5 Å, and β of 97° to 98°.
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公开(公告)号:US12269750B2
公开(公告)日:2025-04-08
申请号:US18040403
申请日:2020-08-07
Inventor: Allen W. Burton , Hilda B. Vroman , Joseph M. Falkowski
Abstract: An aluminosilicate zeolite may have a molar ratio of Si to Al of about 3 to about 10, a monoclinic space group C2/m with unit cell dimensions of a of 13.6 Å+/−5%, b of 21.7 Å+/−5%, c of 6.7 Å+/−5%, and β of 93°+/−3°, 12-ring pores along a c-axis having dimensions of 7 Å+/−5% by 6 Å+/−5%, and 8-ring pores along an a-axis having dimensions of 3 Å+/−5% by 3 Å+/−5%. Said aluminosilicate zeolites may be useful in hydrocarbon conversion processes, selective catalytic reduction of NOx, CO2 and/or N2 adsorption, carbonylation reactions, and the monoalkylamine and dialkylamine syntheses.
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公开(公告)号:US20250025855A1
公开(公告)日:2025-01-23
申请号:US18910441
申请日:2024-10-09
Inventor: Ross MABON , Michael A. Marella , Allen W. Burton , Hilda B. Vroman , Kirk D. Schmitt , Tom Willhammar , Hongyi Xu , Xiaodong Zou , Simon C. Weston
Abstract: This disclosure relates to EMM-41 materials, methods for making it, and processes for its use. This disclosure also relates to the structure directing agents used in the methods for making the EMM-41 material as well as the synthesis method used to prepare such structure directing agents.
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公开(公告)号:US20250025854A1
公开(公告)日:2025-01-23
申请号:US18910399
申请日:2024-10-09
Inventor: Ross MABON , Michael A. Marella , Allen W. Burton , Hilda B. Vroman , Kirk D. Schmitt , Tom Willhammar , Hongyi Xu , Xiaodong Zou , Simon C. Weston
Abstract: This disclosure relates to EMM-41 materials, methods for making it, and processes for its use. This disclosure also relates to the structure directing agents used in the methods for making the EMM-41 material as well as the synthesis method used to prepare such structure directing agents.
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公开(公告)号:US12161990B2
公开(公告)日:2024-12-10
申请号:US17311394
申请日:2019-11-12
Inventor: Ross Mabon , Michael A. Marella , Allen W. Burton , Hilda B. Vroman , Kirk D. Schmitt , Tom Willhammar , Hongyi Xu , Xiaodong Zou , Simon C. Weston
Abstract: This disclosure relates to EMM-41 materials, methods for making it, and processes for its use. This disclosure also relates to the structure directing agents used in the methods for making the EMM-41 material as well as the synthesis method used to prepare such structure directing agents.
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公开(公告)号:US20240383763A1
公开(公告)日:2024-11-21
申请号:US18696716
申请日:2022-08-26
Inventor: Trong D. Pham , Allen W. Burton , Stuart L. Soled , Hilda B. Vroman
Abstract: Aluminosilicate zeolites, designated as EMM-68, characterized by a unique powder XRD pattern or unique connectivities, methods of making the same, and uses thereof.
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