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公开(公告)号：US12269750B2
公开(公告)日：2025-04-08
申请号：US18040403
申请日：2020-08-07
Inventor： Allen W. Burton , Hilda B. Vroman , Joseph M. Falkowski
Abstract: An aluminosilicate zeolite may have a molar ratio of Si to Al of about 3 to about 10, a monoclinic space group C2/m with unit cell dimensions of a of 13.6 Å+/−5%, b of 21.7 Å+/−5%, c of 6.7 Å+/−5%, and β of 93°+/−3°, 12-ring pores along a c-axis having dimensions of 7 Å+/−5% by 6 Å+/−5%, and 8-ring pores along an a-axis having dimensions of 3 Å+/−5% by 3 Å+/−5%. Said aluminosilicate zeolites may be useful in hydrocarbon conversion processes, selective catalytic reduction of NOx, CO2 and/or N2 adsorption, carbonylation reactions, and the monoalkylamine and dialkylamine syntheses.
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公开(公告)号：US20250025855A1
公开(公告)日：2025-01-23
申请号：US18910441
申请日：2024-10-09
Inventor： Ross MABON , Michael A. Marella , Allen W. Burton , Hilda B. Vroman , Kirk D. Schmitt , Tom Willhammar , Hongyi Xu , Xiaodong Zou , Simon C. Weston
Abstract: This disclosure relates to EMM-41 materials, methods for making it, and processes for its use. This disclosure also relates to the structure directing agents used in the methods for making the EMM-41 material as well as the synthesis method used to prepare such structure directing agents.
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公开(公告)号：US20250025854A1
公开(公告)日：2025-01-23
申请号：US18910399
申请日：2024-10-09
Inventor： Ross MABON , Michael A. Marella , Allen W. Burton , Hilda B. Vroman , Kirk D. Schmitt , Tom Willhammar , Hongyi Xu , Xiaodong Zou , Simon C. Weston
Abstract: This disclosure relates to EMM-41 materials, methods for making it, and processes for its use. This disclosure also relates to the structure directing agents used in the methods for making the EMM-41 material as well as the synthesis method used to prepare such structure directing agents.
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公开(公告)号：US11739274B2
公开(公告)日：2023-08-29
申请号：US17634962
申请日：2020-07-14
Inventor： Brandon J. O'Neill , Joseph M. Falkowski , Allen W. Burton , Scott J. Weigel
CPC classification number: C10G47/10 , B01J31/1691 , C10G2300/4006 , C10G2300/4012 , C10G2300/70 , C10G2400/02
Abstract: A hydrocarbon feed stream, particularly one comprising heavier hydrocarbons, may be converted to valuable products such as motor gasoline and/or lubricating oil by employing one or more MOF catalysts, which may be prepared from a precursor metal-organic framework (MOF). A MOF catalyst may be prepared by exchanging one or more organic linking ligands of the precursor MOF for an organic linking ligand having a different acidity and/or electron-withdrawing properties, which, in turn, may affect catalytic activity.
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公开(公告)号：US20240317594A1
公开(公告)日：2024-09-26
申请号：US18733491
申请日：2024-06-04
Inventor： Ross Mabon , Allen W. Burton , Hilda B. Vroman , Simon C. Weston
IPC: C01B39/48 , C07C211/09
CPC classification number: C01B39/48 , C07C211/09 , C01P2002/72
Abstract: A method can include heating an aqueous reaction mixture comprising a silicon source and a boron source and/or an aluminum source in the presence of a quaternary structure directing agent to a temperature of at least 75° C. to produce a zeolite. A composition can include a borosilicate zeolite, an aluminosilicate zeolite, or an aluminoborosilicate zeolite having a framework symmetry of C2/m and a unit cell with measurements of a of 3.5 Å to 4.5 Å, b of 20.1 Å to 21.1 Å, c of 15.5 to 16.5 Å, and β of 97° to 98°.
