Hydrogenation Catalyst, a Process for Its Preparation and the Use Thereof

    公开(公告)号:CA2119388A1

    公开(公告)日:1994-09-28

    申请号:CA2119388

    申请日:1994-03-18

    Applicant: HOECHST AG

    Abstract: A hydrogenation catalyst is specified containing nickel, nickel oxide, magnesium oxide, sodium oxide and a water-insoluble support material, which is characterised in that the hydrogenation catalyst is composed of 25 to 50% by weight of nickel (metallic) 10 to 35% by weight of nickel oxide 4 to 12% by weight of magnesium oxide 1 to 5% by weight of sodium oxide remainder support material and the sum of nickel and nickel oxide is 40 to 70% by weight, the hydrogenation catalyst having a BET surface area of 80 to 200 m /g and a total pore volume, determined by Hg porosimetry, of 0.35 to 0.6 ml/g and the total pore volume being divided up into 30 to 60% by volume having a pore radius of 40 to 300 ANGSTROM , 30 to 60% by volume having a pore radius of > 300 to 5000 ANGSTROM . In addition, a process for the production of the hydrogenation catalyst is specified, which is characterised in that a green catalyst is prepared in a precipitation stage from nickel salt, magnesium salt, soda and support material, this green catalyst, after separating off the mother liquor and partial washing, is slurried in alkali solution, separated off from the liquid phase, dried and the dried green catalyst is treated with hydrogen until 42 to 83% by weight of the total nickel content is present in metallic form. The hydrogenation catalyst according to the invention is suitable in particular for the hydrogenation of propanal, n-butanal and i-butanal at temperatures between 100 and 160@C.

    PROCESS FOR THE PREPARATION OF 2-AMINOMETHYLPIPERIDINE

    公开(公告)号:CA2079155A1

    公开(公告)日:1993-04-03

    申请号:CA2079155

    申请日:1992-09-25

    Applicant: HOECHST AG

    Abstract: 6230 Frankfurt 80, 30.09.1991 PAT-bin-hrr Hoe91/Y006 Hoechst Aktiengesellschaft, 6230 Frankfurt am Main 80 The present invention relates to a process for the preparation of 2-aminomethylpiperidine by the catalytic hydrogenation of 2-cyanopyridine in the presence of a cobalt-containing catalyst at elevated temperature and under elevated pressure. The reaction can be carried out either in two steps or in a single stage.

    POLYMER ELECTROLYTES AND PROCESS FOR THEIR PREPARATION

    公开(公告)号:CA2215911C

    公开(公告)日:2008-05-20

    申请号:CA2215911

    申请日:1996-03-19

    Applicant: HOECHST AG

    Abstract: A sulfonated aromatic polyether ketone of the formula (II) [[Ar-O-]p -Ar'-]x-O-Ar]m-[CO-Ar'-]y-[O-Ar-]n-CO-] (II) in which from 1% to 100% of the O-phenylene-CO units are substituted with an SO3M group, with sulfonated and unsulfonated O-phenylene-CO units and sulfonated and unsulfonated O-phenylene-O units being able to be in any desired sequence with respect to one another, and where Ar, Ar' , M, x, n, m, y and p are, defined as follows: Ar is a phenylene ring with para and/or meta bonds, Ar' is a phenylene, naphthylene, biphenylylene or anthrylene unit or another divalent aromatic unit, x, n and m independently of one another are 0 or 1, y is 0, 1, 2 or 3, p is 1, 2, 3 or 4, and M, taking into account the ionic valencies, comprises one or more elements selected from the following group : H, NR4 +, where R = H or C1-C4-alkyl, or a metal, preferably an alkali metal or alkaline earth metal or a metal from subgroup 8, with the exception of the combination p=1, m=0, Y=2, n=1.

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