公开(公告)号：AT182160T

公开(公告)日：1999-07-15

申请号：AT96106523

申请日：1996-04-25

Applicant: HOECHST AG

Inventor： EPPLE ULRICH DR ,  KUBILLUS UWE DR ,  OSWALD HARALD

IPC: C08F220/32 ,  C08F20/32 ,  C08F220/04 ,  C08F222/02 ,  C08F222/16 ,  C08G18/62 ,  C09D133/02 ,  C09D133/04 ,  C09D133/14 ,  C09D135/00 ,  C09J133/02 ,  C09J133/04 ,  C09J133/14 ,  C09J135/00 ,  C09K3/10

Abstract: Low-mol. wt. copolymers (I) with a wt.-average mol. wt. (Mw) of less than 3500 contain at least 20 wt.% of components with branched side chains, obtd. by the reaction of (aa) glycidyl ester(s) of satd. aliphatic monocarboxylic acids with a tert. or quat. alpha -C atom; and (ab) at least two unsatd. comonomers, at least one of which contains at least one COOH gp., under radical copolymerisation conditions. Also claimed are (i) prepn. of (I) by heating component (aa) to 210-260 degrees C and reacting with component (ab) (which contains at least 2.0 wt.% of a COOH gp.-contg. monomer) in the presence of radical initiator(s), to a degree of conversion of at least 95 (pref. at least 97.5) %; (ii) polymer mixts. contg. (I), obtd. by reaction of (aa) and (ab) as above in at least two time intervals with a constant temp. in each interval, using at least two different reaction temps., at least one of which is in the range 210-260 degrees C; (iii) polymer mixts. contg. (I) and other polymers etc.; (iv) binders for coating materials contg. (I) or the above polymer mixts.; (v) coating materials contg. binders as above and hardeners such as amino resins, capped or uncapped polyisocyanates or organic cpds. with acid and/or anhydride gps.

公开(公告)号：DE59010628D1

公开(公告)日：1997-02-20

申请号：DE59010628

申请日：1990-09-25

Applicant: HOECHST AG

Inventor： HOENEL MICHAEL DR ,  WALZ GERD DR ,  ZIEGLER PETER DR ,  KUBILLUS UWE DR

IPC: C08G59/50 ,  C08L63/00 ,  C08L101/00 ,  C09D5/02 ,  C09D7/12 ,  C09D5/44 ,  C09D163/00 ,  C09D201/00

Abstract: The invention relates to the use of crosslinked polymer microparticles having an average particle size of at most 5 mu m and a glass transition temperature (Tg) of at least +30 DEG C. in aqueous paint preparations as filler and/or as partial substitute of white pigments, in particular of titanium dioxide. Among other things, the corresponding paints show increased spreading power, less tendency for sedimentation and reduced crater formation.

公开(公告)号：DE19520855A1

公开(公告)日：1996-11-07

申请号：DE19520855

申请日：1995-06-08

Applicant: HOECHST AG

Inventor： EPPLE ULRICH DR ,  MARTEN MANFRED ,  KUBILLUS UWE DR ,  OSWALD HARALD

IPC: C08G59/02 ,  C08G18/32 ,  C08G18/64 ,  C08G59/00 ,  C08G59/14 ,  C08G59/18 ,  C08G59/40 ,  C08G59/64 ,  C08L63/00 ,  C09D133/00 ,  C09D133/04 ,  C09D133/06 ,  C09D133/08 ,  C09D163/00 ,  C09D167/00 ,  C09J163/00 ,  C09K3/10 ,  C08L101/06 ,  C08F220/26 ,  C08F222/20

Abstract: Epoxide-amine adducts (I) are claimed, contg. at least 20 wt% aliphatic epoxide and/or amine units with at least one tert. or quat. carbon atom. Also claimed are: (i) binders for coatings, contg. adduct(s) (I); (ii) mixts. of 0.1-99.9 wt% OH gp.-contg. copolymers and 99.9-0.1 wt% (I); (iii) binders for coatings, contg. mixts. (ii); (iv) coating materials contg. these binders, together with hardeners such as amino resins, capped or uncapped polyisocyanates and cpds. with acid and/or anhydride gps.. Pref. (I) are obtd.: (A) by reacting (a) 7-33C (cyclo)aliphatic mono-epoxides (a1), at least 20 wt% of which comprises monoepoxides with a tert. or quat. C atom with (b) 2-30C amines with at least 2 prim. or sec. amino gps. not attached directly to an aromatic ring; or (B) by reacting (a) 8-50C (cyclo)aliphatic diepoxides (a2) with (b) 4-30C prim. or sec. mono-amines with amino gps. not directly attached to aromatic rings, of which at least 20 wt% comprises mono-amines with at least one tert. or quat. C atom; or (C) by reacting (a1) with (b), the corresp. proportions of mono-amine and mono-epoxide with tert. or quat. C atoms being a% and b% respectively, where a + b = 20 and both a and b are greater than zero. The functionality of (I) is reduced by partial or complete reaction of the functional OH and amino gps., pref. by blocking with temporary protecting gps., esp. oxazolidine gps..

