METHOD FOR ISOLATING POLYPHENYLENE ETHER POLYMER RESINS FROM SOLUTION
    1.
    发明申请
    METHOD FOR ISOLATING POLYPHENYLENE ETHER POLYMER RESINS FROM SOLUTION 审中-公开
    从溶液中分离聚苯乙烯聚合物树脂的方法

    公开(公告)号:WO03041831A2

    公开(公告)日:2003-05-22

    申请号:PCT/US0233240

    申请日:2002-10-15

    Applicant: GEN ELECTRIC

    CPC classification number: B01D1/225 C08G65/48

    Abstract: A method of removing substantially all solvent from a solution containing a polyphenylene ether polymer resin with little by-product formation (less than 250 ppm) is provided. The method employs a wiped thin film evaporator with a cylindrical heating chamber operating under conditions that satisfy the relationships defined by Equations I and II: 5.3*10 RL delta exp( )/m

    Abstract translation: 提供了从含有少量副产物形成的聚苯醚聚合物树脂(小于250ppm)的溶液中除去基本上所有溶剂的方法。 该方法采用具有圆柱形加热室的擦拭薄膜蒸发器,该条件在满足方程式I和II定义的关系条件下操作:5.3×10 24 RLΔexp(<-24123 / T)/ m

    METHOD OF PREPARING A POLY(ARYLENE ETHER), AND A POLY(ARYLENE ETHER) PREPARED THEREBY
    2.
    发明申请
    METHOD OF PREPARING A POLY(ARYLENE ETHER), AND A POLY(ARYLENE ETHER) PREPARED THEREBY 审中-公开
    制备聚(亚乙基醚)的方法和制备的聚(亚乙基醚)

    公开(公告)号:WO03000769A3

    公开(公告)日:2003-03-06

    申请号:PCT/US0210422

    申请日:2002-04-03

    Applicant: GEN ELECTRIC

    CPC classification number: C08G65/46 C08G65/44

    Abstract: A method of preparing a poly(arylene ether)includes oxidatively polymerizing a monohydric phenol in solution, concentrating the solution by removing a portion of the solvent to form a concentrated solution having a cloud point, Tcloud, and combining the concentrated solution with an anti-solvent to precipitate the poly(arylene ether), wherein the concentrated solution has a temperature of at least about (Tcloud-10 DEG C) imme diately before it is combined with the anti-solvent. The method reduces the formation of undesirably fine particles in the product poly(arylene ether).

    Abstract translation: 制备聚(亚芳基醚)的方法包括使溶液中的一元酚氧化聚合,通过除去一部分溶剂浓缩溶液以形成具有浊点Tcloud的浓缩溶液,并将浓缩溶液与抗 - 溶剂以沉淀聚(亚芳基醚),其中浓缩溶液在与抗溶剂组合之前具有至少约(Tcloud-10℃)的温度。 该方法减少了产物聚(亚芳基醚)中不期望的细颗粒的形成。

    Method for isolating polyphenylene ether polymer resins from solution

    公开(公告)号:AU2002335073A1

    公开(公告)日:2003-05-26

    申请号:AU2002335073

    申请日:2002-10-15

    Applicant: GEN ELECTRIC

    Abstract: A method of removing substantially all solvent from a solution containing a polyphenylene ether polymer resin with little by-product formation (less than 250 ppm) is provided. The method employs a wiped thin film evaporator with a cylindrical heating chamber operating under conditions that satisfy the relationships defined by Equations I and II.Yields are maximized wherein values for feed rate (m) and percent solids (C) are selected to provide a maximum value for the output, Q, determined from the equation m*C=Q and the melt viscosity of the polyphenylene ether product is less than 50,000 centipoise at the operating temperature of the cylindrical heating chamber.

    5.
    发明专利
    未知

    公开(公告)号:DE60204022T2

    公开(公告)日:2006-01-19

    申请号:DE60204022

    申请日:2002-04-03

    Applicant: GEN ELECTRIC

    Abstract: A method of preparing a poly(arylene ether) includes oxidatively polymerizing a monohydric phenol in solution, concentrating the solution by removing a portion of the solvent to form a concentrated solution having a cloud point, Tcloud, and combining the concentrated solution with an anti-solvent to precipitate the poly (arylene ether), wherein the concentrated solution has a temperature of at least about (Tcloud-10° C.) immediately before it is combined with the anti-solvent. The method reduces the formation of undesirably fine particles in the product poly(arylene ether).

    PROCEDIMIENTO DE PREPARACION DE POLI(ETER DE ARILENO) Y POLI(ETER DE ARILENO)ASI PREPARADO.

    公开(公告)号:ES2240823T3

    公开(公告)日:2005-10-16

    申请号:ES02780863

    申请日:2002-04-03

    Applicant: GEN ELECTRIC

    Abstract: Un procedimiento para preparar un poli(éter de arileno), que comprende: el acoplamiento oxidativo de un fenol monohídrico usando un gas que contiene oxígeno en presencia de un disolvente y un catalizador de complejo metálico para producir una resina de poli(éter de arileno); la eliminación de una parte del disolvente para producir una solución concentrada que tenga un punto de turbidez, Tturbidez; y la combinación de la solución concentrada con un antidisolvente para precipitar el poli(éter de arileno), en la que la solución concentrada tiene una temperatura de al menos (Tturbidez -10ºC) aproximadamente, inmediatamente antes de combinarla con el antidisolvente.

    8.
    发明专利
    未知

    公开(公告)号:DE60204022D1

    公开(公告)日:2005-06-09

    申请号:DE60204022

    申请日:2002-04-03

    Applicant: GEN ELECTRIC

    Abstract: A method of preparing a poly(arylene ether) includes oxidatively polymerizing a monohydric phenol in solution, concentrating the solution by removing a portion of the solvent to form a concentrated solution having a cloud point, Tcloud, and combining the concentrated solution with an anti-solvent to precipitate the poly (arylene ether), wherein the concentrated solution has a temperature of at least about (Tcloud-10° C.) immediately before it is combined with the anti-solvent. The method reduces the formation of undesirably fine particles in the product poly(arylene ether).

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