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    1.
    发明专利
    未知

    公开(公告)号：DE3751844D1

    公开(公告)日：1996-07-25

    申请号：DE3751844

    申请日：1987-02-10

    Applicant: HOECHST AG

    Inventor： WALZ GERD DR ,  HOENEL MICHAEL DR ,  BRINDOEPKE GERHARD DR ,  SPRENGER WALTER ,  FINKE MANFRED DR ,  LENZ RUEDIGER DR

    IPC: C07D317/36 ,  C07C67/00 ,  C07C239/00 ,  C07C269/00 ,  C07C271/20 ,  C07D303/28 ,  C08G18/06 ,  C08G18/32 ,  C08G18/64 ,  C08G18/70 ,  C08G18/80 ,  C08G18/83 ,  C08G59/02 ,  C08G59/40 ,  C08G71/04 ,  C09D5/44 ,  C09D175/04 ,  C09D175/12

    Abstract: Amino-urethanes (I) claimed are of formula R3-N(Re)-A-R1-NH-C(O)-O-CH2-CH(OH)-CH2- R-CH2-CH(OH)-CH2-O-C(O)-NH- R1-A-N(R2)R3 R is residue of a diglycidyl ether or ester, or 2-18 alkylene gp.; R1 is opt. branched 2-18C alkylene; R2 is H, 1-8Calkyl, or 1-8C hydroxyalkyl; R3 is R2, or R3 with R2 can form cyclic ring, or, if R2 is H then R3 can be at least one gp. of formula (a) -C(O)-O-CH2-CH(R4)-CH2- (R-CH2-CH(R4)-CH2-OmB-(R4)n R4 is OH or -CONH-PI-NHCO R6; B is residue of a polyol; m is 1-3; n is 1-6; and PI is residue of a polyisocyanate and R6 is residue of (cylco)aliphatic, or alkylaromatic alcohol, an aminoalcohol, ketoxime, or a CH- or NH- acidic cpd.: b) R3 is gp. of formula (I) R5 is H or R4; R7 is 1-8Calkyl; and s is 1-6; c) -C(O)-NH-PI-NH-C(O)-O-B-d)R8-CHOH-CH2-O-CO-; e) R8-CHOH-CH2-; R8 is H, 1-18C alkyl, or residue of a glycidyl ester or ether; or f) PI'NHCO- PI' is residue of a partly capped polyisocyanate; and A 75 chemical bond or -R1NH)r-R1NH- r is 0-6. Prodn. of a (I) by heating an at least bifunctional 2-oxo-1,3-dioxolan (II) and a prim polyamine at 20-150 deg.C is claimed. Structural formulae are given for pref. R, viz. residues of a bisphenol diglycidyl ether opt. linked by residues of a diamine, diol, dicarboxylic acid, di-isocyanate, etc. Pref. (II) is bicyclic carbonate of specified formuls esp. derived from polyglycidyl ether of a polyphenol, or a epoxide-cyclic carbonate.

    7.
    发明专利
    未知

    公开(公告)号：DE3825584A1

    公开(公告)日：1990-02-01

    申请号：DE3825584

    申请日：1988-07-28

    Applicant: HOECHST AG

    Inventor： HOENEL MICHAEL DR ,  ZIEGLER PETER DR ,  SPRENGER WALTER ,  WENDT WOLFGANG

    IPC: C08G18/58 ,  C08G18/71 ,  C08G18/80 ,  C08G59/14 ,  C08G59/50 ,  C09D5/44 ,  C09D17/00

    Abstract: The invention relates to paste resins based on epoxide compounds, containing (a) specific quaternary ammonium groups, (b) OH groups and (c) isocyanate radicals bonded to the epoxide compound, of which at least 10 mol% are derived from a long-chain, monofunctional isocyanate having at least 8 carbon atoms, the mean molecular weight (Mn) of these paste resins being 500 to 10000. … In addition, the invention relates to the preparation of these paste resins, to their use for pigment pastes and to these pigment pastes. Water-thinnable paints, in particular electrodeposition paints, which contain the pigment pastes according to the invention give defect-free surfaces and comparable coating thicknesses even on different substrates.

    8.
    发明专利
    未知

    公开(公告)号：DE3809695A1

    公开(公告)日：1989-10-12

    申请号：DE3809695

    申请日：1988-03-23

    Applicant: HOECHST AG

    Inventor： HOENEL MICHAEL DR ,  FINKE MANFRED DR ,  WALZ GERD DR ,  ZIEGLER PETER DR

    IPC: C08G18/32 ,  C08G18/38 ,  C08G18/64 ,  C08G18/80 ,  C09D5/44 ,  C09D175/00 ,  C09D175/04

    Abstract: Curing agents (A) for isocyanate-curable resins (B) which have an amine number of from 20 to 150 mg of KOH/g, a maximum OH number of 20 mg KOH/g and contain, per molecule, at least two capped isocyanate groups which are reactive under the curing conditions, are obtained by reacting A) an amine which contains at least one ss-hydroxyalkyl group per molecule, as an OH number of from 100 to 1200 mg KOH/g and an amine number of from 100 to 1200 mg of KOH/g and optionally also contains NHCO groups, optionally blended with another OH- and/or NH-functional compound, with B) a partially capped polyisocyanate, optionally blended with an at least bifunctional, OH- and/or NH-reactive compound. These curing agents, if necessary after neutralisation, are readily dispersible in aqueous systems and frequently have a stability-increasing action in water-borne paint formulations.

    10.
    发明专利
    未知

    公开(公告)号：AT192472T

    公开(公告)日：2000-05-15

    申请号：AT92114212

    申请日：1992-08-20

    Applicant: HOECHST AG

    Inventor： DREISCHHOFF DIETER ,  GEISLER JOERG-PETER DR ,  GODAU CLAUS DI ,  HOENEL MICHAEL DR

    IPC: C08L63/00 ,  C08G59/00 ,  C08J3/03 ,  C09D163/00 ,  C09K23/52

    Abstract: A process for the preparation of aqueous epoxy resin dispersions comprising (1) 20 to 75% by weight, based on the total dispersion, of an epoxy resin constituting a condensation product of a) epoxy compounds having at least one epoxy group per molecule and an epoxide equivalent weight of 90 to 3000 g/mol, and b) aromatic polyols; (2) 3 to 20% by weight, based on the total dispersion, of an emulsifier comprising a) a condensation product of an aliphatic polyol and an epoxy compound having at least two epoxy groups per molecule and an epoxide equivalent weight of 90 to 3000 g/mol, the equivalent ratio of the OH groups to the epoxy groups being 1:0.85 to 1:1.5 and the epoxide equivalent weight of this condensation product being between 5000 and 400,000 g/mol, b) an organic solvent, and c) water; (3) up to 10% by weight, based on the total dispersion, of organic solvents; and (4) water in an amount to make up to 100% by weight, which comprises stirring the epoxy resin (1) firstly with the emulsifier (2) and, if appropriate, organic solvents corresponding to (3), and then with water.

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