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1.发明授权公开(公告)号：US12227526B2
公开(公告)日：2025-02-18
申请号：US17310622
申请日：2020-03-30
Inventor： Joseph M. Falkowski , Carter W. Abney , Mary S. Abdulkarim , Aaron Sattler , Michele Paccagnini , Simon C. Weston
Abstract: Metal-organic framework materials (MOFs) are highly porous entities comprising a multidentate organic ligand coordinated to multiple metal centers, typically as a coordination polymer. Crystallization may be problematic in some instances when secondary binding sites are present in the multidentate organic ligand. Multidentate organic ligands comprising first and second binding sites bridged together with a third binding site comprising a diimine moiety may alleviate these issues, particularly when using a preformed metal cluster as a metal source to form a MOF. Such MOFs may comprise a plurality of metal centers, and a multidentate organic ligand coordinated to the plurality of metal centers to define an at least partially crystalline network structure having a plurality of internal pores, and in which the multidentate organic ligand comprises first and second binding sites bridged together with a third binding site comprising a diimine moiety. Particular MOFs may comprise N,N′-di(1H-pyrazol-4-yl)ethane-1,2-diimine as a multidentate organic ligand.
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公开(公告)号：US20240327442A1
公开(公告)日：2024-10-03
申请号：US18294067
申请日：2022-07-21
Applicant: THE REGENTS OF THE UNIVERSITY OF CALIFORNIA , EXXONMOBIL TECHNOLOGY AND ENGINEERING COMPANY
Inventor： Megan N. Jackson , Jeffrey R. Long , Joseph M. Falkowski
IPC: C07F15/06
CPC classification number: C07F15/065
Abstract: Methods of synthesizing crystalline metal-organic frameworks (MOFs) having polytopic organic linkers and, cations, where each linker is connected, to two or more cations, are provided. In the disclosed methods, the linkers are reacted with one or more compounds of formula MnXm, where each M is independently cationic Be, Mg, Ca, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Zr, Nb, Mo, Ru, Rh, Pd, Cd, or Hf, X is anionic, n and m are integers. The reaction is performed in the presence of a salicylate, salicylamide, 1,3-phthalate, or hydroxybenzoate based modulator.
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公开(公告)号：US12037349B2
公开(公告)日：2024-07-16
申请号：US17310633
申请日：2020-03-30
Inventor： Joseph M. Falkowski , Mary S. Abdulkarim , Carter W. Abney
CPC classification number: C07F3/06 , C01B37/00 , C01B39/00 , C07F3/003 , C07F3/02 , C07F15/045 , C07F15/065 , C07F19/005
Abstract: Metal-organic framework materials (MOFs) are highly porous entities comprising a multidentate organic ligand coordinated to multiple metal centers, typically as a coordination polymer. MOFs may comprise a plurality of metal centers, and a multidentate organic ligand coordinated via at least two binding sites to the plurality of metal centers to define an at least partially crystalline network structure having a plurality of internal pores, and in which the multidentate organic ligand comprises first and second binding sites bridged together with a third binding site comprising a diimine moiety. The multidentate organic ligand may comprise a reaction product of a vicinal dicarbonyl compound and an amine-substituted salicylic acid to define the first, second and third binding sites. Particular MOFs may comprise 5,59′-(((1E,2E)-ethane-1,2-diylidene)bis-(azaneylylidene))bis(2-hydroxybenzoic acid) as a multidentate organic ligand.
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公开(公告)号：US11939225B2
公开(公告)日：2024-03-26
申请号：US17285546
申请日：2019-11-01
Inventor： Joseph M. Falkowski , Hilda Bouza Vroman , Allen W. Burton , Eugene Terefenko , Kanmi Mao , Karl G. Strohmaier
IPC: B01J20/18 , B01D53/047 , C01B39/48
CPC classification number: C01B39/48 , B01D53/047 , B01J20/186 , B01D2253/116 , B01D2253/306 , B01D2253/311 , B01D2256/245 , B01D2257/504 , C01P2002/72 , C01P2002/74 , C01P2006/12 , C01P2006/14 , C01P2006/16
Abstract: A composition can include a Rho zeolite with a RHO topology having a Si to B ratio or a Si to Al ratio greater than or equal to 8. Making such a composition can include heating an aqueous reaction mixture having a molar ratio of atomic Si to atomic B of about 4 to about 50 or a molar ratio of atomic Si to atomic Al of about 4 to about 50 in the presence of a C4-C6 diquat of N,2-dimethylbenzimidazole structure directing agent to a temperature of at least 75° C. to produce a Rho zeolite.
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公开(公告)号：US11865515B2
公开(公告)日：2024-01-09
申请号：US17457677
申请日：2021-12-06
Inventor： Brian M. Weiss , Sophie Liu , Joseph M. Falkowski , Marc R. Schreier , Herb W. Barry
IPC: B01J21/04 , B01J21/10 , B01J23/00 , B01J23/02 , B01J23/10 , B01J23/30 , B01J23/32 , B01J23/34 , B01J37/02 , C07C5/333
CPC classification number: B01J23/32 , B01J23/002 , B01J23/005 , B01J23/02 , B01J23/30 , B01J37/0215 , C07C5/3332 , B01J21/04 , B01J21/10 , B01J2523/12 , B01J2523/22 , B01J2523/31 , B01J2523/69 , B01J2523/72 , C07C2523/02 , C07C2523/30 , C07C2523/32
Abstract: An active material useful in an oxidative dehydrogenation reactor system has an active phase, and a mixed metal oxide support phase. The active phase includes a transition metal oxide such as manganese oxide, which is reversibly oxidizable and/or reducible between oxidized and reduced states. The support phase includes a mixed metal oxide of a two or more IUPAC Group 2-14 elements. The active phase can also include a promoter such as Na-WO4 and/or a selectivity modifier such as Al or ceria. Also, a reactor including the active material in a reactor, a method of making the active material, and a method of using the active material in a regenerative reaction process.
