公开(公告)号：WO2007109518A3

公开(公告)日：2008-01-24

申请号：PCT/US2007064126

申请日：2007-03-16

Applicant: GEN ELECTRIC ,  CELLA JAMES ANTHONY ,  LEWIS LARRY NEIL

Inventor： CELLA JAMES ANTHONY ,  LEWIS LARRY NEIL

IPC: C07C25/18 ,  C07C25/24 ,  C08G61/10 ,  C08G77/04

CPC classification number: C08G77/38 ,  C08G61/02 ,  C08G77/42 ,  C09K11/06 ,  C09K2211/1416 ,  H01L51/0039 ,  H01L51/0094 ,  H01L51/5012 ,  H05B33/14

Abstract: Optoelectronic devices include a polymer composition derived from reaction between a hydrosiloxane and a polyfluorene comprising structural units of formula (I) wherein R 1 and R 2 are independently alkyl, substituted alkyl, alkenyl, alkynyl, substituted alkenyl, substituted alkynyl, alkyloxy, substituted alkoxy, alkenoxy, alkynoxy, substituted alkenoxy, substituted alkynoxy, or a combination thereof; Ar 1 and Ar 2 are independently aryl or substituted aryl; m and n are independently 0 or 1 ; and at least one of R 1 and R 2 is alkenyl, alkynyl, substituted alkenyl, or substituted alkynyl.

Abstract translation: 光电子器件包括衍生自包含式（I）的结构单元的氢硅氧烷和聚芴之间的反应的聚合物组合物，其中R 1和R 2独立地是烷基，取代的烷基， 烯基，炔基，取代的烯基，取代的炔基，烷氧基，取代的烷氧基，烯氧基，炔氧基，取代的烯氧基，取代的炔氧基或其组合; Ar 1和Ar 2独立地是芳基或取代的芳基; m和n独立地为0或1; 并且R 1和R 2中的至少一个是烯基，炔基，取代的烯基或取代的炔基。

公开(公告)号：WO03024939A3

公开(公告)日：2003-10-02

申请号：PCT/US0224458

申请日：2002-07-31

Applicant: GEN ELECTRIC

Inventor： BROWN STERLING BRUCE ,  BRACK HANS PETER ,  CELLA JAMES ANTHONY ,  KARLIK DENNIS

IPC: C08G85/00 ,  C07D251/26 ,  C07D251/34 ,  C07D405/12 ,  C07D405/14 ,  C07D251/32

CPC classification number: C07D405/12 ,  C07D251/26 ,  C07D251/34 ,  C07D405/14 ,  C08G65/485

Abstract: In various embodiments the present invention comprises 2,4,6-trisubstituted-1,3,5-triazine capping agents comprising one, two, or three leaving groups as substituents with any remaining substituents being essentially inert to reaction with a nucleophilic group on a polymer or monomer, or reactive with a nucleophilic group on a polymer or monomer at a slower rate than any leaving group. The invention also comprises polymers or monomers with nucleophilic groups capped with a triazine moiety. Still other embodiments of the invention comprise processes for capping nucleophilic groups in a polymer or monomer which comprises combining and reacting the polymer or monomer with a triazine-comprising capping agent.

Abstract translation: 在各种实施方案中，本发明包含2,4,6-三取代-1,3,5-三嗪封端剂，其包含一个，两个或三个离去基团作为取代基，其中任何残留的取代基基本上与在亲核基团上反应的惰性基团 聚合物或单体，或者与聚合物或单体上的亲核基团以比任何离去基团更慢的速率反应。 本发明还包括具有用三嗪部分封端的亲核基团的聚合物或单体。 本发明的其它实施方案包括在聚合物或单体中封端亲核基团的方法，其包括将聚合物或单体与含三嗪的封端剂混合并使其反应。

公开(公告)号：WO2008014037A2

公开(公告)日：2008-01-31

申请号：PCT/US2007068620

申请日：2007-05-10

Applicant: GEN ELECTRIC ,  SHIANG JOSEPH JOHN ,  LITZ KYLE ERIK ,  CELLA JAMES ANTHONY ,  CHICHAK KELLY SCOTT ,  YE QING

Inventor： SHIANG JOSEPH JOHN ,  LITZ KYLE ERIK ,  CELLA JAMES ANTHONY ,  CHICHAK KELLY SCOTT ,  YE QING

IPC: C07F15/00 ,  C09K11/06

CPC classification number: C07F15/0033 ,  H01L51/0035 ,  H01L51/0043 ,  H01L51/0061 ,  H01L51/0085 ,  H01L51/5012 ,  Y02E10/549 ,  Y10S428/917

