EXPANDED POLYPROPYLENE RESIN BEAD AND PROCESS OF PRODUCING SAME
    1.
    发明申请
    EXPANDED POLYPROPYLENE RESIN BEAD AND PROCESS OF PRODUCING SAME 审中-公开
    膨胀型聚丙烯树脂珠及其制造方法

    公开(公告)号:WO0224794A9

    公开(公告)日:2002-05-10

    申请号:PCT/JP0108187

    申请日:2001-09-20

    CPC classification number: C08J9/224 C08J2323/10 C08L23/10 C08L2203/14

    Abstract: Expanded, substantially non-crosslinked polypropylene resin beads capable of producing a high rididity foamed molding at a relatively low temperature. The beads are produced by a process including a step of dispersing substantially non-crosslinked polypropylene resin particles in a dispersing medium containing an organic peroxide to obtain a dispersion, a step of heating the dispersion to decompose the organic peroxide and to modify the surface of the surface-modified polypropylene resin particles, and a step of expanding the non-crosslinked, surface-modified polypropylene resin particles using a blowing agent.

    Abstract translation: 膨胀的基本上非交联的聚丙烯树脂珠粒能够在相对较低的温度下产生高吸收性发泡模制品。 通过包括以下步骤的方法生产珠粒:将基本上未交联的聚丙烯树脂颗粒分散在含有机过氧化物的分散介质中以获得分散体,加热分散体以分解有机过氧化物和改性 表面改性聚丙烯树脂颗粒,以及使用发泡剂使未交联的表面改性聚丙烯树脂颗粒发泡的步骤。

    EXPANDED POLYPROPYLENE RESIN BEAD
    3.
    发明申请
    EXPANDED POLYPROPYLENE RESIN BEAD 审中-公开
    膨胀聚丙烯树脂珠

    公开(公告)号:WO0224794A3

    公开(公告)日:2002-12-05

    申请号:PCT/JP0108187

    申请日:2001-09-20

    CPC classification number: C08J9/224 C08J2323/10 C08L23/10 C08L2203/14

    Abstract: Expanded, substantially non-crosslinked polypropylene resin beads capable of producing a high rididity foamed molding at a relatively low temperature. The beads are produced by a process including a step of dispersing substantially non-crosslinked polypropylene resin particles in a dispersing medium containing an organic peroxide to obtain a dispersion, a step of heating the dispersion to decompose the organic peroxide and to modify the surface of the surface-modified polypropylene resin particles, and a step of expanding the non-crosslinked, surface-modified polypropylene resin particles using a blowing agent.

    Abstract translation: 膨胀的,基本上非交联的聚丙烯树脂珠,其能够在相对较低的温度下产生高的吸附发泡成型。 珠粒通过包括将基本上未交联的聚丙烯树脂颗粒分散在含有机过氧化物的分散介质中以获得分散体的步骤的方法制备,加热分散体以分解有机过氧化物并改性表面的步骤 表面改性聚丙烯树脂颗粒,以及使用发泡剂使未交联的表面改性聚丙烯树脂颗粒膨胀的步骤。

    SHOCK ABSORBING MATERIAL
    6.
    发明公开
    SHOCK ABSORBING MATERIAL 失效
    减震材料

    公开(公告)号:EP0918066A4

    公开(公告)日:2002-06-19

    申请号:EP97934755

    申请日:1997-08-08

    Applicant: JSP CORP

    Abstract: A conventional shock absorbing material formed from a foamed molding of polypropylene resin particles has an excellent cushioning property and impact resilience as compared with shock absorbing materials formed of other material resins, but is not satisfactory in terms of rigidity and energy absorbing efficiency. The present invention provides a shock absorbing material formed from an in-mold formed molding manufactured by using foamed particles, of which a base material resin is a propylene homopolymer prepared with the use of a metallocene polymerization catalyst. The base material resin has a tensile elastic modulus of 15000 kgf/cm2 or more, and the in-mold formed molding has such a crystal structure that an intrinsic peak a and a high temperature peak b appear as endothermic peaks in the DSC curve obtained by differential scanning calorimetry of the molding. The high temperature peak b appears on a higher temperature side than the inherent peak a does, and has a heat quantity of 25 J/g or more.

