Abstract:
A method of removing substantially all solvent from a solution containing a polyphenylene ether polymer resin with little by-product formation (less than 250 ppm) is provided. The method employs a wiped thin film evaporator with a cylindrical heating chamber operating under conditions that satisfy the relationships defined by Equations I and II: 5.3*10 RL delta exp( )/m
Abstract translation:提供了从含有少量副产物形成的聚苯醚聚合物树脂(小于250ppm)的溶液中除去基本上所有溶剂的方法。 该方法采用具有圆柱形加热室的擦拭薄膜蒸发器,该条件在满足方程式I和II定义的关系条件下操作:5.3×10 24 RLΔexp(<-24123 / T)/ m
Abstract:
A method of preparing a poly(arylene ether)includes oxidatively polymerizing a monohydric phenol in solution, concentrating the solution by removing a portion of the solvent to form a concentrated solution having a cloud point, Tcloud, and combining the concentrated solution with an anti-solvent to precipitate the poly(arylene ether), wherein the concentrated solution has a temperature of at least about (Tcloud-10 DEG C) imme diately before it is combined with the anti-solvent. The method reduces the formation of undesirably fine particles in the product poly(arylene ether).
Abstract:
Thermosetting polymers and the electrical laminates made therefrom are disclosed. The laminate comprises a cross-linked product of: a) one or more ethylenically unsaturated aromatic monomers, with fire retardation being optionally contributed by one halogenated monomer; b) a vinyl-terminated polybutadiene or butadiene-styrene copolymer containing either a urethane or an ester group; and c) a chemically modified polyphenylene ether resin, preferably low molecular weight chemically modified polyphenylene ether resin. It has been discovered that an unexpected combination of thermal, electrical, and mechanical properties are obtained from the composition recited herein. Therefore, the composition is ideally suited as a matrix polymer for electrical substrate applications.
Abstract:
A method of removing substantially all solvent from a solution containing a polyphenylene ether polymer resin with little by-product formation (less than 250 ppm) is provided. The method employs a wiped thin film evaporator with a cylindrical heating chamber operating under conditions that satisfy the relationships defined by Equations I and II.Yields are maximized wherein values for feed rate (m) and percent solids (C) are selected to provide a maximum value for the output, Q, determined from the equation m*C=Q and the melt viscosity of the polyphenylene ether product is less than 50,000 centipoise at the operating temperature of the cylindrical heating chamber.
Abstract:
A method of preparing a poly(arylene ether) includes oxidatively polymerizing a monohydric phenol in solution, concentrating the solution by removing a portion of the solvent to form a concentrated solution having a cloud point, Tcloud, and combining the concentrated solution with an anti-solvent to precipitate the poly (arylene ether), wherein the concentrated solution has a temperature of at least about (Tcloud-10° C.) immediately before it is combined with the anti-solvent. The method reduces the formation of undesirably fine particles in the product poly(arylene ether).
Abstract:
A method of preparing a poly(arylene ether) includes oxidatively polymerizing a monohydric phenol in solution, concentrating the solution by removing a portion of the solvent to form a concentrated solution having a cloud point, Tcloud, and combining the concentrated solution with an anti-solvent to precipitate the poly (arylene ether), wherein the concentrated solution has a temperature of at least about (Tcloud-10° C.) immediately before it is combined with the anti-solvent. The method reduces the formation of undesirably fine particles in the product poly(arylene ether).
Abstract:
Un procedimiento para preparar un poli(éter de arileno), que comprende: el acoplamiento oxidativo de un fenol monohídrico usando un gas que contiene oxígeno en presencia de un disolvente y un catalizador de complejo metálico para producir una resina de poli(éter de arileno); la eliminación de una parte del disolvente para producir una solución concentrada que tenga un punto de turbidez, Tturbidez; y la combinación de la solución concentrada con un antidisolvente para precipitar el poli(éter de arileno), en la que la solución concentrada tiene una temperatura de al menos (Tturbidez -10ºC) aproximadamente, inmediatamente antes de combinarla con el antidisolvente.
Abstract:
A method of preparing a poly(arylene ether) includes oxidatively polymerizing a monohydric phenol in solution, concentrating the solution by removing a portion of the solvent to form a concentrated solution having a cloud point, Tcloud, and combining the concentrated solution with an anti-solvent to precipitate the poly (arylene ether), wherein the concentrated solution has a temperature of at least about (Tcloud-10° C.) immediately before it is combined with the anti-solvent. The method reduces the formation of undesirably fine particles in the product poly(arylene ether).