公开(公告)号：JPH1067833A

公开(公告)日：1998-03-10

申请号：JP17737797

申请日：1997-07-02

Applicant: HOECHST AG

Inventor： BENDER ALBERT DR ,  GIENCKE ASTRID DR

IPC: C09F1/04 ,  C08F8/00 ,  C08F290/00 ,  C09D11/10

Abstract: PROBLEM TO BE SOLVED: To provide a novel lowly viscous binder resin for toluene intaglio printing ink, having improved abrasion resistance and improved wettability with black ink, and showing a good heat stability in its production. SOLUTION: This resin is produced by reacting (A) a 4-10C linear, branched or cyclic hydrocarbon having at least two unsaturations and/or an oligomer thereof having a degree of oligomeration of 2-10 with (B) a natural resin and/or a natural resin acid, (C) an α,β-olefinically unsaturated carboxylic acid and/or an anhydride thereof, (D) a divalent-metal compound, (E) a carboxylic acid selected from the group consisting of aromatic and saturated aliphatic carboxylic acids, and (F) a fatty acid ester. This reaction is carried out in at least two stages including stage 1 where compound (A) is reacted with compound (B) and stage 2 and subsequent stages where the reaction product from the preceding stage is reacted with at least one compound selected among compounds C, D, E and F at 100-300 deg.C under the exclusion of water.

公开(公告)号：JPH1067831A

公开(公告)日：1998-03-10

申请号：JP17737497

申请日：1997-07-02

Applicant: HOECHST AG

Inventor： BENDER ALBERT DR ,  GIENCKE ASTRID DR

IPC: C08F290/00 ,  C08F8/00 ,  C09D11/10

Abstract: PROBLEM TO BE SOLVED: To obtain a binder resin which can exhibit improved abrasion resistance and wetting performances when used in black ink and is desirably used for especially toluene intaglio printing ink by reacting a specified unsaturated hydrocarbon with a natural resin, an α,β-unsaturated carboxylic acid, a divalent- metal compound and a fatty acid under specified conditions. SOLUTION: This resin comprises recurring units derived from compounds selected from groups of (A) 4-10C di- or poly-unsaturated linear or branched or cyclic hydrocarbons and mixed or non-mixed oligomers thereof having a degree of oligomeration of 2-10, (B) natural resins or natural resin acids, (C) α,β-ethylenically unsaturated carboxylic acids and/or anhydrides thereof, (D) divalent-metal compounds and (E) fatty acids, respectively. This is obtained by reacting first component A with component B and reacting the formed copolymer with components C, D and E at 100-300 deg.C under the exclusion of water.

公开(公告)号：DE4337253A1

公开(公告)日：1995-05-04

申请号：DE4337253

申请日：1993-11-02

Applicant: HOECHST AG

Inventor： GIENCKE ASTRID DR ,  WALZ GERD DR ,  MERGARDT BERND DR

IPC: C08F2/28 ,  C08F2/44 ,  C08F283/00 ,  C08L63/00 ,  C09D11/10 ,  C09D17/00 ,  C08J3/03 ,  C08J3/20 ,  C09D5/02 ,  C09D163/00

Abstract: Emulsifier-free multimodal polymer mixtures as grinding resins, grinding dispersions and binders for water-based printing inks and printing varnishes, containing at least two different, optionally neutralised or partially neutralised amino-containing polymers A and B, optionally water, and optionally a water-insoluble polymer resin C in the form of latex particles, which can be prepared by emulsion polymerisation of ethylenically unsaturated compounds in the presence of the amino-containing polymers A and B.

