公开(公告)号：WO2017083468A1

公开(公告)日：2017-05-18

申请号：PCT/US2016/061244

申请日：2016-11-10

Applicant: ICL-IP AMERICA INC.

Inventor： ZILBERMAN, Joseph ,  PIOTROWSKI, Andrew ,  GLUZ, Eran ,  STOWELL, Jeffrey ,  GLEMONT, Mark ,  CHEN, Zhihao ,  SINGH, Mayank

IPC: C08G18/50 ,  C07F9/02 ,  C08G18/76 ,  C08K5/00 ,  C08G18/38 ,  C08G18/42 ,  C08G18/48 ,  C08K5/49

CPC classification number: C08G18/4208 ,  C07F9/657172 ,  C08G18/388 ,  C08G18/48 ,  C08G18/4804 ,  C08G18/5078 ,  C08G18/7621 ,  C08G18/7664 ,  C08G2101/0008 ,  C08G2101/0025 ,  C08K5/0066 ,  C08K5/49

Abstract: The present invention provides novel cyclic phosphorus-containing compounds, namely hydroxyl-functional phospholene-1-oxides, serving as highly efficient reactive flame retardants in urethane systems, particularly in flexible polyurethane foams, semi-rigid and rigid polyurethane and polyisocyanurate foams. The invention further provides fire-retarded polyurethane compositions comprising said hydroxyl-functional phospholene-1-oxides.

Abstract translation: 本发明提供新的环状含磷化合物，即羟基官能磷杂环戊烯-1-氧化物，用作聚氨酯体系中的高效反应性阻燃剂，特别是软质聚氨酯泡沫体，半刚性和 硬质聚氨酯和聚异氰脲酸酯泡沫。 本发明进一步提供了包含所述羟基官能磷杂环戊烯-1-氧化物的阻燃聚氨酯组合物。

公开(公告)号：WO2017083471A1

公开(公告)日：2017-05-18

申请号：PCT/US2016/061248

申请日：2016-11-10

Applicant: ICL-IP AMERICA INC.

Inventor： ZILBERMAN, Joseph ,  PIOTROWSKI, Andrew ,  GLUZ, Eran ,  STOWELL, Jeffrey ,  GELMONT, Mark ,  CHEN, Zhihao ,  SINGH, Mayank

IPC: C08G18/50 ,  C07F9/02 ,  C08G18/76 ,  C08K5/00 ,  C08G18/38 ,  C08G18/42 ,  C08G18/48 ,  C08K5/49

CPC classification number: C08G18/4208 ,  C07F9/657172 ,  C08G18/388 ,  C08G18/48 ,  C08G18/4804 ,  C08G18/5078 ,  C08G18/7621 ,  C08G18/7664 ,  C08G2101/0008 ,  C08G2101/0025 ,  C08K5/0066 ,  C08K5/49

Abstract: The present invention provides novel cyclic phosphoras-containing compounds, namely hydroxyl-functional phospholene-1-oxides, serving as highly efficient reactive flame retardants in urethane systems, particularly in flexible polyurethane foams, rigid polyurethane foams and rigid polyisocyanurate foams. The invention further provides fire-retarded polyurethane compositions comprising said hydroxyl-functional phospholene-1-oxides.

Abstract translation: 本发明提供了新的含环状磷光体的化合物，即羟基官能磷杂环戊烯-1-氧化物，用作聚氨酯体系中的高效反应性阻燃剂，特别是软质聚氨酯泡沫体，硬质聚氨酯泡沫体和 刚性聚异氰脲酸酯泡沫。 本发明进一步提供了包含所述羟基官能磷杂环戊烯-1-氧化物的阻燃聚氨酯组合物。

公开(公告)号：WO2012040074A1

公开(公告)日：2012-03-29

申请号：PCT/US2011/052083

申请日：2011-09-19

Applicant: ICL-IP AMERICA INC. ,  PIOTROWSKI, Andrew ,  DESIKAN, Anantha, N. ,  DASHEVSKY, Sophia

Inventor： PIOTROWSKI, Andrew ,  DESIKAN, Anantha, N. ,  DASHEVSKY, Sophia

IPC: C07F9/40

CPC classification number: C08K5/5357 ,  C07F9/657181 ,  C08L75/08

Abstract: A monohydroxy cyclic phosphonate substantially free of polyhydroxy phosphonate is employed as a reactive flame retardant in flexible polyurethane.

Abstract translation: 使用基本上不含多羟基膦酸酯的单羟基环状膦酸酯作为柔性聚氨酯中的反应性阻燃剂。

公开(公告)号：WO2010075276A1

公开(公告)日：2010-07-01

申请号：PCT/US2009/068975

申请日：2009-12-21

Applicant: ICL-IP AMERICA INC. ,  ZILBERMAN, Joseph ,  CANFI, Dorit ,  GREGOR, Andrew ,  PIOTROWSKI, Andrew

Inventor： ZILBERMAN, Joseph ,  CANFI, Dorit ,  GREGOR, Andrew ,  PIOTROWSKI, Andrew

IPC: C07F9/12 ,  C08K5/523 ,  C09K21/12

CPC classification number: C07F9/12 ,  C08K5/523 ,  C09K21/12

Abstract: There is provided herein a process for purifying bisphosphate comprising solvating a molten bisphosphate in a mixture of water and water miscible solvent; cooling the solution over a period and to a temperature that provides for crystallization of solid product; increasing the pH of the solution prior to, and/or during, and/or after the initiation of crystallization, and/or after crystallization, by the addition of a base; and after crystallization is complete, separating solid product from the solution; washing the separated solid product in the same and/or different mixture of water and water miscible solvent; and, washing the solid product which has been washed in the mixture with water.

