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公开(公告)号:BR9600888A
公开(公告)日:1997-12-30
申请号:BR9600888
申请日:1996-03-04
Applicant: HOECHST AG
Inventor: EICHHORN MATHIAS , ELSAESSER ANDREAS
IPC: G03F7/022 , C08F20/52 , C08F20/54 , C08F20/60 , C08K5/28 , C08L33/24 , G03F7/023 , G03F7/033 , G03F7/037 , G03F7/039 , G03C1/695
Abstract: N-(N,N-Diacyl-iminomethyl)acrylamide polymers (I) have repeating units of formula (A) -Ä-C(R )(R )-C(Cä=Oü-NH-CH2-NT1T )-Ü- (A) where R ,R ,R = H or alkyl; T = -X-Y; T = -C(=O)-Z; X ==C=O or =SO2; Y,Z = (cyclo)alkyl, alkenyl or (het)aryl or Y + Z = a 5-6-membered heterocycle.
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公开(公告)号:BR9305037A
公开(公告)日:1994-06-21
申请号:BR9305037
申请日:1993-12-13
Applicant: HOECHST AG
Inventor: EICHHORN MATHIAS , BUHR GERHARD
IPC: C07C311/51 , C07C311/53 , C08F20/38 , C08F22/38 , G03F7/038 , G03F7/039 , C07C311/16 , C07C311/13 , C07C311/21 , C07C311/24 , C07C311/29 , C08C288/00
Abstract: The invention relates to monomers of the formulae R -SO2-N(CO-OR )-R -O-CO-CR = CH2 and R -N(CO-OR )-SO2-R -O-CO-CR = CH2, in which R is a (C1 -C20)alkyl, (C3-C10)cycloalkyl, (C6-C14)aryl or (C7-C20)aralkyl radical, where, in the alkyl-containing radicals, individual methylene groups may be replaced by heteroatoms, R is a (C3-C11)alkyl, (C3-C11)alkenyl or (C7-C11)aralkyl radical, R is an unsubstituted or substituted (C1-C6)alkyl, (C3-C6)cycloalkyl, (C6-C14)aryl or (C7-C20 )aralkyl radical, and R is a hydrogen atom or a methyl group. It furthermore relates to polymers containing at least 5 mol% of units containing side groups of the formula(e) -R -N(CO-OR )-SO2-R (I) and/or -R -SO2-N(CO-OR (II), and to a radiation-sensitive mixture containing a) a compound which forms an acid on exposure to actinic radiation and b) an acid-cleavable compound whose cleavage products have greater solubility in an aqueous-alkaline developer than does the starting compound, where the acid-cleavable compound is a polymer of the said type, and to a recording material having a support (carrier, base) and a radiation-sensitive coating. The mixture according to the invention is particularly suitable for the production of offset printing plates and photoresists.
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公开(公告)号:BR9503065A
公开(公告)日:1996-06-11
申请号:BR9503065
申请日:1995-07-03
Applicant: HOECHST AG
Inventor: BRENK MICHAEL , EICHHORN MATHIAS , ELSAESSER ANDREAS
Abstract: A mechanically and/or electrochemically roughened, and opt. anodically oxidised, carrier is made of aluminium or its alloys. The carrier carries a hydrophilic layer made from at least one polymer with basic and acidic groups. On the layer is a further hydrophilic layer that contains at least one compound with at least one phosphono group. Also claimed a process for the prodn. of the carrier; and a recording material with a radiation sensitive layer on the carrier.