Abstract: The present invention provides compositions comprising at least one novel organic iridium compound which comprises at least one cyclometallated ligand and at least one ketopyrrole ligand. The organic iridium compositions of the present invention are referred to as Type (1) organic iridium compositions and are constituted such that no ligand of the novel organic iridium compound has a number average molecular weight of 2,000 grams per mole or greater (as measured by gel permeation chromatography). Type (1) organic iridium compositions are referred to herein as comprising "organic iridium complexes". The novel organic iridium compositions are useful in optoelectronic electronic devices such as OLED devices and photovoltaic devices. In one aspect, the invention provides novel organic iridium compositions useful in the preparation of OLED devices exhibiting enhanced color properties and light output efficiencies.

Abstract translation: 本发明提供包含至少一种新型有机铱化合物的组合物，其包含至少一个环金属化配体和至少一个酮吡咯配体。 本发明的有机铱组合物被称为（1）型有机铱组合物，并且构成为使新型有机铱化合物的配体不具有2,000克/摩尔或更大的数均分子量（如通过凝胶 渗透色谱法）。 类型（1）有机铱组合物在本文中被称为包含“有机铱配合物”。 新颖的有机铱组合物可用于光电子电子器件如OLED器件和光伏器件。 一方面，本发明提供了用于制备显示增强的颜色性质和光输出效率的OLED器件的新型有机铱组合物。

公开(公告)号：WO02053623A2

公开(公告)日：2002-07-11

申请号：PCT/US0149211

申请日：2001-12-21

Applicant: GEN ELECTRIC

Inventor： BRACK HANS-PETER ,  BRUNELLE DANIEL JOSEPH ,  CELLA JAMES ANTHONY ,  KARLIK DENNIS

IPC: C07C69/96 ,  C08G64/06 ,  C08G64/30 ,  C08G64/00

CPC classification number: C08G64/307

Abstract: A process for the production of polycarbonate be melt-polycondensing an aromatic dihydroxy compound and diphenylcarbonate, the process comprising adding to the polycarbonate under melt conditions a compound of the formula (I) wherein R1 and R3 may be the same or different and are selected from the group consisting of alkoxy, phenoxy, benzoxy, aryloxy, phenyl and aryl groups, R2 is selected from the group consisting of alkyl, phenyl, aryl, or aralkyl groups.

Abstract translation: 制备聚碳酸酯的方法是使芳族二羟基化合物和碳酸二苯酯熔融缩聚，该方法包括在熔融条件下向聚碳酸酯中加入式（I）化合物，其中R 1和R 3可以相同或不同，并且选自 由烷氧基，苯氧基，苯氧基，芳氧基，苯基和芳基组成的基团，R2选自烷基，苯基，芳基或芳烷基。

公开(公告)号：WO2007111763A2

公开(公告)日：2007-10-04

申请号：PCT/US2007000629

申请日：2007-01-10

Applicant: GEN ELECTRIC ,  LIU JIE ,  CELLA JAMES ANTHONY ,  LEWIS LARRY NEIL ,  DUGGAL ANIL RAJ ,  SPIVACK JAMES LAWRENCE ,  YE QING

Inventor： LIU JIE ,  CELLA JAMES ANTHONY ,  LEWIS LARRY NEIL ,  DUGGAL ANIL RAJ ,  SPIVACK JAMES LAWRENCE ,  YE QING

IPC: H01L51/54

CPC classification number: H01L51/5012 ,  C09K11/06 ,  H01L51/4206 ,  H01L51/5032 ,  H01L51/5092 ,  H01L2251/564 ,  H05B33/14 ,  H05B33/20 ,  Y02E10/549

Abstract: Described herein is an organic opto-electronic device comprising a cathode comprising at least one zero-valent metal; an anode; an opto-electronically active organic material; wherein said cathode is in contact with at least one organic ammonium salt. In certain embodiments, the organic ammonium salt has structure (I), wherein R 1 -R 4 are independently at each occurrence a C 1 -C 20 aliphatic radical, a C 3- C 20 cycloaliphatic radical, or a C 3 -C 2O aromatic radical is disclosed and wherein X - is selected from the group consisting of monovalent inorganic anions, monovalent organic anions, polyvalent inorganic anions, polyvalent organic anions, and mixtures thereof.