Abstract translation: 本文提供了一种纯化二磷酸盐的方法，其包括在水和水混溶性溶剂的混合物中溶解熔融的二磷酸盐; 在一段时间内将溶液冷却至提供固体产物结晶的温度; 在结晶开始之前和/或期间和/或之后，和/或在结晶后，通过加入碱来增加溶液的pH值; 结晶完成后，将固体产物与溶液分离; 在与水和水混溶的溶剂的相同和/或不同混合物中洗涤分离的固体产物; 并且用水洗涤已经在混合物中洗涤的固体产物。

公开(公告)号：WO2019023091A1

公开(公告)日：2019-01-31

申请号：PCT/US2018/043219

申请日：2018-07-23

Applicant: ICL-IP AMERICA INC.

Inventor： PIOTROWSKI, Andrew ,  ZILBERMAN, Joseph ,  STOWELL, Jeffrey ,  GELMONT, Mark ,  SINGH, Mayank ,  CHEN, Zhihao ,  GLUZ, Eran

IPC: C08G18/76 ,  C08G18/18 ,  C08G18/28 ,  C08G18/42 ,  C08K5/00 ,  C08G101/00 ,  C08K5/5313

Abstract: The present invention provides fire -retarded rigid polyurethane foam comprising the reaction product of polyol and isocyanate foam forming components and a dialkyl phosphorus-containing compound, namely a reactive mono-hydroxyl-functional dialkyl phosphinates, as flame retardant, serving as highly efficient reactive flame retardant in said rigid polyurethane foam.

公开(公告)号：WO2017083136A1

公开(公告)日：2017-05-18

申请号：PCT/US2016/059878

申请日：2016-11-01

Applicant: ICL-IP AMERICA INC.

Inventor： PIOTROWSKI, Andrew ,  ZILBERMAN, Joseph ,  LEVCHIK, Sergei ,  ZHANG, Meng ,  GLUZ, Eran ,  SURYADEVARA, Kali

IPC: C08G63/692 ,  B32B27/38 ,  C08J5/24 ,  C08G59/42 ,  H05K1/03

CPC classification number: C08G63/6926 ,  B32B15/08 ,  B32B15/20 ,  B32B27/08 ,  B32B27/26 ,  B32B27/38 ,  B32B2260/021 ,  B32B2260/046 ,  B32B2262/101 ,  B32B2307/3065 ,  B32B2457/08 ,  C08G59/4071 ,  C08G59/4276 ,  C08J5/24 ,  C08J2363/00 ,  C08L63/00 ,  H05K1/0326 ,  H05K1/0373 ,  H05K2201/012 ,  C08L67/00

Abstract: There is provided herein a flame retardant and curing agent compound for curing thermosetting resins, e.g., epoxy resins, a composition comprising a thermosetting resin, e.g., epoxy resin and the curing agent, an article comprising the curing agent, and a method of making the curing agent.

Abstract translation: 本文提供了用于固化热固性树脂（例如环氧树脂）的阻燃剂和固化剂化合物，包含热固性树脂（例如环氧树脂和固化剂）的组合物，包含固化剂 剂，以及制造固化剂的方法。

公开(公告)号：WO2019023090A1

公开(公告)日：2019-01-31

申请号：PCT/US2018/043218

申请日：2018-07-23

Applicant: ICL-IP AMERICA INC.

Inventor： PIOTROWSKI, Andrew ,  ZILBERMAN, Joseph ,  STOWELL, Jeffrey ,  GELMONT, Mark ,  SINGH, Mayank ,  CHEN, Zhihao ,  GLUZ, Eran

IPC: C08G18/76 ,  C08G18/18 ,  C08G18/28 ,  C08G18/42 ,  C08K5/00 ,  C08G101/00 ,  C08K5/5313

Abstract: The present invention provides dialkyl phosphorus-containing compounds, namely reactive mono-hydroxyl-functional dialkyl phosphinates, serving as highly efficient reactive flame retardants in flexible polyurethane foams. The invention further provides fire-retarded polyurethane compositions comprising said the reaction product of the mono-hydroxyl-functional dialkyl phosphinates with polyol and isocyanate foam forming components.

公开(公告)号：WO2018031103A1

公开(公告)日：2018-02-15

申请号：PCT/US2017/035453

申请日：2017-06-01

Applicant: ICL-IP AMERICA INC.