    EXPANDABLE POLYPROPYLENE RESIN BEADS AND PRODUCTS OF IN-MOLD EXPANSION
    7.
    发明公开
    EXPANDABLE POLYPROPYLENE RESIN BEADS AND PRODUCTS OF IN-MOLD EXPANSION 有权
    发泡聚丙烯树脂珠和因膨胀IN形式获得的产品

    公开(公告)号:EP1036814A4

    公开(公告)日:2001-07-18

    申请号:EP98956020

    申请日:1998-12-01

    Applicant: JSP CORP

    CPC classification number: C08J9/18 C08J9/16 C08J2203/06 C08J2323/12

    Abstract: Expandable beads comprising as the base resin a propylene random copolymer prepared by copolymerizing propylene with one or more comonomers selected from the group consisting of ethylene and α-olefins having 4 or more carbon atoms in the presence of a metallocene polymerization catalyst, wherein the propylene random copolymer is an isotactic one having a melting point exceeding 140 °C and a melt flow rate of 12 g/10 min or below. For example, propylene/ethylene random copolymers are suitably usable as the base resin. Products of in-mold expansion are produced by packing the expandable beads in a mold and expanding the beads by steam heating to fuse the beads with each other into a cavity-shaped product.

    METHOD FOR PRODUCING POLYPROPYLENE TYPE RESIN FOAMED PARTICLE
    8.
    发明公开
    METHOD FOR PRODUCING POLYPROPYLENE TYPE RESIN FOAMED PARTICLE 有权
    用于生产发泡聚丙烯

    公开(公告)号:EP1403305A4

    公开(公告)日:2004-12-15

    申请号:EP02736043

    申请日:2002-06-10

    Applicant: JSP CORP

    CPC classification number: C08J9/18 B29C44/445 C08J2203/06 C08J2323/12

    Abstract: A method for producing polypropylene type resin foamed particles wherein polypropylene type resin particles impregnated with a physical foaming agent and heated together with an aqueous medium and a dispersing agent are released out of a closed vessel to a low pressure region, to produce foamed particles, characterized in that the aqueous medium has an electric conductivity of 0.00 mS/m to 20.00 mS/m. The method can be used for producing good polyolefin resin foamed particles free from the mutual adhesion during its production with almost same amounts, independent of locations of plants for production, of a dispersing agent added for preventing the adhesion of particles in a heat treatment process for impregnating resin particles dispersed in an aqueous medium in a closed vessel with a foaming agent, and of the dispersing agent attached to the resultant foamed articles. The above polyolefin resin foamed particles exhibit good melting and mutual adhesion in a step of forming them and can provide a formed article having excellent mechanical strength, and further can be produced with stability.

    EXPANDED PARTICLES OF POLYOLEFIN RESIN AND PROCESS FOR PREPARING THE SAME
    9.
    发明公开
    EXPANDED PARTICLES OF POLYOLEFIN RESIN AND PROCESS FOR PREPARING THE SAME 失效
    为了生产膨胀聚烯烃和方法

    公开(公告)号:EP0905176A4

    公开(公告)日:2000-11-22

    申请号:EP97926228

    申请日:1997-06-11

    Applicant: JSP CORP

    CPC classification number: C08J9/18 C08J9/0066 C08J2201/03 C08J2323/02

    Abstract: When it is intended to obtain foamed particles having a high expansion ratio upon the production of foamed particles of a polyolefin resin, there has been a problem that foamed particles uneven in cell diameter are produced. Any molded article produced with such foamed particles has involved a drawback that it is poor in dimensional stability, and its surface profile becomes uneven. The invention relates to foamed particles comprising a polyolefin resin as a base resin, wherein the base resin contains a metal salt (excluding alkali metal salts) of boric acid in such a manner that the content of the metal salt of boric acid in the raw resin amounts to 50-50,000 ppm. Zinc borate, magnesium borate or the like is used as the metal salt of boric acid. The foamed particles are obtained by using a polyolefin resin containing the metal salt of boric acid to prepare resin particles, dispersing the resin particles in a dispersion medium in a closed vessel and at the same time impregnating the resin particles with a foaming agent, holding the resin particles in a heated and pressurized atmosphere, and then releasing the resin particles together with the dispersion medium into an atmosphere of a pressure lower than the internal pressure of the vessel to expand the resin particles.

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