Abstract translation: 本文描述的是一种有机光电子器件，其包括：包含至少一种零价金属的阴极; 阳极; 光电活性有机材料; 其中所述阴极与至少一种有机铵盐接触。 在某些实施方案中，有机铵盐具有结构（I），其中R 1 -R 4 - 在每次出现时独立地为C 1〜 C 20脂肪族基团，C 3 -C 20脂环族基团或C 3 -C 3亚烷基 > OO 2芳族基团，其中X为 - 选自一价无机阴离子，一价有机阴离子，多价无机阴离子，多价有机阴离子及其混合物。

公开(公告)号：WO2006026421A3

公开(公告)日：2007-02-01

申请号：PCT/US2005030390

申请日：2005-08-25

Applicant: GEN ELECTRIC ,  CELLA JAMES ANTHONY ,  COLOMBO DANIEL GERARD ,  KAPUSTA CHRISTOPHER JAMES

Inventor： CELLA JAMES ANTHONY ,  COLOMBO DANIEL GERARD ,  KAPUSTA CHRISTOPHER JAMES

IPC: C08J3/24 ,  C08J5/18 ,  C08L69/00 ,  G02F1/361

CPC classification number: C08J5/18 ,  C08G64/045 ,  C08J2369/00 ,  C08K5/0025 ,  G02F1/3615

Abstract: Crosslinkable polymeric materials are disclosed useful for the temporal stabilization of a poling- induced noncentrosymmetric host lattice containing guest nonlinear optical chromophores . The materials are also suitable as, crosslinkable coatings in the absence of chromophores. Also disclosed is a method of srosslinking such polymeric material comprising reacting i)a crosslinkable polymeric material comprising olefin groups and ii) a crosslinking agent comprising electron deficient olefin groups, at a temperature at which crosslinking occurs.

Abstract translation: 公开了可交联聚合材料，其用于包含客体非线性光学发色团的极化诱导的非中心对称主体晶格的时间稳定性。 在不存在发色团的情况下，这些材料也适合作为可交联涂层。 还公开了一种交联这种聚合材料的方法，包括使i）包含烯烃基团的可交联聚合物材料和ii）在发生交联的温度下包含电子缺陷烯烃基团的交联剂。

公开(公告)号：WO02060855A2

公开(公告)日：2002-08-08

申请号：PCT/US0149472

申请日：2001-12-26

Applicant: GEN ELECTRIC

Inventor： BRACK HANS PETER ,  CELLA JAMES ANTHONY ,  KARLIK DENNIS ,  PRADA LINA

IPC: C08G64/14 ,  C08G64/30 ,  C07C68/00

CPC classification number: C08G64/14 ,  C08G64/307

Abstract: A process for the production of polycarbonate having increased end-cap levels, the process comprising adding a terminal blocking agent of formula (I), wherein R1 is a propoxy or butoxy and R2 is selected from the group consisting of C1-C30 alkyl, C1-C30 alkoxy, C6-C30 aryl, C7-C30 aralkyl, and C6-C30 aryloxy.

Abstract translation: 一种生产具有增加的端帽水平的聚碳酸酯的方法，该方法包括加入式（I）的封端剂，其中R1是丙氧基或丁氧基，R2选自C1-C30烷基，C1 -C30烷氧基，C6-C30芳基，C7-C30芳烷基和C6-C30芳氧基。

公开(公告)号：WO2010044940A2

公开(公告)日：2010-04-22

申请号：PCT/US2009051476

申请日：2009-07-23

Applicant: GEN ELECTRIC ,  CELLA JAMES ANTHONY ,  SHIANG JOSEPH JOHN ,  SHANKLIN ELLIOTT WEST ,  SMIGELSKI PAUL MICHAEL JR

Inventor： CELLA JAMES ANTHONY ,  SHIANG JOSEPH JOHN ,  SHANKLIN ELLIOTT WEST ,  SMIGELSKI PAUL MICHAEL JR

IPC: C07C39/42 ,  C07C43/225 ,  C07D295/088 ,  C07F5/02 ,  C09K11/00

CPC classification number: C07F5/025 ,  C07C39/42 ,  C07C43/225 ,  C07C2603/18 ,  C07D295/088 ,  C09K11/06 ,  C09K2211/1416 ,  C09K2211/1425 ,  H05B33/14

Abstract: Polyfluorene polymers and copolymers having substantial amounts (10-100%) of fluorenes coupled at the 2 and 5 positions of fluorene are useful as active layers in OLED devices where triplet energies > 2.10 eV are required.

