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公开(公告)号:ES2056988T3
公开(公告)日:1994-10-16
申请号:ES89105014
申请日:1989-03-21
Applicant: HOECHST AG
Inventor: HONEL MICHAEL DR , FINKE MANFRED DR , WALZ GERD DR , ZIEGLER PETER DR
IPC: C08G18/32 , C08G18/38 , C08G18/64 , C08G18/80 , C09D5/44 , C09D175/00 , C09D175/04
Abstract: Curing agents (A) for isocyanate-curable resins (B) which have an amine number of from 20 to 150 mg of KOH/g, a maximum OH number of 20 mg KOH/g and contain, per molecule, at least two capped isocyanate groups which are reactive under the curing conditions, are obtained by reacting A) an amine which contains at least one ss-hydroxyalkyl group per molecule, as an OH number of from 100 to 1200 mg KOH/g and an amine number of from 100 to 1200 mg of KOH/g and optionally also contains NHCO groups, optionally blended with another OH- and/or NH-functional compound, with B) a partially capped polyisocyanate, optionally blended with an at least bifunctional, OH- and/or NH-reactive compound. These curing agents, if necessary after neutralisation, are readily dispersible in aqueous systems and frequently have a stability-increasing action in water-borne paint formulations.
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公开(公告)号:ES2056081T3
公开(公告)日:1994-10-01
申请号:ES88112532
申请日:1988-08-02
Applicant: HOECHST AG
Inventor: HONEL MICHAEL DR , ZIEGLER PETER DR , FOEDDE HARTMUT
Abstract: Curable compounds carrying basic nitrogen groups and essentially comprising structural units derived from A) a compound containing on average at least one terminal 2-oxo-1,3-dioxolane group per molecule, with B) a disecondary amine containing hydroxyl groups in the beta -position to the secondary amino groups, it also being possible for this amine to contain blocked primary amino groups, and optionally C) a bifunctional amine containing at least one free primary amino group and optionally at least one secondary amino group, are used, in particular, in surface coating preparations, especially in electrodeposition coating compositions. The coatings obtainable using these compositions have, in particular optimised interlayer adhesion.
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公开(公告)号:ES2137410T3
公开(公告)日:1999-12-16
申请号:ES95109598
申请日:1995-06-21
Applicant: HOECHST AG
Inventor: NEUMANN UWE DR , HONEL MICHAEL DR , VOLKER ACHIM DR , WALZ GERD DR , WEHNER SUSANNE , ZIEGLER PETER DR
IPC: C08L75/04 , C08F283/10 , C08F290/06 , C08F290/14 , C08G18/08 , C08G18/58 , C08G18/64 , C08G18/67 , C08G18/80 , C08G59/06 , C08G59/14 , C08G59/24 , C08G59/40 , C08G59/50 , C08G59/56 , C08J3/03 , C08L51/08 , C08L63/00 , C08L75/00 , C09D5/44 , C09D175/00 , C09D175/04
Abstract: The aq. synthetic resin dispersions (I) contain: (a) an ionic epoxy resin derived from bisphenol A substd. with aralkyl gp(s)., (b) a capped polyisocyanate, and (c) a polymer of radically polymerisable olefinic monomer(s). Also claimed are: (i) a process for the prodn. of (I) from a mixt. of vinyl monomer (c), resin (a) and blocked di or poly-isocyanate (b), by converting the mixt. into an aq. dispersion and polymerising with a radical initiator; and (ii) articles coated with the dispersion (I).
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公开(公告)号:ES2098236T3
公开(公告)日:1997-05-01
申请号:ES90118375
申请日:1990-09-25
Applicant: HOECHST AG
Inventor: HONEL MICHAEL DR , WALZ GERD DR , ZIEGLER PETER DR , KUBILLUS UWE DR
IPC: C08G59/50 , C08L63/00 , C08L101/00 , C09D5/02 , C09D7/12 , C09D5/44 , C09D163/00 , C09D201/00
Abstract: The invention relates to the use of crosslinked polymer microparticles having an average particle size of at most 5 mu m and a glass transition temperature (Tg) of at least +30 DEG C. in aqueous paint preparations as filler and/or as partial substitute of white pigments, in particular of titanium dioxide. Among other things, the corresponding paints show increased spreading power, less tendency for sedimentation and reduced crater formation.
