公开(公告)号：WO03000769A3

公开(公告)日：2003-03-06

申请号：PCT/US0210422

申请日：2002-04-03

Applicant: GEN ELECTRIC

Inventor： SINGH PROBJOT ,  INGELBRECHT HUGO GERARD EDUARD ,  PARRILLO DAVID ,  PARTHASARATHY MUKUND

IPC: C08G65/44 ,  C08G65/46

CPC classification number: C08G65/46 ,  C08G65/44

Abstract: A method of preparing a poly(arylene ether)includes oxidatively polymerizing a monohydric phenol in solution, concentrating the solution by removing a portion of the solvent to form a concentrated solution having a cloud point, Tcloud, and combining the concentrated solution with an anti-solvent to precipitate the poly(arylene ether), wherein the concentrated solution has a temperature of at least about (Tcloud-10 DEG C) imme diately before it is combined with the anti-solvent. The method reduces the formation of undesirably fine particles in the product poly(arylene ether).

Abstract translation: 制备聚（亚芳基醚）的方法包括使溶液中的一元酚氧化聚合，通过除去一部分溶剂浓缩溶液以形成具有浊点Tcloud的浓缩溶液，并将浓缩溶液与抗 - 溶剂以沉淀聚（亚芳基醚），其中浓缩溶液在与抗溶剂组合之前具有至少约（Tcloud-10℃）的温度。 该方法减少了产物聚（亚芳基醚）中不期望的细颗粒的形成。

公开(公告)号：WO03041831A2

公开(公告)日：2003-05-22

申请号：PCT/US0233240

申请日：2002-10-15

Applicant: GEN ELECTRIC

Inventor： PARRILLO DAVID ,  SINGH PROBJOT

IPC: B01D1/22 ,  C08G65/48 ,  B01D1/00

CPC classification number: B01D1/225 ,  C08G65/48

Abstract: A method of removing substantially all solvent from a solution containing a polyphenylene ether polymer resin with little by-product formation (less than 250 ppm) is provided. The method employs a wiped thin film evaporator with a cylindrical heating chamber operating under conditions that satisfy the relationships defined by Equations I and II: 5.3*10 RL delta exp( )/m

Abstract translation: 提供了从含有少量副产物形成的聚苯醚聚合物树脂（小于250ppm）的溶液中除去基本上所有溶剂的方法。 该方法采用具有圆柱形加热室的擦拭薄膜蒸发器，该条件在满足方程式I和II定义的关系条件下操作：5.3×10 24 RLΔexp（<-24123 / T）/ m

公开(公告)号：AU2002335073A1

公开(公告)日：2003-05-26

申请号：AU2002335073

申请日：2002-10-15

Applicant: GEN ELECTRIC

Inventor： SINGH PROBJOT ,  PARRILLO DAVID

IPC: B01D1/22 ,  C08G65/48

Abstract: A method of removing substantially all solvent from a solution containing a polyphenylene ether polymer resin with little by-product formation (less than 250 ppm) is provided. The method employs a wiped thin film evaporator with a cylindrical heating chamber operating under conditions that satisfy the relationships defined by Equations I and II.Yields are maximized wherein values for feed rate (m) and percent solids (C) are selected to provide a maximum value for the output, Q, determined from the equation m*C=Q and the melt viscosity of the polyphenylene ether product is less than 50,000 centipoise at the operating temperature of the cylindrical heating chamber.

公开(公告)号：DE60204022T2

公开(公告)日：2006-01-19

申请号：DE60204022

申请日：2002-04-03

Applicant: GEN ELECTRIC

Inventor： SINGH PROBJOT ,  INGELBRECHT GERARD ,  PARRILLO DAVID ,  PARTHASARATHY MUKUND

IPC: C08G65/44 ,  C08G65/46

Abstract: A method of preparing a poly(arylene ether) includes oxidatively polymerizing a monohydric phenol in solution, concentrating the solution by removing a portion of the solvent to form a concentrated solution having a cloud point, Tcloud, and combining the concentrated solution with an anti-solvent to precipitate the poly (arylene ether), wherein the concentrated solution has a temperature of at least about (Tcloud-10° C.) immediately before it is combined with the anti-solvent. The method reduces the formation of undesirably fine particles in the product poly(arylene ether).

公开(公告)号：AU2002307084A1

公开(公告)日：2003-01-08

申请号：AU2002307084

申请日：2002-04-03

Applicant: GEN ELECTRIC

Inventor： INGELBRECHT HUGO GERARD EDUARD ,  PARRILLO DAVID ,  SINGH PROBJOT ,  PARTHASARATHY MUKUND

IPC: C08G65/44 ,  C08G65/46

Abstract: A method of preparing a poly(arylene ether) includes oxidatively polymerizing a monohydric phenol in solution, concentrating the solution by removing a portion of the solvent to form a concentrated solution having a cloud point, Tcloud, and combining the concentrated solution with an anti-solvent to precipitate the poly (arylene ether), wherein the concentrated solution has a temperature of at least about (Tcloud-10° C.) immediately before it is combined with the anti-solvent. The method reduces the formation of undesirably fine particles in the product poly(arylene ether).

公开(公告)号：ES2240823T3

公开(公告)日：2005-10-16

申请号：ES02780863

申请日：2002-04-03

Applicant: GEN ELECTRIC

Inventor： SINGH PROBJOT ,  INGELBRECHT HUGO GERARD EDUARD ,  PARRILLO DAVID ,  PARTHASARATHY MUKUND

IPC: C08G65/44 ,  C08G65/46

Abstract: Un procedimiento para preparar un poli(éter de arileno), que comprende: el acoplamiento oxidativo de un fenol monohídrico usando un gas que contiene oxígeno en presencia de un disolvente y un catalizador de complejo metálico para producir una resina de poli(éter de arileno); la eliminación de una parte del disolvente para producir una solución concentrada que tenga un punto de turbidez, Tturbidez; y la combinación de la solución concentrada con un antidisolvente para precipitar el poli(éter de arileno), en la que la solución concentrada tiene una temperatura de al menos (Tturbidez -10ºC) aproximadamente, inmediatamente antes de combinarla con el antidisolvente.

公开(公告)号：DE60204022D1

公开(公告)日：2005-06-09

申请号：DE60204022

申请日：2002-04-03

Applicant: GEN ELECTRIC

Inventor： SINGH PROBJOT ,  INGELBRECHT GERARD ,  PARRILLO DAVID ,  PARTHASARATHY MUKUND

IPC: C08G65/44 ,  C08G65/46

Abstract: A method of preparing a poly(arylene ether) includes oxidatively polymerizing a monohydric phenol in solution, concentrating the solution by removing a portion of the solvent to form a concentrated solution having a cloud point, Tcloud, and combining the concentrated solution with an anti-solvent to precipitate the poly (arylene ether), wherein the concentrated solution has a temperature of at least about (Tcloud-10° C.) immediately before it is combined with the anti-solvent. The method reduces the formation of undesirably fine particles in the product poly(arylene ether).