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Patent Agency Ranking
![USE OF 1-METHYL-6,7-DIHYDRO-5H-CYCLOPENTA[B]PYRIDINE-1-IUM CATION AS STRUCTURE DIRECTING AGENT FOR THE PREPARATION OF ZEOLITES AND ZEOLITES OBTAINED USING THE SAME](/abs-image/US/2025/01/09/US20250011177A1/abs.jpg.150x150.jpg)
公开(公告)号：US20250011177A1
公开(公告)日：2025-01-09
申请号：US18570389
申请日：2022-06-08
Inventor： Allen W. Burton , Stuart L. Soled , Hilda B. Vroman
IPC: C01B39/48 , B01J29/70 , B01J29/86 , B01J37/00 , B01J37/03 , B01J37/04 , B01J37/10 , C01B39/12 , C07D221/04
Abstract: This disclosure relates to the use of 1-methyl-6,7-dihydro-5H-cyclopenta[b]pyridine-1-ium cation as structure directing agent (SDA) for the preparation of zeolites. This disclosure also relates to compositions of matter, designated as EMM-64 and EMM-65, obtainably by using this SDA, as well as a method of making the same and uses thereof. This disclosure further relates to a method of making an aluminosilicate molecular sieve of RTH framework type using said SDA, aluminosilicate molecular sieves of RTH framework type obtainable by said method, and uses thereof.
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公开(公告)号：US20240400400A1
公开(公告)日：2024-12-05
申请号：US18690620
申请日：2022-08-11
Inventor： Allen W. Burton , Hilda B. Vroman , Trong D. Pham , Eugene A. Terefenko
IPC: C01B39/48
Abstract: Various zeolites may be produced under hydrothermal synthesis conditions in the presence of a silicon atom source and a bis-pyridinium compound having a structure represented by formula (I). Q is an optionally substituted C1-C10 hydrocarbyl group and two Q may join to form a carbocyclic ring; n is an integer ranging from 0 to 5; m is an integer ranging from 0 to 5; n+m is greater than or equal to 1; and A is a spacer group containing 2 to about 10 atoms.
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公开(公告)号：US12161990B2
公开(公告)日：2024-12-10
申请号：US17311394
申请日：2019-11-12
Inventor： Ross Mabon , Michael A. Marella , Allen W. Burton , Hilda B. Vroman , Kirk D. Schmitt , Tom Willhammar , Hongyi Xu , Xiaodong Zou , Simon C. Weston
Abstract: This disclosure relates to EMM-41 materials, methods for making it, and processes for its use. This disclosure also relates to the structure directing agents used in the methods for making the EMM-41 material as well as the synthesis method used to prepare such structure directing agents.
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公开(公告)号：US11939225B2
公开(公告)日：2024-03-26
申请号：US17285546
申请日：2019-11-01
Inventor： Joseph M. Falkowski , Hilda Bouza Vroman , Allen W. Burton , Eugene Terefenko , Kanmi Mao , Karl G. Strohmaier
IPC: B01J20/18 , B01D53/047 , C01B39/48
CPC classification number: C01B39/48 , B01D53/047 , B01J20/186 , B01D2253/116 , B01D2253/306 , B01D2253/311 , B01D2256/245 , B01D2257/504 , C01P2002/72 , C01P2002/74 , C01P2006/12 , C01P2006/14 , C01P2006/16
Abstract: A composition can include a Rho zeolite with a RHO topology having a Si to B ratio or a Si to Al ratio greater than or equal to 8. Making such a composition can include heating an aqueous reaction mixture having a molar ratio of atomic Si to atomic B of about 4 to about 50 or a molar ratio of atomic Si to atomic Al of about 4 to about 50 in the presence of a C4-C6 diquat of N,2-dimethylbenzimidazole structure directing agent to a temperature of at least 75° C. to produce a Rho zeolite.
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公开(公告)号：US20250001404A1
公开(公告)日：2025-01-02
申请号：US18251641
申请日：2021-08-26
Inventor： Sina Sartipi , Marc H. Anthonis , Scott J. Weigel , Allen W. Burton
Abstract: Disclosed is a method of synthesizing aluminum-rich molecular sieve of *MRE framework type, comprising the steps of preparing a synthesis mixture comprising at least one source of silica, at least one source of alumina having a low water solubility, at least one source of hydroxide ions, at least one source of alkali and/or alkaline earth metal M, at least one source of diquaternary alkylammonium structure directing agent R, water and optional seed crystals.
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