公开(公告)号：US3676414A

公开(公告)日：1972-07-11

申请号：US3676414D

申请日：1969-06-25

Applicant: HOECHST AG

Inventor： DIEDRICH BERND ,  KEIL KARL DIETHER ,  RUST KURT

IPC: C08F2/00 ,  C08F10/02 ,  C08F1/56 ,  C08F3/06

CPC classification number: C08F10/02 ,  C08F4/654

Abstract: The invention provides a process for homopolymerizing or copolymerizing ethylene in the presence of mixed catalysts comprising as component A the reaction products of specific tetravalent titanium compounds with chlorine-containing magnesium compounds containing at least 1.5 moles of OH groups per gramatom of magnesium and as component B an organo-aluminum compound. Under a pressure below 20 atmospheres the yields are so high per unit of catalyst that the residues thereof need not be removed from the polymer. It is possible to produce polymers having a very narrow distribution of molecular weight and very good color and corrosion values.

Abstract translation: 本发明提供了一种在混合催化剂存在下均匀聚合或共聚乙烯的方法，所述混合催化剂包含特定四价钛化合物与每克原子镁至少含有1.5摩尔OH基团的含氯化合物的反应产物作为组分A， 组分B为有机铝化合物。 在低于20个大气压的压力下，每单位催化剂的产率如此之高，使其残余物不需要从聚合物中除去。 可以生产具有非常窄的分子量分布和非常好的颜色和腐蚀值的聚合物。

公开(公告)号：US3644318A

公开(公告)日：1972-02-22

申请号：US3644318D

申请日：1969-06-25

Applicant: HOECHST AG

Inventor： DIEDRICH BERND ,  KEIL KARL DIETHER

IPC: C08F4/64 ,  C08F10/00 ,  C08F1/56 ,  C08F3/02

CPC classification number: C08F10/00 ,  Y10S526/901 ,  C08F4/654

Abstract: PROCESS FOR HOMO- AND COPOLYMERIZING OLEFINS IN THE PRESENCE OF A MIXED CATALYST COMPRISING, AS COMPONENT A, A REACTION PRODUCT OF MAGNESIUM ALCOHOLATES WITH TETRAVALENT HALOGENATED TITANIUM COMPOUNDS AND, AS COMPONENT B, ORGANO-ALUMINUM COMPOUNDS. ALREADY UNDER A PRESSURE OF LESS THAN 20 ATMOSPHERES THE YIELDS PER CATALYST OBTAINED ARE SO HIGH THAT THE REMAINDERS OF CATALYST NEED NOT BE REMOVED FROM THE POLYMER. OPTIONALLY, PRODUCTS CAN ALSO BE PREPARED WHICH HAVE A VERY NARROW MOLECULAR WEIGHT DISTRIBUTION AND VERY GOOD COLOR AND CORROSION VALUES.

公开(公告)号：US3567701A

公开(公告)日：1971-03-02

申请号：US3567701D

申请日：1968-05-01

Applicant: HOECHST AG

Inventor： KEIL KARL DIETHER

IPC: C08F10/00 ,  C08F1/42 ,  C08F3/06

CPC classification number: C08F10/00 ,  C08F4/642

Abstract: THE PRSENT INVENTION RELATES TO A PROCESS FOR THE POLYMERIZATION OF ETHYLENE OR MIXTURES OF ETHYLENE WITH UP TO 10% BY WEIGHT OF HIGHER A-OLEFINS IN THE PRESENCE OF A MIXED CATALYST COMPOSED OF A TRIVALENT CHLORINE-CONTAINING TITANIUM COMPOUND AND AN ALUMINIUM-ORGANIC COMPONENT OBTAINED BY REACTING ACETYLENES WITH ALUMINUM HYDROCARBONS.

