公开(公告)号：US20150287606A1

公开(公告)日：2015-10-08

申请号：US14744835

申请日：2015-06-19

Applicant: INSTITUTE OF MICROELECTRONICS, CHINESE ACADEMY OF SCIENCES

Inventor： Qiang Xu ,  Chao Zhao ,  Jun Luo ,  Guilei Wang ,  Tao Yang ,  Junfeng Li

IPC: H01L21/285 ,  H01L21/28

CPC classification number: H01L21/28562 ,  C23C16/0272 ,  C23C16/14 ,  C23C16/45525 ,  H01L21/28079 ,  H01L21/28088 ,  H01L21/32051 ,  H01L21/76876 ,  H01L21/76877 ,  H01L29/66545

Abstract: A method of depositing a tungsten (W) layer is disclosed. In one aspect, the method includes depositing a SiH4 base W film on a surface of a substrate to preprocess the surface. The method includes depositing a B2H6 base W layer on the preprocessed surface. The SiH4 base W film may be several atom layers thick. The film and base W layer may be deposited in a single ALD process, include reactive gas soak, reactive gas introduction, and main deposition operations. Forming the film may include introducing SiH4 gas into a reactive cavity during the gas soak operation, and introducing SiH4 and WF6 gas into the cavity during the gas introduction operation. The SiH4 and WF6 gases may be alternately introduced, for a number of cycles depending on the thickness of the tungsten layer to be deposited.

Abstract translation: 公开了沉积钨（W）层的方法。 一方面，该方法包括在衬底的表面上沉积SiH 4基底W膜以预处理该表面。 该方法包括在预处理的表面上沉积B2H6基底W层。 SiH4基底W膜可以是几个原子层厚。 膜和基底W层可以沉积在单个ALD工艺中，包括反应气体浸泡，反应气体引入和主沉积操作。 形成膜可以包括在气体浸泡操作期间将SiH 4气体引入反应腔中，并且在气体引入操作期间将SiH 4和WF 6气体引入空腔。 SiH4和WF6气体可以根据待沉积的钨层的厚度交替地引入多个循环。

公开(公告)号：US09589809B2

公开(公告)日：2017-03-07

申请号：US14744835

申请日：2015-06-19

Applicant: INSTITUTE OF MICROELECTRONICS, CHINESE ACADEMY OF SCIENCES

Inventor： Qiang Xu ,  Chao Zhao ,  Jun Luo ,  Guilei Wang ,  Tao Yang ,  Junfeng Li

IPC: H01L21/28 ,  H01L21/285 ,  C23C16/02 ,  C23C16/14 ,  C23C16/455 ,  H01L21/3205 ,  H01L21/768

CPC classification number: H01L21/28562 ,  C23C16/0272 ,  C23C16/14 ,  C23C16/45525 ,  H01L21/28079 ,  H01L21/28088 ,  H01L21/32051 ,  H01L21/76876 ,  H01L21/76877 ,  H01L29/66545

Abstract: A method of depositing a tungsten (W) layer is disclosed. In one aspect, the method includes depositing a SiH4 base W film on a surface of a substrate to preprocess the surface. The method includes depositing a B2H6 base W layer on the preprocessed surface. The SiH4 base W film may be several atom layers thick. The film and base W layer may be deposited in a single ALD process, include reactive gas soak, reactive gas introduction, and main deposition operations. Forming the film may include introducing SiH4 gas into a reactive cavity during the gas soak operation, and introducing SiH4 and WF6 gas into the cavity during the gas introduction operation. The SiH4 and WF6 gases may be alternately introduced, for a number of cycles depending on the thickness of the tungsten layer to be deposited.

Abstract translation: 公开了沉积钨（W）层的方法。 一方面，该方法包括在衬底的表面上沉积SiH 4基底W膜以预处理该表面。 该方法包括在预处理的表面上沉积B2H6基底W层。 SiH4基底W膜可以是几个原子层厚。 膜和基底W层可以沉积在单个ALD工艺中，包括反应气体浸泡，反应气体引入和主沉积操作。 形成膜可以包括在气体浸泡操作期间将SiH 4气体引入反应腔中，并且在气体引入操作期间将SiH 4和WF 6气体引入空腔。 SiH4和WF6气体可以根据待沉积的钨层的厚度交替地引入多个循环。