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1.发明授权公开(公告)号：US11873453B2
公开(公告)日：2024-01-16
申请号：US17664171
申请日：2022-05-19
Inventor： Randall D. Partridge , Changyub Paek , Yogesh V. Joshi , Carmen C. Lasso , Scott J. Weigel
CPC classification number: C10G25/03 , B01J20/18 , B01J20/2808 , B01J20/3408 , C10G21/28 , C10G25/12 , C10G2300/1037 , C10G2300/301 , C10G2300/302
Abstract: Provided herein are methods and systems of making a high quality isoparaffinic base stock which include contacting an adsorbent material with a hydrocarbon feedstock and a solvent and separating at least some of the one or more high VI components from the hydrocarbon feedstock to produce a first fraction base stock having a first fraction base stock viscosity index. The adsorbent material is desorbed with a second solvent to produce a second fraction base stock having a second fraction base stock viscosity index. In these methods, the first fraction base stock viscosity index is less than the hydrocarbon feedstock viscosity index and the second fraction base stock viscosity index is greater than the hydrocarbon feedstock viscosity index.
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2.发明申请公开(公告)号：US20220389331A1
公开(公告)日：2022-12-08
申请号：US17664171
申请日：2022-05-19
Inventor： Randall D. Partridge , Changyub Paek , Yogesh V. Joshi , Carmen C. Lasso , Scott J. Weigel
Abstract: Provided herein are methods and systems of making a high quality isoparaffinic base stock which include contacting an adsorbent material with a hydrocarbon feedstock and a solvent and separating at least some of the one or more high VI components from the hydrocarbon feedstock to produce a first fraction base stock having a first fraction base stock viscosity index. The adsorbent material is desorbed with a second solvent to produce a second fraction base stock having a second fraction base stock viscosity index. In these methods, the first fraction base stock viscosity index is less than the hydrocarbon feedstock viscosity index and the second fraction base stock viscosity index is greater than the hydrocarbon feedstock viscosity index.
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公开(公告)号：US12172146B2
公开(公告)日：2024-12-24
申请号：US17607168
申请日：2020-05-26
Inventor： Joseph M. Falkowski , Yogesh V. Joshi , Mary S. Abdulkarim , Simon C. Weston
Abstract: Metal-organic framework materials (MOFs) are highly porous entities comprising a multidentate organic ligand coordinated to multiple metal centers, typically as a coordination polymer. Some highly porous MOFs lack stability at ambient conditions. MOFs having ambient condition stability may comprise a plurality of metal clusters (M4O clusters, M=a metal), and a plurality of 4-(1H-pyrazol-4-yl)benzoate ligands coordinated to the plurality of metal clusters to define an at least partially crystalline network structure having a plurality of internal pores. Methods for synthesizing these MOFs may comprise combining a metal source, such as a preformed metal cluster, with 4-(1H-pyrazol-4-yl)benzoic acid, and reacting the preformed metal cluster with the 4-(1H-pyrazol-4-yl)benzoic acid to form a MOF having an at least partially crystalline network structure with a plurality of internal pores defined therein and comprising a plurality of metal clusters coordinated to a multidentate organic ligand comprising 4-(1H-pyrazol-4-yl)benzoate.
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公开(公告)号：US20240071575A1
公开(公告)日：2024-02-29
申请号：US17899271
申请日：2022-08-30
Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATION , EXXONMOBIL TECHNOLOGY AND ENGINEERING COMPANY
Inventor： Rodrigo Neumann Barros Ferreira , Ricardo Luis Ohta , Yogesh V. Joshi , Mathias B. Steiner , Tonia Elengikal , Binquan Luan , Ashish B. Mhadeshwar , Jayashree Kalyanaraman , Anantha Sundaram , Sumathy Raman
IPC: G16C20/30
CPC classification number: G16C20/30
Abstract: Ranking materials for post combustion carbon capture by characterizing sorbent materials with a molecular model workflow that generates microscopic figures of merit for materials by microscopic properties; and evaluating the materials from the molecular model workflow with a process model workflow that generates macroscopic figures of merit for process steps of a carbon recovery process. The materials for applicability as a sorbent material are ranked using a combined microscopic performance and macroscopic process feasibility generator that ranks the materials according to the microscopic figures of merit for materials and the macroscopic figures of merit for the process steps.
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公开(公告)号：US11634371B2
公开(公告)日：2023-04-25
申请号：US17457731
申请日：2021-12-06
Inventor： Changyub Paek , Randall D. Partridge , Yogesh V. Joshi , Jayashree Kalyanaraman , Joseph M. Falkowski
Abstract: A method for separating classes of hydrocarbon compounds from a feed stream including a hydrocarbon mixture is disclosed. The method includes the steps of passing a feed stream through a plurality of separation units arranged in a series in any order, wherein each separation unit has an adsorbent material; and separating classes of hydrocarbon compounds from the feed stream. When one of the plurality of separation units comprises an adsorbent material that is a metal organic framework selected from a zirconium, hafnium, cerium, or titanium-based metal organic framework, then another plurality of separation units includes an adsorption material that is different from the metal organic framework. The method is conducted in a liquid phase. The method can also use a single separation unit with a continuous cyclic bed apparatus. The method can be combined with refining and downstream processes.
