Abstract:
2,5-Bis-(4'-aminophenyl)-1,3,4-oxadiazoles which are chlorinated in the phenyl nuclei are obtained by condensing hydrazine or a hydrazine yielding agent with equal or different chlorinated benzoic acids or acylating acid derivatives having in para-position to the acid group an amino group or a group capable of being transformed into the amino group, and, thereafter, effecting ring closure of the so-obtained bis-hydrazide to yield the oxadiazole. The products are bis-diazo components, especially for pigments having a very high tinctorial strength, clear and pure shades, a good fastness to light, to heat and to solvents.
Abstract:
2,5-diarylamino terephthalates are obtained in good yields and excellent purity when the aromatic nitro compound used for oxidizing the corresponding dihydro-2,5-diarylamino terephthalate contains the aromatic radical of said diarylamino groups, i.e. when the amine formed during the oxidation is that from which said diarylamino groups derive. The products yield vary pure quinacridone pigments and allow the sythesis of only one isomer of substituted quinacridones.