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公开(公告)号：JPH06157660A
公开(公告)日：1994-06-07
申请号：JP19258393
申请日：1993-08-03
Applicant: HOECHST AG
Inventor： WINTER ANDREAS , ROHRMANN JUERGEN , ANTBERG MARTIN , SPALECK WALTER , HERRMANN WOLFGANG A , RIEPL HERBERT
IPC: C07F17/00 , C08F4/60 , C08F4/639 , C08F4/6392 , C08F4/642 , C08F4/6592 , C08F4/76 , C08F10/00 , C08F110/06
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2.发明专利
公开(公告)号：JP2002265486A
公开(公告)日：2002-09-18
申请号：JP2002002357
申请日：2002-01-09
Applicant: HOECHST AG
Inventor： RIEPL HERBERT , HERRMANN WOLFGANG A , ROHRMANN JUERGEN
IPC: B01J31/22 , C07B61/00 , C07F7/08 , C07F7/22 , C07F7/30 , C07F17/00 , C08F4/602 , C08F4/639 , C08F4/6392 , C08F4/64 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/06
Abstract: PROBLEM TO BE SOLVED: To obtain a bridged metallocene having a bis cyclic derivative of cyclopentadiene in which the cyclopentadiene may be additionally substituted as a ligand. SOLUTION: The compound of this invention is expressed by general formula XI (wherein M expresses Ge or Sn, R and R are mutually the same or different and express each H, a halogen, a 1-10C alkyl, a 6-10C aryl, a 2-10C alkenyl; a 7-40C arylalkyl, a 8-40C arylalkenyl or a 7-40C alkylaryl or R and R may form a ring together with atoms bonded to them; p expresses 1, 2 or 3 and n expresses 2-18 integer).
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公开(公告)号：EP0672674A3
公开(公告)日：1998-08-12
申请号：EP95108100
申请日：1989-11-24
Applicant: HOECHST AG
Inventor： HERRMANN WOLFGANG PROF DR , KULPE JUERGEN , KELLNER JUERGEN , RIEPL HERBERT
IPC: B01J31/24 , B01J31/16 , B01J31/18 , B01J31/20 , B01J31/22 , C07B61/00 , C07C2/86 , C07C5/03 , C07C13/18 , C07C13/26 , C07C15/48 , C07C45/30 , C07C45/49 , C07C45/50 , C07C45/62 , C07C47/02 , C07C49/04 , C07C49/403 , C07C201/08 , C07C205/06 , C07C209/32 , C07C209/36 , C07C209/60 , C07C211/21 , C07D301/00 , C07D303/04 , C07F1/00 , C07F9/04 , C07F9/50 , C07F9/53 , C07F13/00 , C07F15/00 , C07F15/02 , C07F15/04 , C07F15/06 , C07F19/00
CPC classification number: C07F15/065 , B01J31/20 , B01J31/2295 , B01J31/2404 , B01J2231/32 , B01J2231/321 , B01J2231/4205 , B01J2231/4266 , B01J2231/641 , B01J2231/645 , B01J2231/70 , B01J2531/72 , B01J2531/821 , B01J2531/822 , B01J2531/827 , B01J2531/828 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07C45/30 , C07C45/49 , C07C45/50 , C07C45/62 , C07C209/325 , C07C209/36 , C07C209/60 , C07D301/14 , C07D303/04 , C07F1/005 , C07F9/5045 , C07F13/005 , C07F15/0013 , C07F15/004 , C07F15/0053 , C07F15/008 , C07F15/0093 , C07F15/025 , C07F15/045 , C07C49/04
Abstract: Gegenstand der Erfindung sind neue Komplexverbindungen von Elementen der Gruppe VII A des Periodensystems mit dem Trinatriumsalz von Tris(m-sulfophenyl)-phosphan als Komplexliganden und die Verwendung dieser Komplexverbindungen als Katalysatoren für Hydrierungen für die Wassergas-Reaktion, für Hydrocarbonylierungen, Hydroformylierungen, Oxidationen, CC-Verknüpfungsreaktionen (zB Allen/Alkin-Kupplung) und Additionen von sekundären Aminen an CC-Doppelbindungen.