Inventor： PIOTROWSKI, Andrew ,  ZHANG, Meng ,  ALESSIO, Gerald, R. ,  ZILBERMAN, Joseph ,  GLUZ, Eran

IPC: C08G63/692 ,  C08L63/00 ,  C08G59/42 ,  C08G59/40

CPC classification number: C08L63/00 ,  C08G59/4071 ,  C08G59/42 ,  C08G63/6926 ,  C08L67/02

Abstract: There is provided herein a curable epoxy composition comprising (a) at least one epoxy compound; (b) at least one oligomeric aromatic polyester phosphorus- containing curing agent; and, (c) at least one co-curing agent having a dielectric constant less than 4.0, or at least one co-curing agent which results in the cured epoxy composition having a dielectric constant of less than 4.0 and wherein the co-curing agent is other than the curing agent (b); and, an article comprising the curing agent, and a process of making a laminate.

Abstract translation: 这里提供了一种可固化的环氧组合物，其包含（a）至少一种环氧化合物; （b）至少一种低聚芳族聚酯含磷固化剂; 和（c）至少一种介电常数小于4.0的共固化剂，或至少一种导致固化的环氧组合物具有小于4.0的介电常数的共固化剂，并且其中共固化剂 不是固化剂（b）; 以及包含该固化剂的制品，以及制造层压制品的方法。

公开(公告)号：WO2017083463A1

公开(公告)日：2017-05-18

申请号：PCT/US2016/061236

申请日：2016-11-10

Applicant: ICL-IP AMERICA INC.

Inventor： ZILBERMAN, Joseph ,  PIOTROWSKI, Andrew ,  GLUZ, Eran ,  STOWELL, Jeffrey ,  GELMONT, Mark ,  CHEN, Zhihao ,  SINGH, Mayank

IPC: C08G18/50 ,  C07F9/02 ,  C08G18/76 ,  C08K5/00 ,  C08G18/38 ,  C08G18/42 ,  C08G18/48 ,  C08K5/49

CPC classification number: C08G18/4208 ,  C07F9/657172 ,  C08G18/388 ,  C08G18/48 ,  C08G18/4804 ,  C08G18/5078 ,  C08G18/7621 ,  C08G18/7664 ,  C08G2101/0008 ,  C08G2101/0025 ,  C08K5/0066 ,  C08K5/49

Abstract: The present invention provides novel cyclic phosphorus-containing compounds, namely hydroxyl-functional phospholene-1-oxides, serving as highly efficient reactive flame retardants in urethane systems, particularly in flexible polyurethane foams, rigid polyurethane foams and rigid polyisocyanurate foams. The invention further provides fire-retarded polyurethane compositions comprising said hydroxyl-functional phospholene-1-oxides.

Abstract translation: 本发明提供新型环状含磷化合物，即羟基官能磷杂环戊烯-1-氧化物，用作聚氨酯体系中的高效反应性阻燃剂，特别是软质聚氨酯泡沫体，硬质聚氨酯泡沫体和 刚性聚异氰脲酸酯泡沫。 本发明进一步提供了包含所述羟基官能磷杂环戊烯-1-氧化物的阻燃聚氨酯组合物。

公开(公告)号：WO2015094961A1

公开(公告)日：2015-06-25

申请号：PCT/US2014/070000

申请日：2014-12-12

Applicant: ICL-IP AMERICA INC.

Inventor： STOWELL, Jeffrey, K. ,  PIOTROWSKI, Andrew ,  NAGRIDGE, Mike ,  SYMES, Greg ,  PINZONI, Manny ,  DESIKAN, Anantha ,  SCHAFER, Francis

IPC: C09K21/12

CPC classification number: C09K21/12 ,  C08J9/0038 ,  C08J2205/06 ,  C08J2375/04 ,  C08K5/521 ,  C08K5/523 ,  C08K5/5357 ,  C08K2201/014

Abstract: There is provided herein a flame retardant additive composition comprising (a) a cyclic phosphonate mixture of (i) (5-ethyl-2-methyl-2-oxido-l,3,2-dioxaphosphorinan-5-yl)methyl methyl ester of P-alkylphosphonic acid and (ii) bis[(5-ethyl-2-2-methyl-2- oxido-l,3,2-dioxaphosphorinan-5-yl)methyl]ester of P-alkyl phosphonic acid; and, (b) an aryl bisphosphate ester of the general formula (I) herein. There is also provided herein a polyurethane foam containing the flame retardant additive composition as well as articles made comprising said polyurethane foam.

Abstract translation: 本文提供了一种阻燃添加剂组合物，其包含（a）（i）（5-乙基-2-甲基-2-氧化-1,2-二氧杂磷杂环己烷-5-基）甲基甲基酯的环状膦酸酯混合物， 对 - 烷基膦酸和（ii）P-烷基膦酸的双[（5-乙基-2,2-甲基-2-氧代-1,3,2-二氧杂磷杂环己烷-5-基）甲基]酯; 和（b）本文通式（I）的芳基二磷酸酯。 本文还提供含有阻燃添加剂组合物的聚氨酯泡沫以及由所述聚氨酯泡沫制成的制品。