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公开(公告)号:BR9501830A
公开(公告)日:1996-03-05
申请号:BR9501830
申请日:1995-04-27
Applicant: HOECHST AG
Inventor: EICHHORN MATHIAS , BUHR GERHARD
Abstract: A positive-functioning radiation-sensitive mixt. (A) is claimed, contg. (a) a polymeric binder with acid-labile gps., contg. units of formula (I), (II) and (III) and (b) a cpd. which forms a strong acid when irradiated; R OH (I), R -O-CO2OR (II), R -O-CH2-CHR -OH (III): R = opt. substd. Ph attached to a polymer main or side chain; R = 3-11C alkyl or alkenyl, or 7-11C aralkyl; R = H, opt. substd. alkyl or aryl, phthalimidomethyl, or -CH2OR (with R = H, or opt. substd. aliphatic, cycloaliphatic or aromatic gp.). Also claimed is a recording material with a substrate and a radiation-sensitive layer consisting of compsn. (A).
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公开(公告)号:BR9505897A
公开(公告)日:1998-01-06
申请号:BR9505897
申请日:1995-12-14
Applicant: HOECHST AG
Inventor: EICHHORN MATHIAS , BUHR GERHARD
Abstract: In a radiation-sensitive mixt. based on a cpd. with acid-hydrolysable C-O-C gp(s). and a strong photo-acid, the hydrolysable cpd. is of formula (R -C(=O)-O-CH(R )-O-C(=O)-)nR (I). In (I), R = opt. substd. alkyl; R = H or opt. substd. 1-4C alkyl; R = an n-valent, opt. polymeric aliphatic or aromatic gp.; and n = 1-100.
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公开(公告)号:BR9501829A
公开(公告)日:1996-04-30
申请号:BR9501829
申请日:1995-04-27
Applicant: HOECHST AG
Inventor: EICHHORN MATHIAS , BUHR GERHARD
IPC: C07D295/12 , C07C245/20 , C07C309/06 , C07C323/48 , C07D209/88 , C07D295/135 , G03C1/56 , G03F7/016 , G03F7/021 , G03F7/09 , C07C323/31 , C07D307/91 , C07D333/76 , C09D7/12 , C09D125/18 , C09D161/06 , G03F7/039
Abstract: (Hetero)aromatic mono- or bis-diazonium 1,1,2,3,3,3-hexa- fluoropropane sulphonates (I) are new. Also claimed are radiation-sensitive mixts. contg. (I).
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公开(公告)号:BR9305036A
公开(公告)日:1994-06-21
申请号:BR9305036
申请日:1993-12-13
Applicant: HOECHST AG
Inventor: EICHHORN MATHIAS , BUHR GERHARD
IPC: C07C311/16 , C07C311/53 , G03F7/004 , G03F7/039 , H01L21/027 , C07C311/03 , C07C311/13 , C07C311/21 , C07C311/24 , C07C311/29 , C08K5/44
Abstract: The invention relates to N,N-disubstituted sulphonamides of the formulae R [-N(CO-OR )-SO2R ]n and R [-SO2-N(CO-OR )-R ]n, in which R - in the case where n = 1 - is a (C1-C20)alkyl, (C3-C10)cycloalkyl, (C6-C14)aryl or (C7-C20)aralkyl radical and - in the case where n > 1 - is the divalent, trivalent or tetravalent radical of a (C1-C20)alkane or (C5-C7)cycloalkane, of an unfused or fused monocyclic or polycyclic (C6-C18)aromatic compound, R is a (C3-C11)alkyl, (C3-C11)alkenyl or (C7-C11)aralkyl radical, R is an unsubstituted or substituted (C1-C6)alkyl, (C3-C6)cycloalkyl, (C6-C14)aryl or (C7-C20 )aralkyl radical. In addition, the invention relates to a positive-working radiation-sensitive mixture containing a) a compound which forms an acid on exposure to actinic radiation, b) an acid-cleavable compound whose cleavage products have greater solubility in an aqueous-alkaline developer than does the starting compound, and c) a polymeric binder which is insoluble in water, but soluble, at least swellable, in aqueous-alkaline solutions, where compound b) is a sulphonamide of the formula I or II. The mixture according to the invention is particularly suitable for the production of offset printing plates and photoresists.
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