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公开(公告)号：EP0668287A3
公开(公告)日：1998-08-12
申请号：EP95108099
申请日：1989-11-24
Applicant: HOECHST AG
Inventor： HERRMANN WOLFGANG PROF DR , KULPE JUERGEN , KELLNER JUERGEN , RIEPL HERBERT
IPC: B01J31/24 , B01J31/16 , B01J31/18 , B01J31/20 , B01J31/22 , C07B61/00 , C07C2/86 , C07C5/03 , C07C13/18 , C07C13/26 , C07C15/48 , C07C45/30 , C07C45/49 , C07C45/50 , C07C45/62 , C07C47/02 , C07C49/04 , C07C49/403 , C07C201/08 , C07C205/06 , C07C209/32 , C07C209/36 , C07C209/60 , C07C211/21 , C07D301/00 , C07D303/04 , C07F1/00 , C07F9/04 , C07F9/50 , C07F9/53 , C07F13/00 , C07F15/00 , C07F15/02 , C07F15/04 , C07F15/06 , C07F19/00
CPC classification number: C07F15/065 , B01J31/20 , B01J31/2295 , B01J31/2404 , B01J2231/32 , B01J2231/321 , B01J2231/4205 , B01J2231/4266 , B01J2231/641 , B01J2231/645 , B01J2231/70 , B01J2531/72 , B01J2531/821 , B01J2531/822 , B01J2531/827 , B01J2531/828 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07C45/30 , C07C45/49 , C07C45/50 , C07C45/62 , C07C209/325 , C07C209/36 , C07C209/60 , C07D301/14 , C07D303/04 , C07F1/005 , C07F9/5045 , C07F13/005 , C07F15/0013 , C07F15/004 , C07F15/0053 , C07F15/008 , C07F15/0093 , C07F15/025 , C07F15/045 , C07C49/04
Abstract: Gegenstand der Erfindung sind neue Komplexverbindungen von Elementen der Gruppe IB des Periodensystems mit dem Trinatriumsalz von Tris(m-sulfophenyl)-phosphan als Komplexliganden und die Verwendung dieser Komplexverbindungen als Katalysatoren für Hydrierungen für die Wassergas-Reaktion, für Hydrocarbonylierungen, Hydroformylierungen, Oxidationen, CC-Verknüpfungsreaktionen (zB Allen/Alkin-Kupplung) und Additionen von sekundären Aminen an CC-Doppelbindungen.
Abstract translation: 本发明涉及周期表的与三（间 - 磺苯基）膦作为配合物配位体和使用这些配位化合物作为催化剂用于水煤气反应氢化反应，Hydrocarbonylierungen，加氢甲酰化，氧化，CC的三钠盐IB族的元素的新的配位化合物 - 连接反应（例如Allen /炔偶联）和仲胺添加到CC双键。
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公开(公告)号：DE4039451A1
公开(公告)日：1992-06-17
申请号：DE4039451
申请日：1990-12-11
Applicant: HOECHST AG
Inventor： HERRMANN WOLFGANG ANTON PROF D , RIEPL HERBERT , ROHRMANN JUERGEN DR
IPC: C07B61/00 , C07F7/08 , C07F7/22 , B01J31/22 , C07F7/30 , C07F17/00 , C08F4/602 , C08F4/639 , C08F4/6392 , C08F4/64 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/06
Abstract: The invention relates to a process for the preparation of a compound of the formula XI (XI) wherein preferably M1 is zirconium, the radicals R1 are alkyl, the radicals R2 are halogen or alkyl, R3 is dimethylsilyl or ethylene and n is 2-18, wherein a compound of the formula II (II) is reacted with an alkali metal or alkaline earth metal salt of a malonic ester and then with an alkyl halide, the reaction product is converted by decarboxylation into the corresponding lactone, which is further reacted by known methods to give the compound XI. The compounds of the formula XI, some of which are novel, can advantageously be used as catalysts for olefin polymerization.