公开(公告)号：DE4330767A1

公开(公告)日：1995-03-16

申请号：DE4330767

申请日：1993-09-10

Applicant: HOECHST AG

Inventor： GIENCKE ASTRID DR ,  ULRICH PETRA ,  WALZ GERD DR ,  MERGARDT BERND DR

IPC: C08L33/02 ,  C08F2/22 ,  C08F2/24 ,  C08F8/14 ,  C08F265/04 ,  C08F291/00 ,  C09D11/10 ,  C08F20/04 ,  C08F22/02 ,  C08F22/04 ,  C08F22/16 ,  C08J3/03 ,  C08L33/04 ,  C08L35/00

Abstract: Emulsifier-free synthetic resins and synthetic resin mixtures with water as binders for water-based printing inks and printer's varnishes, containing a) an optionally neutralised or partially neutralised polymer resin A containing acid groups, obtainable by in-situ polymerisation of ethylenically unsaturated compounds containing acid groups with other ethylenically unsaturated compounds and condensation with monohydroxyl compounds and optionally neutralisation or partial neutralisation, and b) optionally a water-insoluble polymer resin B in the form of latex particles, obtainable by emulsion polymerisation of ethylenically unsaturated compounds in the presence of the polymer resin A.

公开(公告)号：DE19626724A1

公开(公告)日：1998-01-08

申请号：DE19626724

申请日：1996-07-03

Applicant: HOECHST AG

Inventor： BENDER ALBERT DR ,  GIENCKE ASTRID DR

IPC: C09F1/04 ,  C08F8/00 ,  C08F290/00 ,  C09D11/10 ,  C08F240/00 ,  C07D307/60 ,  C08K5/101 ,  C08L93/04 ,  C09D11/02 ,  C09D17/00

公开(公告)号：DE4314298A1

公开(公告)日：1994-11-03

申请号：DE4314298

申请日：1993-04-30

Applicant: HOECHST AG

Inventor： GIENCKE ASTRID DR ,  KIEHL ROBERT ,  WALZ GERD DR ,  MERGATH BERND DR

IPC: C08F2/22 ,  C08F2/16 ,  C08F2/44 ,  C08F283/10 ,  C08G59/14 ,  C09D11/10 ,  C08L63/00 ,  C08L57/00 ,  C09D157/00 ,  C09D163/00

公开(公告)号：DE19626725A1

公开(公告)日：1998-01-08

申请号：DE19626725

申请日：1996-07-03

Applicant: HOECHST AG

Inventor： BENDER ALBERT DR ,  GIENCKE ASTRID DR

IPC: C08F290/00 ,  C08F8/00 ,  C09D11/10 ,  C08F240/00 ,  C07D307/60 ,  C08K3/20 ,  C08L93/04 ,  C09D11/02 ,  C09D17/00 ,  C09F1/04

公开(公告)号：DE19509648A1

公开(公告)日：1996-09-19

申请号：DE19509648

申请日：1995-03-17

Applicant: HOECHST AG

Inventor： BENDER ALBERT DR ,  BOTHE LOTHAR DR ,  GIENCKE ASTRID DR

IPC: C09F1/04 ,  C08G8/34 ,  C09D11/00 ,  C09D11/08 ,  C09D11/10 ,  C09D165/00 ,  C09D193/00

公开(公告)号：DE4422869A1

公开(公告)日：1996-01-04

申请号：DE4422869

申请日：1994-06-30

Applicant: HOECHST AG

Inventor： GIENCKE ASTRID DR ,  NEUMANN UWE DR ,  MERGARDT BERND DR

IPC: C08F283/10 ,  C08F290/06 ,  C08F290/14 ,  C08G18/08 ,  C08G18/58 ,  C08G18/67 ,  C08G18/80 ,  C08G59/06 ,  C08G59/50 ,  C08G59/56 ,  C08L51/08 ,  C08L63/00 ,  C09D11/10 ,  C08G85/00 ,  C08G59/14 ,  C08G64/42 ,  C08G71/04 ,  C09D5/02 ,  C09D17/00 ,  C09D163/00 ,  C09D169/00 ,  C09D175/12

Abstract: Polymer system (I) contains a polymer (mixt.) (II) with amino gps., which has a Tg of at least 40 deg C, Mw of 2000-75000 and amine no. of 50-300, in which at least 35% of the amino gps. are neutralised. (II) is obtd. by reacting (a) epoxide(s), carbonate(s) and/or epoxide-carbonate(s), (b) amine(s) and (c) phenol(s), (partial)neutralisation and transfer into water. (I) may also contain a water-insol. polymer (III), obtd. by polymerising ethylenically unsatd. monomer in the presence of (II). Also claimed is the prodn. of (I).