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    3.
    发明专利
    未知

    公开(公告)号：BR9703064A

    公开(公告)日：1998-11-10

    申请号：BR9703064

    申请日：1997-05-06

    Applicant: HOECHST AG

    Inventor： LAPPE PETER ,  MUELLER THOMAS ,  BAHRMANN HELMUT

    IPC: C07C45/50 ,  C07F9/50

    Abstract: Ammonium diphosphine-carboxylates, -sulphonates or -phosphonates of formula (I) are new (where, R1 = COO , SO3 , PO3 or 2-aminoethane bisphosphonate Ä-NH-CH2-CH(PO3 )2Ü group; R2 = linear alkylene with 1-8 carbon (C) atoms, 2-6 C alkylene containing oxygen, 3-10 C cycloalkylene or a group of formulae(II), (III), (IV) or (V); at least one of a, b, c, d, e, f, g, h, k, l = 1, otherwise 0; x = 0 or 1; R3, R4 = 4-26 C alkyl, optionally substituted 6-10 C aryl or 6-10 C cycloalkyl or benzyl and R3 may also = H).

    METHOD OF SEPARATING PHOSPHIN AND ALKYLARYLPHOSPHIN OXIDES FROM A HYDROFORMYLATION REACTION MIXTURE CONSTITUTING HOMOGENOUS MEDIUM
    4.
    发明专利
    METHOD OF SEPARATING PHOSPHIN AND ALKYLARYLPHOSPHIN OXIDES FROM A HYDROFORMYLATION REACTION MIXTURE CONSTITUTING HOMOGENOUS MEDIUM 未知

    公开(公告)号：PL321489A1

    公开(公告)日：1998-02-16

    申请号：PL32148997

    申请日：1997-08-06

    Applicant: HOECHST AG

    Inventor： BAHRMANN HELMUT ,  MUELLER THOMAS

    IPC: C07B63/00 ,  B01J31/40 ,  C07C45/50 ,  C07F9/02 ,  C07F9/50 ,  C07F9/53

    Abstract: The separation of phosphine oxides (I) and alkylarylphosphines (II) from an organic reaction mixture from homogeneous hydroformylation is carried out using a catalyst system of organometallic complex compounds and a molar excess of ammonium salts (III) of aromatic phosphines as ligand. The reaction mixture is extracted with a 0.01-0.5 wt.% alkali hydroxide solution, then the aqueous phase containing (I) and (II) is separated. (III) are e.g. alkyl- and/or arylammonium salts (IIIA) of sulphonated or carboxylated triarylphosphines or salts (IIIB) of amino-substituted triarylphosphines and organic carboxylic or sulphonic acids, etc;in which X, A, R = a sulphonate (SO3 ) or carboxylate (COO ) group or R = a phosphonate (PO3 ) or 2-aminoethane bisphosphonate Ä-NH-CH2-CH(PO3 )2Ü group; at least one of a , b, c = 1, the rest = 0 or 1, n = 1, 2 or 3; R , R - 4-30 carbon (C) alkyl or 6-10 C aryl or cycloalkyl and R may also = hydrogen (H); R = H or 1-12 C alkyl; R = 1-25 C alkyl or 6-10 C aryl; R = linear 1-8 C alkylene, 2-6 C alkylene with ether oxygen (O) in the chain, 3-10 C cycloalkylene or a group e.g. of formula (IVA); at least one of d, e, f, g, h, k, l, m, o, p = 1, the rest = 0 or 1; y = (d+e+f+g+h+k+l+m+o+p); x = 0 or 1; R , R = 4-26 C alkyl, benzyl or optionally substituted 6-10 C aryl or cycloalkyl and R may also = H; R = H or 1-12 C alkyl; R = linear 1-8 C alkylene, 2-4 C alkylene with ether O in the chain, 3-10 C cycloalkylene, (IVA; h = 0) or (IVB; e = 0); R = 1-25 C alkyl or 6-10 C aryl; q = 0 and r, s, t = 1; or q, r = 1 and s, t = 1 or 2; or, if R = (IVA) or (IVB), q = 1, r = 0 and s, t = 0 or 1.

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