公开(公告)号：US3676415A

公开(公告)日：1972-07-11

申请号：US3676415D

申请日：1969-06-25

Applicant: HOECHST AG

Inventor： DIEDRICH BERND ,  KEIL KARL DIETHER ,  RUST KURT

IPC: C07F7/00 ,  C08F10/02 ,  C08F1/56 ,  C08F3/06

CPC classification number: C07F7/006 ,  C08F10/02 ,  Y10S526/901 ,  C08F4/654

Abstract: The invention provides a process for homopolymerizing or copolymerizing ethylene in the presence of mixed catalysts comprising as component A the reaction products of specific tetravalent titanium compounds with halogen-free magnesium compounds containing 0.1 to 2 moles of OH groups per gram-atom of magnesium and as component B an organo-aluminum compound. Under a pressure below 20 atmospheres the yields are so high per unit of catalyst that the residues thereof need not be removed from the polymer. It is possible to produce polymers having a very narrow distribution of molecular weight and very good color and corrosion values.

Abstract translation: 本发明提供了一种在混合催化剂存在下均匀聚合或共聚乙烯的方法，其包含特定四价钛化合物与每克原子镁含0.1至2摩尔OH基的无卤镁化合物的反应产物作为组分A， 组分B为有机铝化合物。 在低于20个大气压的压力下，每单位催化剂的产率如此之高，使其残余物不需要从聚合物中除去。 可以生产具有非常窄的分子量分布和非常好的颜色和腐蚀值的聚合物。

公开(公告)号：US3513143A

公开(公告)日：1970-05-19

申请号：US3513143D

申请日：1967-03-03

Applicant: HOECHST AG

Inventor： DIEDRICH BERND ,  KEIL KARL DIETHER ,  HOFMANN KLAUS

IPC: C08F210/00 ,  C08F15/04

CPC classification number: C08F210/00

公开(公告)号：US3432573A

公开(公告)日：1969-03-11

申请号：US3432573D

申请日：1966-09-27

Applicant: HOECHST AG

Inventor： KEIL KARL DIETHER

IPC: C07C7/148 ,  C07C7/00 ,  C07C3/10

CPC classification number: C07C7/148 ,  C07C11/02

公开(公告)号：FI51708C

公开(公告)日：1977-03-10

申请号：FI192069

申请日：1969-06-27

Applicant: HOECHST AG

Inventor： DIEDRICH BERND ,  KEIL KARL DIETHER

IPC: C08F4/64 ,  C08F10/00 ,  C08F4/02

公开(公告)号：FI51708B

公开(公告)日：1976-11-30

申请号：FI192069

申请日：1969-06-27

Applicant: HOECHST AG

Inventor： DIEDRICH BERND ,  KEIL KARL DIETHER

IPC: C08F4/64 ,  C08F10/00 ,  C08F4/02

Abstract: 1275142 Supported olefin polymerization catalyst FARBWERKE HOECHST AG 21 Aug 1969 [21 Aug 1968 6 June 1969] 41828/69 Heading C3P Olefins are polymerized in the presence of (a) the reaction product of a magnesium alcoholate, mainly acting as a carrier, and a tetravalent halogen-containing titanium compound and (b) an organo-aluminium compound. The titanium compound may be prepared in situ for reaction with the magnesium compound. The magnesium alcoholate may include halogen, sulphate, carboxylate or hydroxy groups. The alcoholate may be reacted with other inert inorganic compounds, particularly magnesium compounds containing hydroxy groups, prior to reaction with the titanium compound. The mixture of magnesium compounds may be obtained by directly mixing or by partial hydrolysis of the magnesium alcoholate. In examples, Mg(OCH 3 ) 2 , Mg(OC 2 H 5 ) 2 or mixtures thereof with Mg(OH) 2 are reacted with TiCl 4 , TiCl 4 / Ti(O - i - C 3 H 7 ) 4 mixture, TiCl 4 /Ti(O - i- C 4 H 9 ) 4 mixture, or TiCl 2 (O-i-C 3 H 7 ) 2 and then mixed with Al(i-C 4 H 9 ) 3 , Al(C 2 H 5 ) 3 , Al(C 2 H 5 ) 2 H, or Al 2 Cl 3 (C 2 H 5 ) 3 and the catalysts used to polymerize ethylene or an ethylene/butene mixture.