公开(公告)号：JP2006233168A

公开(公告)日：2006-09-07

申请号：JP2005195695

申请日：2005-07-05

Applicant: Jsr Corp ,  Jsr株式会社

Inventor： SHINOHARA NOBUYASU ,  USUI NOBUSHI ,  TANABE TAKAYOSHI

IPC: C08F220/36 ,  B32B27/00 ,  B32B27/30 ,  B32B27/40 ,  C08F230/08 ,  C09D4/00 ,  C09D175/14

Abstract: PROBLEM TO BE SOLVED: To provide a curable composition which has excellent applicability and can form a coating film having a high hardness, reduced curling after immersion in hot water, and excellent scratch resistance on the surfaces of various substrates and to provide a cured film comprising a cured product of the same. SOLUTION: The curable composition comprises the component (A) 5 to 70 mass% of metal oxide particles containing a bonded polymerizable unsaturated organic compound and having a refractive index of 1.50 or higher and the component (B) 10 to 50 mass% of compound represented by formula (1); a cured product prepared by curing the composition; and a laminate. COPYRIGHT: (C)2006,JPO&NCIPI

Abstract translation: 要解决的问题：提供一种具有优异适用性的可固化组合物，并且可以形成具有高硬度的涂膜，浸渍在热水中之后减少的卷曲，并且在各种基材的表面上具有优异的耐擦伤性，并提供 固化膜包含其固化产物。 解决方案：可固化组合物包含组分（A）5至70质量％的含有键合的可聚合不饱和有机化合物的金属氧化物颗粒，折射率为1.50以上，成分（B）为10〜50质量％ 由式（1）表示的化合物; 通过固化组合物制备的固化产物; 和层压板。 版权所有（C）2006，JPO＆NCIPI

公开(公告)号：JP2002229192A

公开(公告)日：2002-08-14

申请号：JP2001027408

申请日：2001-02-02

Applicant: JSR CORP

Inventor： EHATA SATOSHI ,  USUI NOBUSHI ,  ISHII HIROYUKI ,  KATAOKA ATSUKO ,  KAJITA TORU

IPC: G03F7/004 ,  C07D333/16 ,  C08K5/45 ,  C08L101/00 ,  G03F7/038 ,  G03F7/039 ,  H01L21/027

Abstract: PROBLEM TO BE SOLVED: To provide a new radiation sensitive acid generating agent capable of giving positive and negative radiation sensitive resin compositions having high transparency particularly to far UV typified by ArF excimer laser light (193 nm wavelength) and excellent in sensitivity, resolution, pattern shape, etc., and to provide positive and negative radiation sensitive resin compositions containing the radiation sensitive acid generating agent. SOLUTION: The radiation sensitive acid generating agent is typified, e.g. by a compound having a sulfonium cation of formula (1), (2) or (3) and C4F9SO3- as a counter anion. The positive radiation sensitive resin composition contains the radiation sensitive acid generating agent and an acid dissociable group- containing resin. The negative radiation sensitive resin composition contains the radiation sensitive acid generating agent, an alkali-soluble resin and a crosslinker.

公开(公告)号：JP2007031625A

公开(公告)日：2007-02-08

申请号：JP2005219935

申请日：2005-07-29

Applicant: Japan Fine Coatings Co Ltd ,  Jsr Corp ,  Jsr株式会社 ,  日本特殊コーティング株式会社

Inventor： SHINOHARA NOBUYASU ,  USUI NOBUSHI ,  TANABE TAKAYOSHI

IPC: C08F220/36 ,  C08K3/24 ,  C08L33/14 ,  C08L57/00

Abstract: PROBLEM TO BE SOLVED: To provide a curable composition having good coatability, capable of imparting antistaticity onto the surfaces of various substrates, and capable of forming coating film of high scratch resistance and slidability, and to provide cured film consisting of the cured product of the composition. SOLUTION: The curable composition comprises (A) 5-50 mass% of zinc antimonate, (B) 10-50 mass% of a compound of formula (1), (C) 10-70 mass% of a multifunctional (meth)acrylate compound other than the components (A) and (B), and (D) 0.2-9 mass% of organic or inorganic microparticles with a number-average size of 0.1-3 μm determined by dynamic light-scattering technique; wherein the respective mass proportions are based on the whole composition except a solvent therein. The cured product obtained by curing the composition is provided. Laminates comprising the cured product are also provided. COPYRIGHT: (C)2007,JPO&INPIT

Abstract translation: 要解决的问题：提供一种具有良好的涂布性的固化性组合物，能够在各种基材的表面上赋予抗静电性，并且能够形成具有高耐擦伤性和滑动性的涂膜，并且提供由固化的 产品的组成。 解决方案：可固化组合物包含（A）5-50质量％的锑酸锌，（B）10-50质量％的式（1）化合物，（C）10-70质量％的多官能 （A）和（B）以外的（甲）丙烯酸酯化合物，（D）通过动态光散射技术测定的数均分子量为0.1〜3μm的有机或无机微粒的0.2〜9质量％ 其中相应的质量比例基于除其中的溶剂之外的全部组合物。 提供通过固化该组合物获得的固化产物。 还提供了包含固化产物的层压材料。 版权所有（C）2007，JPO＆INPIT