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Patent Agency Ranking
公开(公告)号：US20230121414A1
公开(公告)日：2023-04-20
申请号：US17760339
申请日：2021-01-19
Inventor： Pavel V. Kortunov , Joseph M. Falkowski
Abstract: Methods of contacting a fluid comprising a light hydrocarbon with a metal-organic framework adsorbent having bis(pyrazolyl) ethanediimine ligands and internal pores; adsorbing the fluid in at least a portion of the internal pores of the metal-organic framework thereby creating an adsorbed fluid; storing the adsorbed fluid in the internal pores of the metal-organic framework; and releasing the adsorbed fluid from the internal pores of the metal-organic framework, wherein the metal-organic framework adsorbent undertakes a reversible phase transition upon adsorbing the fluid. Systems of a metal-organic framework having bis(pyrazolyl) ethanediimine ligands and internal pores, wherein the metal-organic framework undertakes a reversible phase transition upon adsorption and desorption of a light hydrocarbon fluid; wherein the fluid is stored in the internal pores of the metal-organic framework.
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公开(公告)号：US12269750B2
公开(公告)日：2025-04-08
申请号：US18040403
申请日：2020-08-07
Inventor： Allen W. Burton , Hilda B. Vroman , Joseph M. Falkowski
Abstract: An aluminosilicate zeolite may have a molar ratio of Si to Al of about 3 to about 10, a monoclinic space group C2/m with unit cell dimensions of a of 13.6 Å+/−5%, b of 21.7 Å+/−5%, c of 6.7 Å+/−5%, and β of 93°+/−3°, 12-ring pores along a c-axis having dimensions of 7 Å+/−5% by 6 Å+/−5%, and 8-ring pores along an a-axis having dimensions of 3 Å+/−5% by 3 Å+/−5%. Said aluminosilicate zeolites may be useful in hydrocarbon conversion processes, selective catalytic reduction of NOx, CO2 and/or N2 adsorption, carbonylation reactions, and the monoalkylamine and dialkylamine syntheses.
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公开(公告)号：US12129436B2
公开(公告)日：2024-10-29
申请号：US17755331
申请日：2020-07-22
Inventor： Changyub Paek , Joseph M. Falkowski , Randall D. Partridge , Yogesh V. Joshi , Carmen C. Lasso
CPC classification number: C10G25/003 , B01D15/426 , B01J20/226 , B01J20/3425 , B01J20/3475 , C10G25/12
Abstract: A process for separating one or more one-ring cycloparaffins and one or more multi-ring cycloparaffins from a hydrocarbon mixture is disclosed. The process comprises the steps of providing the hydrocarbon mixture; and contacting the hydrocarbon mixture with an adsorbent material comprising a metal organic framework to separate the one or more one-ring cycloparaffins and the one or more multi-ring cycloparaffins from the hydrocarbon mixture. The process is conducted in a liquid phase.
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公开(公告)号：US20240300983A1
公开(公告)日：2024-09-12
申请号：US18572039
申请日：2022-06-23
Inventor： Joseph M. Falkowski , Mary S. Abdulkarim
CPC classification number: C07F7/003 , B01J20/226 , B01J20/3078 , B01J20/3085 , B01J31/1691 , B01J37/031 , B01J37/04 , B01J37/08 , B01J2531/48 , B01J2531/49
Abstract: Provided herein are methods of making a metal-organic framework comprising: combining a pre-ligand with a metal source to provide a plurality of solid reactants; adding a solvent to the plurality of solid reactants to form a reaction mixture, wherein at least 50 wt % of the reaction mixture are the plurality of solid reactants; heating the reaction mixture wherein the pre-ligand is converted to a ligand in the reaction mixture and the ligand reacts with the metal component; and cooling the reaction mixture to produce the metal-organic framework. The present methodologies are performed without dimethylformamide in the reaction mixture. The present methods may further comprise the step of adding a crystallization aid such as zinc oxide to the reaction mixture.
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公开(公告)号：US20240278208A1
公开(公告)日：2024-08-22
申请号：US18572034
申请日：2022-06-23
Inventor： Joseph M. Falkowski , Mary S. Abdulkarim , Sophie Liu , Scott J. Weigel , Trong D. Pham
CPC classification number: B01J20/226 , B01J20/0225 , B01J20/0237 , B01J20/0244 , B01J20/0251 , B01J20/0288 , B01J20/0296 , B01J20/28066 , B01J20/28071 , B01J20/28073 , B01J20/28076 , B01J20/3085
Abstract: Provided are metal-organic frameworks made by the process of comprising the steps of reacting a first metal source that can generate a tetravalent metal cation in solution, a linear dicarboxylic acid, a second metal source that can generate a divalent cation in solution, and one or more monocarboxylic acid modulators in a solvent to provide a reaction solution. The reaction solution is heated to provide a metal-organic framework having between about 0 wt. % to 10 wt. % of divalent cation, surface area between about 1100 m2/g and 2700 m2/g, a porosity of between about 0.45 cc/g and 1.1 cc/g, and a relative intensity equal to or greater than 0.35 and a peak width ratio of less than 3.0.
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