公开(公告)号：DE4032751A1

公开(公告)日：1992-04-23

申请号：DE4032751

申请日：1990-10-16

Applicant: HOECHST AG

Inventor： BRINDOEPKE GERHARD DR ,  KUBILLUS UWE DR ,  PLUM HELMUT DR

IPC: A47K3/28 ,  A47K3/30 ,  C08G59/14 ,  C08G59/16 ,  C08G59/40 ,  C08G59/50 ,  C08G59/62 ,  C09D163/00

Abstract: A liquid coating composition is based on an acetoacetate group-containing polymer and a polyamine in the form of the corresponding aldimine or ketimine, where the acetoacetate group-containing polymer is obtained by reacting a polyepoxide with water, an amine, a hydroxycarboxylic acid and subsequently esterifying or transesterifying the final product using acetoacetic acid. This liquid coating composition is particularly suitable as a binder in two-component automobile repair fillers or as a two-component primer.

公开(公告)号：ES2122101T3

公开(公告)日：1998-12-16

申请号：ES94111031

申请日：1994-07-15

Applicant: HOECHST AG

Inventor： EPPLE ULRICH DR ,  KUBILLUS UWE DR ,  BRINDOPKE GERHARD DR ,  DOSSEL KARL-FRIEDRICH DR

IPC: C08F4/28 ,  C08F4/34 ,  C08F20/10 ,  C08F20/26 ,  C08F212/08 ,  C08F220/04 ,  C08F220/12 ,  C08F220/18 ,  C08F220/26 ,  C08F220/28 ,  C08F220/32 ,  C09D5/00 ,  C09D5/03 ,  C09D133/00 ,  C09D133/02 ,  C09D133/04 ,  C09D133/06 ,  C09D133/14 ,  C09D175/04

Abstract: Copolymers comprising from 5 to 50 % by weight of one or more glycidyl esters of saturated aliphatic C4-C30-monocarboxylic acids containing a tertiary or quaternary alpha -carbon atom and from 95 to 5 % by weight of at least two olefinically unsaturated, copolymerisable monomers, of which at least one contains at least one carboxyl group. The copolymers are characterised by an OH number of from 50 to 250 mg of KOH/g, a solution viscosity of from 15 to 2000 mPa s (50 % strength solution at 23 DEG C), a mean molecular weight (weight average Mw) of less than 8600 g/mol and a nonuniformity of less than 3.4. The copolymers according to the invention are particularly suitable as binder components for high-solids coating compositions.

公开(公告)号：DK0638591T3

公开(公告)日：1998-03-16

申请号：DK94112082

申请日：1994-08-03

Applicant: HOECHST AG

Inventor： KUBILLUS UWE DR ,  SCHMIDT HOLGER DR ,  EPPLE ULRICH DR

IPC: C08F220/32 ,  C08F2/02 ,  C08F220/04 ,  C08F220/06 ,  C08F220/10 ,  C08F222/02 ,  C08G18/62 ,  C09D133/02 ,  C09D133/06 ,  C09D133/14 ,  C09D135/00 ,  C09D175/04

Abstract: Copolymers of particularly low viscosity which can be prepared by bulk polymerisation in which component (A) is introduced at the beginning of the polymerisation and at least two olefinically unsaturated, copolymerisable monomers (B), of which at least one contains at least one COOH group and at least one is sterically hindered, are added during the further course of the polymerisation.

公开(公告)号：DE19510520A1

公开(公告)日：1996-09-26

申请号：DE19510520

申请日：1995-03-23

Applicant: HOECHST AG

Inventor： SCHOEN MANFRED DR ,  KUBILLUS UWE DR ,  OSWALD HARALD ,  NECKE HILMAR

IPC: C08L61/32 ,  C08J3/03 ,  C08J3/07 ,  C08L33/00 ,  C08L61/20 ,  C09D161/20 ,  C09D161/26 ,  C09D161/32 ,  C08L61/28 ,  C09D5/02 ,  C09D175/04

