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公开(公告)号:IN171309B
公开(公告)日:1992-09-12
申请号:IN990CA1990
申请日:1990-11-22
Applicant: HOECHST AG
Inventor: PAPENFUHS THEODOR , SCHUBERT HANS , HESS REINER
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公开(公告)号:AU7865691A
公开(公告)日:1991-12-31
申请号:AU7865691
申请日:1991-05-18
Applicant: HOECHST AG
Inventor: GILB WALTER , GROTSCH GEORG , SCHUBERT HANS
IPC: B01J27/08 , C07B61/00 , C07C45/46 , C07C49/813
Abstract: PCT No. PCT/EP91/00929 Sec. 371 Date Nov. 25, 1992 Sec. 102(e) Date Nov. 25, 1992 PCT Filed May 18, 1991 PCT Pub. No. WO92/18862 PCT Pub. Date Dec. 12, 1991.Process for producing 1,4-bis-(4-fluorbenzoyl)-benzol by reacting terephthaloyl chloride with fluorbenzol in the presence of aluminium chloride or aluminium bromide, characterized in that aluminium chloride or aluminium bromide is added in metered quantities to a mixture of terephthaloyl chloride and fluorbenzol at temperatures of approximately 25 degrees C. to approximately 68 degrees C. and the mixture is allowed to react at said temperatures.
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公开(公告)号:CA2083715A1
公开(公告)日:1991-11-26
申请号:CA2083715
申请日:1991-05-18
Applicant: HOECHST AG
Inventor: GILB WALTER , GROETSCH GEORG , SCHUBERT HANS
IPC: B01J27/08 , C07B61/00 , C07C45/46 , C07C49/813
Abstract: Process for producing 1,4-bis-(4-fluorbenzoyl)-benzol by reacting terephthaloyl chloride with fluorbenzol in the presence of aluminium chloride or aluminium bromide characterized in that aluminium chloride or aluminium bromide is added in metered quantities to a mixture of terephthaloyl chloride and fluorbenzol at temperalures of approximately 25.degree.C to approximately 68.degree.C and the mixture is allowed to react at said temperatures.
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公开(公告)号:CA2031444A1
公开(公告)日:1991-06-06
申请号:CA2031444
申请日:1990-12-04
Applicant: HOECHST AG
Inventor: PAPENFUHS THEODOR , SCHUBERT HANS , HESS REINER
Abstract: HOE 89/F 383 Process for the preparation of 3,4'-dichlorodiphenyl ether A process for the preparation of 3,4'-dichlorodiphenyl ether from 1,3-dichlorobenzene and 4-chlorophenol, which comprises mixing 1 mol of 4-chlorophenol with about 2 to about 6 mol of initially introduced 1,3-dichlorobenzene and about 1 to about 3 mol of potassium carbonate in about 1 to about 5 mol of a dipolar aprotic solubilizer which boils above l60.degree.C, at temperatures of about 160.degree.C to about 190.degree.C with stirring, then adding about 0.0l to about 1 mol-% of basic copper carbonate of the formula Cu(OH)2?CuCO3?0.5 H2O and heating with stirring to about 170 to about 173.degree.C while removing the water formed by distillation, then optionally adding further 4-chloxo-phenol with the proviso that from the start the amount of 1,3-dichlorobenzene present in terms of moles is always 1 to 3 mol greater than the totally added amount of 4-chlorophenol and, if desired, additionally adding basic copper carbonate of the formula mentioned if at the start less than 0.1 mol-% had been added, additionally stirring within the last-mentioned temperature range and finally working up after allowing to cool.
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公开(公告)号:MX156075A
公开(公告)日:1988-06-28
申请号:MX19195482
申请日:1982-03-24
Applicant: HOECHST AG
Inventor: SCHUBERT HANS , BAESSLER KONRAD
IPC: C07C67/00 , C07C209/00 , C07C211/50 , C07C209/10 , C07C211/42 , C07C211/51 , C07C87/50 , C07C85/26
Abstract: Crude 3,4,3',4'-tetraaminodiphenyl (TAD) prepared by ammonolysis of 3,3'-dichlorobenzidine in the presence of mainly Cu catalysts is purified by a process in which (a) after its isolation from the preparation process crude TAD is treated with an aqueous NH3 solution and, if desired, TAD thus treated is then (b) dissolved and reprecipitated in water in the presence of adsorbents and also of a water-soluble reducing agent. Compared with relevant processes of the state of the art, the process produces a higher yield of pure TAD and it is also simpler to carry out.