Abstract translation: 在芴的2和5位上具有大量（10-100％）芴的聚芴聚合物和共聚物可用作需要三元组能量> 2.10eV的OLED器件中的有源层。

公开(公告)号：WO2007067407A3

公开(公告)日：2007-11-22

申请号：PCT/US2006045852

申请日：2006-12-01

Applicant: GEN ELECTRIC ,  LIU JIE ,  CELLA JAMES ANTHONY ,  YAN MIN ,  DUGGAL ANIL RAJ ,  HERZOG MICHAEL SCOTT ,  ROGOJEVIC SVETLANA ,  PARTHASARATHY GAUTAM

Inventor： LIU JIE ,  CELLA JAMES ANTHONY ,  YAN MIN ,  DUGGAL ANIL RAJ ,  HERZOG MICHAEL SCOTT ,  ROGOJEVIC SVETLANA ,  PARTHASARATHY GAUTAM

IPC: H01L51/52

CPC classification number: H01L51/5048 ,  H01B1/06 ,  H01L51/0059 ,  H01L51/5221 ,  H01L2251/5323 ,  H05B33/28 ,  Y10T428/31938

Abstract: Described herein is a transparent electrode comprising at least one optically transparent electrically conductive layer; and at least one optically transparent intermediate layer, wherein said optically transparent conductive layer is in contact with said optically intermediate layer, and wherein said optically transparent conductive layer and said optically transparent intermediate layer together transmit at least 50 percent of incident light having a wavelength in a range between about 200 and about 1200 nanometers, said optically transparent conductive layer having a bulk conductivity at least 100 Siemens per centimeter (S/cm), said optically transparent intermediate layer being comprised of a material having a bulk electrical conductivity at room temperature less than 10 -12 Siemens per centimeter and a band gap of 3.5 eV. Described herein are also methods for forming a transparent electrode, and transparent electronic devices comprising at least one transparent electrode.

Abstract translation: 本文描述的是包括至少一个光学透明导电层的透明电极; 以及至少一个光学透明中间层，其中所述光学透明导电层与所述光学中间层接触，并且其中所述光学透明导电层和所述光学透明中间层一起将具有波长的入射光的至少50％ 在约200和约1200纳米之间的范围内，所述光学透明导电层的体积电导率至少为100西门子每厘米（S / cm），所述光学透明中间层由在室温下具有体积电导率的材料组成 每厘米超过10西门子，3.5V的带隙。 这里也描述了形成透明电极的方法和包括至少一个透明电极的透明电子器件。

公开(公告)号：WO2007109519A2

公开(公告)日：2007-09-27

申请号：PCT/US2007064127

申请日：2007-03-16

Applicant: GEN ELECTRIC ,  LEWIS LARRY NEIL ,  CELLA JAMES ANTHONY

Inventor： LEWIS LARRY NEIL ,  CELLA JAMES ANTHONY

IPC: C07C25/18 ,  C07C25/24

CPC classification number: C08G61/02 ,  C07C25/22 ,  C07C25/24 ,  C07C2603/18 ,  H01L51/0039 ,  H01L51/0043 ,  H01L51/0094 ,  H01L51/5012

Abstract: Optoelectronic devices are derived from polymers that include structural units of formula (I) wherein R la and R 2a are independently C 10-20 alkenyl, C 3-20 alkynyl, C 3-20 substituted alkenyl, C 3-20 substituted alkynyl, or a combination thereof; and R lb is alkyl, substituted alkyl, or a combination thereof.

Abstract translation: 光电子器件衍生自包含式（I）的结构单元的聚合物，其中R 1a和R 2b独立地为C 10-20链烯基， C 3-20炔基，C 3-20取代的烯基，C 3-20 - 取代的炔基或其组合; 并且R 1b是烷基，取代的烷基或其组合。