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Patent Agency Ranking
公开(公告)号：US12129436B2
公开(公告)日：2024-10-29
申请号：US17755331
申请日：2020-07-22
Inventor： Changyub Paek , Joseph M. Falkowski , Randall D. Partridge , Yogesh V. Joshi , Carmen C. Lasso
CPC classification number: C10G25/003 , B01D15/426 , B01J20/226 , B01J20/3425 , B01J20/3475 , C10G25/12
Abstract: A process for separating one or more one-ring cycloparaffins and one or more multi-ring cycloparaffins from a hydrocarbon mixture is disclosed. The process comprises the steps of providing the hydrocarbon mixture; and contacting the hydrocarbon mixture with an adsorbent material comprising a metal organic framework to separate the one or more one-ring cycloparaffins and the one or more multi-ring cycloparaffins from the hydrocarbon mixture. The process is conducted in a liquid phase.
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7.发明公开公开(公告)号：US20230287278A1
公开(公告)日：2023-09-14
申请号：US17664177
申请日：2022-05-19
Inventor： Changyub Paek , Joseph M. Falkowski , Yogesh V. Joshi , Carmen C. Lasso
IPC: C10G25/00
CPC classification number: C10G25/003 , C10G2300/1062 , C10G2400/10
Abstract: This disclosure provides methods for separating multi-ring naphthenes from a hydrocarbon feedstock. The hydrocarbon feedstock includes at least normal paraffins, isoparaffins, 1-ring naphthenes attached with a paraffinic alkyl chain, and multi-ring naphthenes. The methods comprise passing the hydrocarbon feedstock and a solvent, at a temperature and pressure through a bed of an adsorbent comprising a metal-organic framework (MOF) adsorbent, to adsorb the multi-ring naphthenes from the hydrocarbon feedstock, thereby producing a base stock product that is depleted in multi-ring naphthenes. The metal-organic framework adsorbent is a porous crystalline material comprised of metal functionalities connected by organic linkers to form a repeating 2-D or 3-D lattice. The base stock product has a viscosity index (VI) greater than the viscosity index of the hydrocarbon feedstock. The methods of this disclosure upgrade Group II base stocks (also Group II+ base stocks) to Group III or Group III+ base stocks, and also upgrade Group III base stocks to Group III+ base stocks.
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8.发明授权公开(公告)号：US12203034B2
公开(公告)日：2025-01-21
申请号：US17664177
申请日：2022-05-19
Inventor： Changyub Paek , Joseph M. Falkowski , Yogesh V. Joshi , Carmen C. Lasso
Abstract: This disclosure provides methods for separating multi-ring naphthenes from a hydrocarbon feedstock. The hydrocarbon feedstock includes at least normal paraffins, isoparaffins, 1-ring naphthenes attached with a paraffinic alkyl chain, and multi-ring naphthenes. The methods comprise passing the hydrocarbon feedstock and a solvent, at a temperature and pressure through a bed of an adsorbent comprising a metal-organic framework (MOF) adsorbent, to adsorb the multi-ring naphthenes from the hydrocarbon feedstock, thereby producing a base stock product that is depleted in multi-ring naphthenes. The metal-organic framework adsorbent is a porous crystalline material comprised of metal functionalities connected by organic linkers to form a repeating 2-D or 3-D lattice. The base stock product has a viscosity index (VI) greater than the viscosity index of the hydrocarbon feedstock. The methods of this disclosure upgrade Group II base stocks (also Group II+ base stocks) to Group III or Group III+ base stocks, and also upgrade Group III base stocks to Group III+ base stocks.
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公开(公告)号：US12036539B2
公开(公告)日：2024-07-16
申请号：US17621281
申请日：2020-05-28
Inventor： Joseph M. Falkowski , Yogesh V. Joshi , Mary S. Abdulkarim , Simon C. Weston
CPC classification number: B01J31/1691 , B01J35/617 , B01J35/618 , B01J35/633 , B01J35/635 , B01J35/643 , B01J35/647 , B01J37/04 , B01J37/30 , C07C5/03 , C07F3/06 , B01J2231/645 , B01J2531/0205 , B01J2531/0211 , B01J2531/0238 , B01J2531/26 , B01J2531/72 , B01J2531/845 , B01J2531/847 , C07C2531/22
Abstract: Metal-organic framework materials (MOFs) are highly porous entities comprising a multidentate organic ligand coordinated to multiple metal centers. MOFs having ambient condition stability may comprise a plurality of metal clusters comprising one or more M4O clusters (M is a metal), and a plurality of 4-pyrazolecarboxylate ligands coordinated to the plurality of metal clusters to define an at least partially crystalline network structure having a plurality of internal pores. The MOFs may have a Pa3 symmetry, which upon activation may convert into Fm3m symmetry. Methods for synthesizing the MOFs may comprise combining a metal source, such as a preformed metal cluster, with 4-pyrazolecarboxylic acid, and reacting the preformed metal cluster with the 4-pyrazolecarboxylic acid to form a MOF having an at least partially crystalline network structure with a plurality of internal pores defined therein and comprising a plurality of metal clusters coordinated to a multidentate organic ligand comprising 4-pyrazolecarboxylate.
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公开(公告)号：US20230357650A1
公开(公告)日：2023-11-09
申请号：US17755331
申请日：2020-07-22
Inventor： Changyub Paek , Joseph M. Falkowski , Randall D. Partridge , Yogesh V. Joshi , Carmen C. Lasso
CPC classification number: C10G25/003 , B01J20/226 , B01J20/3475 , B01J20/3425 , C10G25/12 , B01D15/426
Abstract: A process for separating one or more one-ring cycloparaffins and one or more multi-ring cycloparaffins from a hydrocarbon mixture is disclosed. The process comprises the steps of providing the hydrocarbon mixture; and contacting the hydrocarbon mixture with an adsorbent material comprising a metal organic framework to separate the one or more one-ring cycloparaffins and the one or more multi-ring cycloparaffins from the hydrocarbon mixture. The process is conducted in a liquid phase.
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