Abstract:
N-acetoacetyl-2,5-dimethoxy-4-chloroanilide is obtained in high yield and purity by suspending 2,5-dimethoxy-4-chloroaniline in water and adding the complete amount of diketene necessary altogether at the beginning of the reaction. The product is obtained in a purity allowing its use as an azoic coupling component without purification.
Abstract:
PROCESS FOR THE PREPARATION OF 5-ACETOACETYLAMINO- . BENZIMIDAZOLONE 5-Acetoacetylamino benzimidazolone-(2) is obtained in high yield and excellent purity by reacting diketene with the aqueous solution of a salt of 5-amino-benzimidazolone-(2) and an acid having a pKa value of 1 to 7, preferably in the presence of an antioxidant and/or a reducing agent.
Abstract:
HOE 75/F 105 PROCESS FOR THE PREPARATION OF ACETOACETYLARYL AMIDES Acetoacetylarylamides are obtained in high yield and excellent purity by reacting a small excess of diketene with an aqueous suspension or emulsion of the arylamine at a temperature which is sufficiently high that the product is obtained in a non-solid form, i.e. in a solution or emulsion.
Abstract:
PROCESS FOR PREPARING 4-CHLORO-2,5-DIMETHOXY ANILINE The catalytic hydrogenation of 4-chloro-2,5-dimethoxy nitrobenzene can be performed in water with a nickel catalyst if the average particle size is below 0.1 mm. The resulting aniline is reacted with diketene and the so-obtained N-aceto-acetyl derivative is an azoic coupling component.
Abstract:
N-acetoacetyl-2,5-dimethoxy-4-chloroanilide is obtained in high yield and purity by suspending 2,5-dimethoxy-4-chloroaniline in water and adding the complete amount of diketene necessary altogether at the beginning of the reaction. The product is obtained in a purity allowing its use as an azoic coupling component without purification.