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公开(公告)号:ES2073848T5
公开(公告)日:1999-05-01
申请号:ES92121047
申请日:1992-12-10
Applicant: HOECHST AG
Inventor: NEUMANN UWE DR , HONEL MICHAEL DR , OBERRESSL PAUL , KELLER MARION
IPC: C08G59/14 , C08G59/18 , C08L63/00 , C08L67/00 , C09D163/00 , C09D167/00
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公开(公告)号:ES2094726T3
公开(公告)日:1997-02-01
申请号:ES89113521
申请日:1989-07-22
Applicant: HOECHST AG
Inventor: HONEL MICHAEL DR , ZIEGLER PETER DR , SPRENGER WALTER , WENDT WOLFGANG
Abstract: The invention relates to paste resins based on epoxide compounds, containing (a) specific quaternary ammonium groups, (b) OH groups and (c) isocyanate radicals bonded to the epoxide compound, of which at least 10 mol% are derived from a long-chain, monofunctional isocyanate having at least 8 carbon atoms, the mean molecular weight (Mn) of these paste resins being 500 to 10000. … In addition, the invention relates to the preparation of these paste resins, to their use for pigment pastes and to these pigment pastes. Water-thinnable paints, in particular electrodeposition paints, which contain the pigment pastes according to the invention give defect-free surfaces and comparable coating thicknesses even on different substrates.
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公开(公告)号:ES2059353T3
公开(公告)日:1994-11-16
申请号:ES87118922
申请日:1987-12-21
Applicant: HOECHST AG
Inventor: BRINDOPKE GERHARD DR , HONEL MICHAEL DR
Abstract: Non-crosslinked reaction products of compounds (A) which contain structural units carrying 1,3-dioxolan-2-one groups in random distribution and compounds (B) which contain at least one primary aliphatic or cycloaliphatic amino group and additionally at least one further basic amino group. These reaction products are suitable, if appropriate together with conventional curing agents, especially as binders for coatings, above all electrodip coatings.
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公开(公告)号:ES2146630T3
公开(公告)日:2000-08-16
申请号:ES94119985
申请日:1994-12-16
Applicant: HOECHST AG
Inventor: HONEL MICHAEL DR , PFEIL ARMIN DR , BUDNICK THOMAS , SCHWAN HEINER DR
IPC: B05D7/24 , B05C9/06 , B05D7/14 , C08G59/50 , C08G71/00 , C08G71/04 , C09D163/00 , C09D175/04
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公开(公告)号:ES2080556T3
公开(公告)日:1996-02-01
申请号:ES93107304
申请日:1993-05-05
Applicant: HOECHST AG
Inventor: WEHNER SUSANNE , KLIMA HEINZ , HONEL MICHAEL DR , ZIEGLER PETER DR , WALZ GERD DR
IPC: C08L63/00 , C08G59/28 , C09D5/44 , C09D175/00 , C09D175/04 , C25D13/06
Abstract: Electrocoating bath containing a urethane of the formula R1-NHCOO-R2 where R1 is alkyl or a group of the formula B1-NH-B2-[X-B3]n-, R2 is a group of the formulae -(C2H4O)y-R1 and -(C3H7O) y-R or of the formula R is C1-C18-alkyl, Y is from zero to 4, B1 is hydrogen, alkyl or a group of the formula -COOR2, B2 and B3 can be identical or different and each is C2-C14-alkylene, n is an integer from 0 to 5, preferably from 0 to 2, X is -O-, -S-, -NH- or @N-(C1-C4)-alkyl, R3 is hydrogen or alkyl, alkenyl, hydroxyalkyl, phenyl or alkylphenyl, R4 and R5 can be identical or different and each is hydrogen or C1-C4-alkyl, and A is a direct bond or one of the groups -O-, -CH2O- or -CH2OCO-. The presence of these urethanes in the electrocoating bath reduces the number of surface defects in galvanised surfaces.
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公开(公告)号:ES2061479T3
公开(公告)日:1994-12-16
申请号:ES87118925
申请日:1987-12-21
Applicant: HOECHST AG
Inventor: HONEL MICHAEL DR , ZIEGLER PETER DR , WALZ GERD DR , LENZ RUDIGER DR , FOEDDE HARTMUT , BRINDOPKE GERHARD DR
IPC: C07C67/00 , C07C239/00 , C07C271/28 , C08G18/32 , C08G71/04 , C09D5/03 , C09D5/44 , C09D175/00 , C09D175/12
Abstract: Aminourethanes, a process for their preparation and their use The invention relates to aminourethanes composed essentially of structural units derived from (A) polyamines of the general formula (I) an/or (II (I) (II) (B) if appropriate, further polyamines, (C) compounds containing, on average, at least one terminal 2-oxo-1,3-dioxolane group per molecule and (D) if appropriate, compounds having a monofunctional reaction, as chain stoppers. The invention also relates to a process for the preparation of these aminourethanes and to their use, in particular in paint formulations and especially in electrodeposition paints.
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