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Patent Agency Ranking
公开(公告)号：AU618427B2
公开(公告)日：1991-12-19
申请号：AU4572189
申请日：1989-12-01
Applicant: HOECHST AG
Inventor： HERRMANN WOLFGANG A PROF DR , KULPE JURGEN , KELLNER JURGEN , RIEPL HERBERT
IPC: B01J31/24 , B01J31/16 , B01J31/18 , B01J31/20 , B01J31/22 , C07B61/00 , C07C2/86 , C07C5/03 , C07C13/18 , C07C13/26 , C07C15/48 , C07C45/30 , C07C45/49 , C07C45/50 , C07C45/62 , C07C47/02 , C07C49/04 , C07C49/403 , C07C201/08 , C07C205/06 , C07C209/32 , C07C209/36 , C07C209/60 , C07C211/21 , C07D301/00 , C07D303/04 , C07F1/00 , C07F9/04 , C07F9/50 , C07F9/53 , C07F13/00 , C07F15/00 , C07F15/02 , C07F15/04 , C07F15/06 , C07F19/00 , C07B43/04 , C07C45/27 , C07F17/00 , C07F1/08 , C07F1/10 , C07F1/12 , C07B33/00 , C07B35/00 , C07B41/00 , C07B41/06 , C07B37/02 , B01J23/28 , C07D301/03 , C07C209/66
Abstract: The invention relates to novel complex compounds of elements from groups VII A, VIII A and I B of the Periodic Table with the trisodium salt of tris(m-sulphophenyl)phosphine as complex ligands, and to the use of these complex compounds as catalysts for hydrogenations, for the water gas reaction, for hydrocarbonylations, hydroformylations, oxidations, C-C linking reactions (e.g. allene/alkyne coupling) and addition reactions of secondary amines with C-C double bonds.
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公开(公告)号：ZA9109717B
公开(公告)日：1992-09-30
申请号：ZA9109717
申请日：1991-11-10
Applicant: HOECHST AG
Inventor： RIEPL HERBERT , HERBERT RIEPL , HERRMANN WOLFGANG ANTON , WOLFGANG ANTON HERRMANN , ROHRMANN JUERGEN , JUERGEN ROHRMANN
IPC: B01J31/22 , C07B61/00 , C07F7/08 , C07F7/22 , C07F7/30 , C07F17/00 , C08F4/602 , C08F4/639 , C08F4/6392 , C08F4/64 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/06 , C07F , C08F
CPC classification number: C07F17/00 , C08F4/63912 , C08F4/63927 , C08F10/00 , C08F110/06 , Y10S526/943 , C08F2500/17 , C08F2500/15 , C08F2500/20 , C08F2500/03
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公开(公告)号：DE59108612D1
公开(公告)日：1997-04-17
申请号：DE59108612
申请日：1991-12-04
Applicant: HOECHST AG
Inventor： RIEPL HERBERT , HERRMANN WOLFGANG PROF DR , ROHRMANN JUERGEN DR
IPC: C07B61/00 , C07F7/08 , B01J31/22 , C07F7/22 , C07F7/30 , C07F17/00 , C08F4/602 , C08F4/639 , C08F4/6392 , C08F4/64 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/06
Abstract: The invention relates to a process for the preparation of a compound of the formula XI (XI) wherein preferably M1 is zirconium, the radicals R1 are alkyl, the radicals R2 are halogen or alkyl, R3 is dimethylsilyl or ethylene and n is 2-18, wherein a compound of the formula II (II) is reacted with an alkali metal or alkaline earth metal salt of a malonic ester and then with an alkyl halide, the reaction product is converted by decarboxylation into the corresponding lactone, which is further reacted by known methods to give the compound XI. The compounds of the formula XI, some of which are novel, can advantageously be used as catalysts for olefin polymerization.
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公开(公告)号：AU648847B2
公开(公告)日：1994-05-05
申请号：AU8892891
申请日：1991-12-10
Applicant: HOECHST AG
Inventor： RIEPL HERBERT , ROHRMANN JURGEN DR , HERRMANN WOLFGANG ANTON PROF D
IPC: B01J31/22 , C07B61/00 , C07F7/08 , C07F7/22 , C07F7/30 , C07F17/00 , C08F4/602 , C08F4/639 , C08F4/6392 , C08F4/64 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/06 , C08F4/76
Abstract: The invention relates to a process for the preparation of a compound of the formula XI (XI) wherein preferably M1 is zirconium, the radicals R1 are alkyl, the radicals R2 are halogen or alkyl, R3 is dimethylsilyl or ethylene and n is 2-18, wherein a compound of the formula II (II) is reacted with an alkali metal or alkaline earth metal salt of a malonic ester and then with an alkyl halide, the reaction product is converted by decarboxylation into the corresponding lactone, which is further reacted by known methods to give the compound XI. The compounds of the formula XI, some of which are novel, can advantageously be used as catalysts for olefin polymerization.
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公开(公告)号：ZA899003B
公开(公告)日：1990-08-29
申请号：ZA899003
申请日：1989-11-24
Applicant: HOECHST AG
Inventor： HERRMANN WOLFGANG A , WOLFGANG A HERRMANN , KULPE JUERGEN , JUERGEN KULPE , KELLNER JUERGEN , JUERGEN KELLNER , RIEPL HERBERT , HERBERT RIEPL
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