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公开(公告)号:IN177610B
公开(公告)日:1997-02-08
申请号:IN805CA1994
申请日:1994-10-03
Applicant: HOECHST AG
Inventor: ARNDT OTTO , SCHUBERT HANS
IPC: C07C50/24
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公开(公告)号:BR9106498A
公开(公告)日:1993-05-25
申请号:BR9106498
申请日:1991-05-18
Applicant: HOECHST AG
Inventor: GILB WALTER , GROETSCH GEORG , SCHUBERT HANS
IPC: B01J27/08 , C07B61/00 , C07C45/46 , C07C49/813
Abstract: PCT No. PCT/EP91/00929 Sec. 371 Date Nov. 25, 1992 Sec. 102(e) Date Nov. 25, 1992 PCT Filed May 18, 1991 PCT Pub. No. WO92/18862 PCT Pub. Date Dec. 12, 1991.Process for producing 1,4-bis-(4-fluorbenzoyl)-benzol by reacting terephthaloyl chloride with fluorbenzol in the presence of aluminium chloride or aluminium bromide, characterized in that aluminium chloride or aluminium bromide is added in metered quantities to a mixture of terephthaloyl chloride and fluorbenzol at temperatures of approximately 25 degrees C. to approximately 68 degrees C. and the mixture is allowed to react at said temperatures.
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公开(公告)号:CA1195342A
公开(公告)日:1985-10-15
申请号:CA399109
申请日:1982-03-23
Applicant: HOECHST AG
Inventor: SCHUBERT HANS , BAESSLER KONRAD
IPC: C07C211/50 , C07C67/00 , C07C209/00 , C07C209/10 , C07C211/42 , C07C211/51 , C07C87/58
Abstract: of the disclosure: Crude 3,4,3',4'-tetraaminodiphenyl (TAD) prepared by ammonolysis of 3,3'-dichlorobenzidine in the presence of mainly Cu catalysts is purified by a process in which a) after its isolation from the preparation process crude TAD is treated with an aqueous NH3 solution and, if desired, TAD thus treated is then b) dissolved and reprecipitated in water in the presence of adsorbents and also of a water-soluble reducing agent. Compared with relevant processes of the state of the art, the process produces a higher yield of pure TAD and it is also simpler to carry out.
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公开(公告)号:IN173459B
公开(公告)日:1994-05-07
申请号:IN954CA1991
申请日:1991-12-27
Applicant: HOECHST AG
Inventor: FOLZ GEORG , PAPENFUHS THEODOR , SCHUBERT HANS
IPC: C07C205/00
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10.
公开(公告)号:SG52792A1
公开(公告)日:1998-09-28
申请号:SG1996009640
申请日:1996-04-30
Applicant: HOECHST AG
Inventor: PFIRMANN RALF , SCHUBERT HANS
IPC: B01J23/72 , C07B37/06 , C07B61/00 , C07C1/207 , C07C15/02 , C07C17/363 , C07C25/02 , C07C37/50 , C07C39/02 , C07C39/24 , C07C51/38 , C07C63/70 , C07C65/03 , C07C65/21 , C07C65/05
Abstract: Prodn. of an aromatic cpd. of formula (I) comprises decarboxylation of the corresp. benzoic acid of formula (II) in aq. soln. in the presence of an inert amine (III) which is insol. in water at pH 3-9 and a temp. of 70-210 degrees C. The reaction mixt. opt. contains a decarboxylation catalyst (V) and opt. an inert, water-insol. solvent (VI). R1-R5 = H, COOH, F, Cl, Br, CF3, OH, 1-4C alkyl, 1-4C alkoxy or NR'R"; R = R4; R6 = R1; R7 = R2; R8 = R3; R9 = R4; or when R1-R5 = H, then R, R6-R9 may also be COOH; R', R" = H, 1-4C alkyl or phenyl.
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