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公开(公告)号:US20250001404A1
公开(公告)日:2025-01-02
申请号:US18251641
申请日:2021-08-26
Inventor: Sina Sartipi , Marc H. Anthonis , Scott J. Weigel , Allen W. Burton
Abstract: Disclosed is a method of synthesizing aluminum-rich molecular sieve of *MRE framework type, comprising the steps of preparing a synthesis mixture comprising at least one source of silica, at least one source of alumina having a low water solubility, at least one source of hydroxide ions, at least one source of alkali and/or alkaline earth metal M, at least one source of diquaternary alkylammonium structure directing agent R, water and optional seed crystals.
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公开(公告)号:US11542446B2
公开(公告)日:2023-01-03
申请号:US16540107
申请日:2019-08-14
Inventor: Preeti Kamakoti , Scott J. Weigel , Stephen J. McCarthy , Shifang L. Luo , Sina Sartipi , Martine Dictus , Marc H. Anthonis , Helge Jaensch
Abstract: Methods are provided for using a molecular sieve catalyst for dewaxing formed using a synthesis mixture comprising a morphology modifier. The catalyst may be used, for example, for production of a lubricant base stock. For example, ZSM-48 crystals formed using the morphology modifier (and/or formulated catalysts made using such crystals) can have an increased activity and/or can provide an improved yield during catalytic dewaxing of lubricant base stocks.
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公开(公告)号:US20240278208A1
公开(公告)日:2024-08-22
申请号:US18572034
申请日:2022-06-23
Inventor: Joseph M. Falkowski , Mary S. Abdulkarim , Sophie Liu , Scott J. Weigel , Trong D. Pham
CPC classification number: B01J20/226 , B01J20/0225 , B01J20/0237 , B01J20/0244 , B01J20/0251 , B01J20/0288 , B01J20/0296 , B01J20/28066 , B01J20/28071 , B01J20/28073 , B01J20/28076 , B01J20/3085
Abstract: Provided are metal-organic frameworks made by the process of comprising the steps of reacting a first metal source that can generate a tetravalent metal cation in solution, a linear dicarboxylic acid, a second metal source that can generate a divalent cation in solution, and one or more monocarboxylic acid modulators in a solvent to provide a reaction solution. The reaction solution is heated to provide a metal-organic framework having between about 0 wt. % to 10 wt. % of divalent cation, surface area between about 1100 m2/g and 2700 m2/g, a porosity of between about 0.45 cc/g and 1.1 cc/g, and a relative intensity equal to or greater than 0.35 and a peak width ratio of less than 3.0.
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公开(公告)号:US11739274B2
公开(公告)日:2023-08-29
申请号:US17634962
申请日:2020-07-14
Inventor: Brandon J. O'Neill , Joseph M. Falkowski , Allen W. Burton , Scott J. Weigel
CPC classification number: C10G47/10 , B01J31/1691 , C10G2300/4006 , C10G2300/4012 , C10G2300/70 , C10G2400/02
Abstract: A hydrocarbon feed stream, particularly one comprising heavier hydrocarbons, may be converted to valuable products such as motor gasoline and/or lubricating oil by employing one or more MOF catalysts, which may be prepared from a precursor metal-organic framework (MOF). A MOF catalyst may be prepared by exchanging one or more organic linking ligands of the precursor MOF for an organic linking ligand having a different acidity and/or electron-withdrawing properties, which, in turn, may affect catalytic activity.
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公开(公告)号:US20240093100A1
公开(公告)日:2024-03-21
申请号:US18271369
申请日:2022-01-24
Inventor: William J. Knaeble , Scott J. Weigel , Preeti Kamakoti
IPC: C10G45/64 , B01J21/04 , B01J29/74 , B01J29/80 , B01J35/00 , B01J35/02 , B01J35/08 , B01J35/10 , B01J37/00 , B01J37/02 , B01J37/08 , B01J37/10 , B01J37/18
CPC classification number: C10G45/64 , B01J21/04 , B01J29/7461 , B01J29/7469 , B01J29/80 , B01J35/0006 , B01J35/0066 , B01J35/026 , B01J35/08 , B01J35/1019 , B01J35/1057 , B01J37/0009 , B01J37/0201 , B01J37/08 , B01J37/10 , B01J37/18 , B01J2229/16 , B01J2229/186 , B01J2229/36
Abstract: Provided herein are catalysts for dewaxing of a feedstock, the catalyst comprising between about 40 wt. % and about 99.9 wt. % zeolite, between about 0 wt. % and about 40 wt. % binder and at least about 0.1 wt. % noble metal, as well as catalyst systems, methods and products produced using the catalysts. The zeolite having a crystal comprising a largest included sphere less than or equal to about 7.5 angstroms, a largest diffusing sphere greater than or equal to about 5.0 angstroms, and a silica to alumina ratio greater than or equal to about 100:1. The catalyst having a temperature-programmed ammonia desorption (“TPAD”) of less than about 0.25 mmol/g.
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6.