公开(公告)号：GR3002421T3

公开(公告)日：1992-12-30

申请号：GR910400241

申请日：1991-08-02

Applicant: HOECHST AG

Inventor： KUBILLUS UWE DR ,  BRINDOEPKE GERHARD DR ,  PLUM HELMUT DR

IPC: C07C69/34 ,  C07C67/00 ,  C07C231/00 ,  C07C231/02 ,  C07C231/12 ,  C07C233/04 ,  C07C233/09 ,  C07C233/18 ,  C07C233/20 ,  C07C233/36 ,  C07C233/38 ,  C07C235/80 ,  C07C253/00 ,  C07C255/17 ,  C07C255/18 ,  C08G59/40 ,  C08G63/91 ,  C08J3/24 ,  C08K3/16 ,  C08K5/07 ,  C08K5/10 ,  C08K5/20 ,  C08K5/29 ,  C08K5/32 ,  C08L63/10 ,  C09D7/12 ,  C09D163/10

Abstract: A curing agent (A) containing active CH groups is characterised in that it contains at least two groups of the formula (I) or structural units of the formula (I') or (I") in which A is X and Y are identical or different and are CO2R , CN, NO2, CONH2, CONR H or CONR R , where the radicals R may be identical or different and are hydrocarbon radicals, preferably alkyl radicals having 1 to 12 carbon atoms, which may also be interrupted by oxygen or an N-alkyl radical, with the proviso that only one of the two radicals X and Y may be an NO2 group; A' is X' and Y' are identical or different and are Curable mixtures of (A) and a Michael acceptor (B) and optionally diluents and conventional additives cure rapidly even at low temperatures and are particularly suitable for surface-coating compositions.

公开(公告)号：DE3932816A1

公开(公告)日：1991-04-11

申请号：DE3932816

申请日：1989-09-30

Applicant: HOECHST AG

Inventor： HOENEL MICHAEL DR ,  WALZ GERD DR ,  ZIEGLER PETER DR ,  KUBILLUS UWE DR

IPC: C08G59/50 ,  C08L63/00 ,  C08L101/00 ,  C09D5/02 ,  C09D5/44 ,  C09D163/00 ,  C09D201/00 ,  C09D7/12

Abstract: The invention relates to the use of crosslinked polymer microparticles having an average particle size of at most 5 mu m and a glass transition temperature (Tg) of at least +30 DEG C. in aqueous paint preparations as filler and/or as partial substitute of white pigments, in particular of titanium dioxide. Among other things, the corresponding paints show increased spreading power, less tendency for sedimentation and reduced crater formation.

公开(公告)号：ES2114627T3

公开(公告)日：1998-06-01

申请号：ES94104863

申请日：1994-03-28

Applicant: HOECHST AG

Inventor： SCHMIDT HOLGER DR ,  BRUCK TANJA REGINA ,  KUBILLUS UWE DR ,  OSWALD HARALD ,  SCHAUB PETRA ,  TRAVERS-HEMMER ANDREA

IPC: B05D3/02 ,  C08F8/44 ,  C08F12/00 ,  C08F20/10 ,  C08F212/06 ,  C08F220/04 ,  C08F220/06 ,  C08F220/18 ,  C08F220/28 ,  C08F220/32 ,  C08G59/02 ,  C08G59/32 ,  C08J3/07 ,  C08L61/28 ,  C09D5/00 ,  C09D125/00 ,  C09D125/02 ,  C09D125/14 ,  C09D133/02 ,  C09D133/04 ,  C09D133/06 ,  C09D133/10 ,  C09D133/14 ,  C09D161/20 ,  C09D161/28 ,  C09D163/00

Abstract: Water-dilutable dispersions of acrylate copolymers having a hydroxyl number of from 40 to 200 mg of KOH/g and an acid number of from 15 to 50 mg of KOH/g, obtained by free-radical copolymerization of a) from 5 to 40 parts by weight of at least one glycidyl ester of an aliphatic, saturated monocarboxylic acid which is branched in the alpha -position, b) from 0 to 30 parts by weight of at least one diester of an alpha , beta -olefinically unsaturated dicarboxylic acid, c) from 0 to 70 parts by weight of at least one vinyl aromatic hydrocarbon, where the molar amount of component c) is always greater than or equal to the molar amount of component b), d) from 0 to 60 parts by weight of an alkyl ester of an alpha , beta -olefinically unsaturated carboxylic acid, e) from 2 to 40 parts by weight of at least one alpha , beta -olefinically unsaturated carboxylic acid, where the molar amount of component e) is always greater than the molar amount of component a), f) from 5 to 40 parts by weight of at least one hydroxyalkyl ester of an alpha , beta -olefinically unsaturated carboxylic acid, where the polymerisation is carried out in the presence or absence of solvents, optionally with addition of a water-dilutable solvent, neutralisation and dilution with water. These dispersions are suitable as water-dilutable binders for stoving (baking) varnishes or stoving solid-colour top coats.