Abstract:
This invention relates to a light-sensitive copying composition for the manufacture of screens for cathode ray tubes, comprising a dispersion of a phosphor pigment in an aqueous solution of a hydrophilic cross-linkable binder and a sensitizer, the sensitizer being a condensation product of an aromatic diazonium compound containing recurrent units of the general types A-N2X and B, which are connected by methylene groups, said units A-N2X being derived from compounds of the general formula (R1-R3)pR2N2X wherein X is the anion of an aliphatic monosulfonic acid with one to six carbon atoms, P IS AN INTEGER FROM 1 TO 3, R1 is a carbocyclic or heterocyclic aromatic group, having at least one condensable position, R2 is an arylene group of the benzene or naphthalene series, R3 is either a single bond or one of the following groups: -(CH2)q-NR4-(CH2)q-NR4-(CH2)r-NR5-O-(CH2)r-NR4-S-(CH2)r-NR4-O-R6-O-O-S-CO -NR4-SO2-NR4wherein Q IS AN INTEGER FROM 0 TO 5, R IS AN INTEGER FROM 2 TO 5, R4 is either hydrogen, or an alkyl group with one to five carbon atoms, or an aralkyl group with seven to 12 carbon atoms, or an aryl group with six to 12 carbon atoms, R5 is hydrogen or an alkyl group with one to five carbon atoms, and R6 is an arylene group with six to 12 carbon atoms AND SAID UNITS B being radicals, free of diazonium groups, of the following compounds: aromatic amines, phenols, thiophenols, phenol ethers, aromatic thioethers, aromatic hydrocarbons, aromatic heterocyclic compounds, or organic acid amides. The invention also includes a process for the manufacture of a screen for a cathode ray tube employing the novel light-sensitive composition.
Abstract:
This invention relates to a light-sensitive composition comprising at least one diazonium salt mixed condensate and at least one compound selected from the group consisting of an oquinone diazide sulfonic amide and an o-quinone diazide sulfonic ester.
Abstract:
This invention relates to a radiation-sensitive copying composition comprising a compound (1) which splits-off an acid upon irradiation and a compound (2) having at least one group selected from the group consisting of a carboxylic ortho acid ester group and a carboxylic acid amide acetal group, which composition, upon irradiation, forms an exposure product having a higher solubility in a liquid developer than the non-irradiated composition.
Abstract:
Compounds of the formula I … … are described in which L denotes H or CO-(R )n(CX3)m, M denotes alkylene, alkenylene or arylene, Q denotes S, Se, O, dialkylmethylene, alken-1,2-ylene, 1,2-phenylene or N-R, where M + Q together form 3 or 4 ring members, R denotes alkyl, aralkyl or alkoxyalkyl, R denotes an aromatic group, and X denotes Cl, Br or I and n = 0 and m = 1 or n = 1 and m = 1 or 2. The compounds eliminate HX on irradiation and form radicals. They are therefore highly active acid donors and radical initiators for photochemical processes.
Abstract:
A positive-working radiation-sensitive mixture is described which is composed of a compound having at least one C-O-C bond which can be split by acid, a compound which forms a strong acid when irradiated, a binder which is insoluble in water and soluble in aqueous-alkaline solutions, and a resin having solubility properties which differ from those of the binder and which is selected from (1) a polyurethane resin obtained from an organic isocyanate and a polymer which contains hydroxyl groups, (2) a polyvinyl alkyl ether, (3) an alkyl acrylate polymer, or (4) a hydrogenated or partially hydrogenated derivative of colophony. As a result of the resin additives, photoresist layers are obtained which have good adhesion to the support, good flexibility, good latitude in developing and good resolution.
Abstract:
This invention relates to a light-sensitive composition comprising at least one diazonium salt mixed condensate and at least one compound selected from the group consisting of an o-quinone diazide sulfonic amide and an o-quinone diazide sulfonic ester.
Abstract:
This invention relates to a light-sensitive composition comprising at least one diazonium salt mixed condensate and at least one compound selected from the group consisting of an o-quinone diazide sulfonic amide and an o-quinone diazide sulfonic ester.