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公开(公告)号:DE69930669D1
公开(公告)日:2006-05-18
申请号:DE69930669
申请日:1999-12-07
Applicant: GEN ELECTRIC
Inventor: BRAAT J , INGELBRECHT GERARD , LISKA JURAJ
Abstract: The invention relates to a novel process for the manufacture of functionalized polyphenylene ether resins through redistribution with a functionalized phenolic compound in the polyphenylene ether resin polymerization reaction solution without the addition of an added redistribution catalyst or promoter.The invention also relates to the functionalized polyphenylene ether resin made by the process as well as blends and articles containing the functionalized polyphenylene ether resin made by the process.
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公开(公告)号:DE69930669T2
公开(公告)日:2006-10-12
申请号:DE69930669
申请日:1999-12-07
Applicant: GEN ELECTRIC
Inventor: BRAAT J , INGELBRECHT GERARD , LISKA JURAJ
Abstract: The invention relates to a novel process for the manufacture of functionalized polyphenylene ether resins through redistribution with a functionalized phenolic compound in the polyphenylene ether resin polymerization reaction solution without the addition of an added redistribution catalyst or promoter.The invention also relates to the functionalized polyphenylene ether resin made by the process as well as blends and articles containing the functionalized polyphenylene ether resin made by the process.
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公开(公告)号:DE60204022T2
公开(公告)日:2006-01-19
申请号:DE60204022
申请日:2002-04-03
Applicant: GEN ELECTRIC
Inventor: SINGH PROBJOT , INGELBRECHT GERARD , PARRILLO DAVID , PARTHASARATHY MUKUND
Abstract: A method of preparing a poly(arylene ether) includes oxidatively polymerizing a monohydric phenol in solution, concentrating the solution by removing a portion of the solvent to form a concentrated solution having a cloud point, Tcloud, and combining the concentrated solution with an anti-solvent to precipitate the poly (arylene ether), wherein the concentrated solution has a temperature of at least about (Tcloud-10° C.) immediately before it is combined with the anti-solvent. The method reduces the formation of undesirably fine particles in the product poly(arylene ether).
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公开(公告)号:DE60118185T2
公开(公告)日:2006-12-28
申请号:DE60118185
申请日:2001-06-06
Applicant: GEN ELECTRIC
Inventor: BRAAT J , INGELBRECHT GERARD
Abstract: Poly(arylene ether) resins having intrinsic viscosities greater than about 0.8 dL/g are produced in the reaction of a phenol with oxygen in the presence of an organic solvent and a metal complex catalyst, the phenol concentration being about 5 to about 15 weight percent of the sum of phenol and solvent, and the molar ratio of metal in the metal complex catalyst to the phenol being about 1:100 to about 1:200.
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公开(公告)号:DE60118185D1
公开(公告)日:2006-05-11
申请号:DE60118185
申请日:2001-06-06
Applicant: GEN ELECTRIC
Inventor: BRAAT J , INGELBRECHT GERARD
Abstract: Poly(arylene ether) resins having intrinsic viscosities greater than about 0.8 dL/g are produced in the reaction of a phenol with oxygen in the presence of an organic solvent and a metal complex catalyst, the phenol concentration being about 5 to about 15 weight percent of the sum of phenol and solvent, and the molar ratio of metal in the metal complex catalyst to the phenol being about 1:100 to about 1:200.
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公开(公告)号:DE60204022D1
公开(公告)日:2005-06-09
申请号:DE60204022
申请日:2002-04-03
Applicant: GEN ELECTRIC
Inventor: SINGH PROBJOT , INGELBRECHT GERARD , PARRILLO DAVID , PARTHASARATHY MUKUND
Abstract: A method of preparing a poly(arylene ether) includes oxidatively polymerizing a monohydric phenol in solution, concentrating the solution by removing a portion of the solvent to form a concentrated solution having a cloud point, Tcloud, and combining the concentrated solution with an anti-solvent to precipitate the poly (arylene ether), wherein the concentrated solution has a temperature of at least about (Tcloud-10° C.) immediately before it is combined with the anti-solvent. The method reduces the formation of undesirably fine particles in the product poly(arylene ether).
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