公开(公告)号:US11873453B2
公开(公告)日:2024-01-16
申请号:US17664171
申请日:2022-05-19
Inventor: Randall D. Partridge , Changyub Paek , Yogesh V. Joshi , Carmen C. Lasso , Scott J. Weigel
CPC classification number: C10G25/03 , B01J20/18 , B01J20/2808 , B01J20/3408 , C10G21/28 , C10G25/12 , C10G2300/1037 , C10G2300/301 , C10G2300/302
Abstract: Provided herein are methods and systems of making a high quality isoparaffinic base stock which include contacting an adsorbent material with a hydrocarbon feedstock and a solvent and separating at least some of the one or more high VI components from the hydrocarbon feedstock to produce a first fraction base stock having a first fraction base stock viscosity index. The adsorbent material is desorbed with a second solvent to produce a second fraction base stock having a second fraction base stock viscosity index. In these methods, the first fraction base stock viscosity index is less than the hydrocarbon feedstock viscosity index and the second fraction base stock viscosity index is greater than the hydrocarbon feedstock viscosity index.
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公开(公告)号:US20240359168A1
公开(公告)日:2024-10-31
申请号:US18770255
申请日:2024-07-11
Inventor: Tilman W. Beutel , Gerardo J. Majano Sanchez , Walter Weissman , Brian M. Weiss , Himanshu Gupta , John F. Brody , Scott J. Weigel
CPC classification number: B01J29/7088 , B01J35/30 , B01J35/617 , B01J35/633 , B01J35/635 , B01J37/0215 , B01J2229/62
Abstract: The present disclosure provides mesoporous catalyst compounds and compositions having one or more group 13 atoms. The present disclosure further relates to processes for converting hydrocarbon feedstocks to small olefins. In one aspect, a catalyst compound includes a zeolite having a structural type selected from MFI, MSE, MTW, Theta-One (TON), Ferrierite (FER), AFI, AFS, ATO, BEA, BEC, BOG, BPH, CAN, CON, EMT, EON, EZT, FAU, GME, GON, IFR, ISV, ITN, IWR, IWW, LTL, MAZ, MEI, MOR, MOZ, OFF, OKO, OSI, SAF, SAO, SEW, SFE, SFO, SSF, SSY, and USI, or a combination thereof, the zeolite having a silicon to aluminum molar ratio (Si/Al ratio) of from about 5 to about 40. In one aspect, a catalyst composition includes the catalyst compound and one or more group 13 metal.
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公开(公告)号:US12030845B2
公开(公告)日:2024-07-09
申请号:US17807024
申请日:2022-06-15
Inventor: Wesley Sattler , Jihad M. Dakka , Guang Cao , Xinrui Yu , Brandon M. Carcuffe , Jason M. Golias , Scott J. Weigel , Carolyn M. Aimino , Megan E. Witzke
CPC classification number: C07C5/2705 , B01J21/066 , B01J23/002 , B01J23/30 , C07C2521/06 , C07C2523/30
Abstract: Isomerization of normal paraffins to form branched paraffins may be complicated by significant cracking of C7+ paraffins under isomerization reaction conditions. This issue may complicate upgrading of hydrocarbon feeds having significant quantities of heavier normal paraffins. Cracking selectivity may be decreased by combining one or more naphthenic compounds with a feed mixture comprising at least one C7+ normal paraffin and/or by utilizing tungstated zirconium catalysts having decreased tungsten loading. Further, C5 and C6 normal paraffins may undergo isomerization in the presence of C7+ normal paraffins. Methods for isomerizing normal paraffins may comprise: providing a feed mixture comprising at least C5-C7 normal paraffins and lacking normal paraffins larger than C8; and contacting the feed mixture with a bifunctional mixed metal oxide catalyst under isomerization reaction conditions effective to form a product mixture comprising one or more branched paraffins formed from each of the C5-C7 normal paraffins.
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公开(公告)号:US20220402838A1
公开(公告)日:2022-12-22
申请号:US17807024
申请日:2022-06-15
Inventor: Wesley Sattler , Jihad M. Dakka , Guang Cao , Xinrui Yu , Brandon M. Carcuffe , Jason M. Golias , Scott J. Weigel , Carolyn M. Aimino , Megan E. Witzke
Abstract: Isomerization of normal paraffins to form branched paraffins may be complicated by significant cracking of C7+ paraffins under isomerization reaction conditions. This issue may complicate upgrading of hydrocarbon feeds having significant quantities of heavier normal paraffins. Cracking selectivity may be decreased by combining one or more naphthenic compounds with a feed mixture comprising at least one C7+ normal paraffin and/or by utilizing tungstated zirconium catalysts having decreased tungsten loading. Further, C5 and C6 normal paraffins may undergo isomerization in the presence of C7+ normal paraffins. Methods for isomerizing normal paraffins may comprise: providing a feed mixture comprising at least C5-C7 normal paraffins and lacking normal paraffins larger than C8; and contacting the feed mixture with a bifunctional mixed metal oxide catalyst under isomerization reaction conditions effective to form a product mixture comprising one or more branched paraffins formed from each of the C5-C7 normal paraffins.
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10.
公开(公告)号:US20220389331A1
公开(公告)日:2022-12-08
申请号:US17664171
申请日:2022-05-19
Inventor: Randall D. Partridge , Changyub Paek , Yogesh V. Joshi , Carmen C. Lasso , Scott J. Weigel
Abstract: Provided herein are methods and systems of making a high quality isoparaffinic base stock which include contacting an adsorbent material with a hydrocarbon feedstock and a solvent and separating at least some of the one or more high VI components from the hydrocarbon feedstock to produce a first fraction base stock having a first fraction base stock viscosity index. The adsorbent material is desorbed with a second solvent to produce a second fraction base stock having a second fraction base stock viscosity index. In these methods, the first fraction base stock viscosity index is less than the hydrocarbon feedstock viscosity index and the second fraction base stock viscosity index is greater than the hydrocarbon feedstock viscosity index.
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