公开(公告)号：JP2006327990A

公开(公告)日：2006-12-07

申请号：JP2005154361

申请日：2005-05-26

Applicant: Jsr Corp ,  Jsr株式会社

Inventor： USUI NOBUSHI ,  HATORI SHIN ,  SHINOHARA NOBUYASU ,  TANABE TAKAYOSHI

IPC: C07C271/28 ,  B05D7/24 ,  B32B27/30 ,  C08F299/06

Abstract: PROBLEM TO BE SOLVED: To provide a radiation curing composition having excellent coating properties and forming a coated film (coat) having high hardness and high refractive index and excellent scuff resistance and adhesiveness to a substrate and a low-refractive index layer on the surfaces of various kinds of substrates and to provide a cured film thereof.
SOLUTION: The radiation curing composition comprises (B) a compound represented by formula (1) (wherein, m and n are each an integer of 0-3), (C) a photopolymerization initiator and (E) a solvent.
COPYRIGHT: (C)2007,JPO&INPIT

Abstract translation: 要解决的问题：提供具有优异涂布性能的辐射固化组合物，并且形成具有高硬度和高折射率的涂膜（涂层），并且对基材和低折射率层具有优异的耐擦伤性和粘附性 各种基材的表面，并提供其固化膜。 解决方案：辐射固化组合物包含（B）由式（1）表示的化合物（其中m和n各自为0-3的整数），（C）光聚合引发剂和（E）溶剂。 版权所有（C）2007，JPO＆INPIT

公开(公告)号：JP2006307028A

公开(公告)日：2006-11-09

申请号：JP2005131774

申请日：2005-04-28

Applicant: Jsr Corp ,  Jsr株式会社

Inventor： USUI NOBUSHI ,  HATORI SHIN ,  SHINOHARA NOBUYASU ,  TANABE TAKAYOSHI

IPC: C08G18/67 ,  C08F299/06 ,  C09D4/00 ,  C09D7/12 ,  C09D175/16

Abstract: PROBLEM TO BE SOLVED: To provide a radiation-curable composition which is excellent in applicability and is capable of forming a coating film on surfaces of various substrates, wherein the coating film has a high hardness and a high refractive index and is excellent in scratch resistance and adhesion property to the substrate and a low-refractive-index layer, and its cured product.
SOLUTION: The radiation-curable composition contains a compound of formula (2) [wherein multiple R
1 s are each independently a monovalent organic group having a (meth)acryloyl group; multiple R
2 s are each independently a 2-4C alkylene group; and m and n are each independently an integer of 1-3], a photopolymerization initiator and a solvent.
COPYRIGHT: (C)2007,JPO&INPIT

Abstract translation: 解决的问题：为了提供适用性优异并且能够在各种基材的表面上形成涂膜的可辐射固化组合物，其中涂膜具有高硬度和高折射率，并且优异 对基材和低折射率层的耐擦伤性和粘合性，及其固化产物。 解决方案：可辐射固化组合物含有式（2）的化合物[其中多个R 1具有（甲基）丙烯酰基的一价有机基团; 多个R“SP”2各自独立地为2-4C亚烷基; m和n各自独立地为1-3的整数]，光聚合引发剂和溶剂。 版权所有（C）2007，JPO＆INPIT

公开(公告)号：JP2006182826A

公开(公告)日：2006-07-13

申请号：JP2004375459

申请日：2004-12-27

Applicant: Japan Fine Coatings Co Ltd ,  Jsr Corp ,  Jsr株式会社 ,  日本特殊コーティング株式会社

Inventor： SHINOHARA NOBUYASU ,  HATORI SHIN ,  USUI NOBUSHI ,  TANABE TAKAYOSHI

IPC: C08F299/06 ,  B32B27/30 ,  B32B27/40 ,  C09D4/00 ,  C09D5/00 ,  C09D175/14

CPC classification number: C09D175/16 ,  C08G18/809 ,  C08G18/8175 ,  G02B1/105 ,  G02B1/14 ,  G03F7/0047 ,  G03F7/027

Abstract: PROBLEM TO BE SOLVED: To provide a curing composition which has superior coating property and can form a coating film (coat) high in hardness and rich in flexibility, and a cured film formed of its cured article.
SOLUTION: The curing composition characterised by containing 20-80 mass% of metal oxide particles (A) formed by bonding an organic compound having a polymerizable unsaturated group with them and having a refractive index of 1.5 or higher, and 10-70 mass% of a urethane (meth)arcylate compound (B) of which a number-average molecular weight converted in terms of polystyrene in gas permeation chromatography (GPC) pattern is 750 or higher to the whole of the composition excluding a solvent; and the cured article formed by curing the curing composition and a laminate including the cured article; are provided.
COPYRIGHT: (C)2006,JPO&NCIPI

Abstract translation: 要解决的问题：提供具有优异的涂布性能并且可以形成硬度高和柔韧性高的涂膜（涂层）的固化组合物以及由其固化物形成的固化膜。 解决方案：固化组合物的特征在于含有20-80质量％的金属氧化物颗粒（A），其通过将具有聚合性不饱和基团的有机化合物与它们折射而成，折射率为1.5以上，10-70 以气体渗透色谱法（GPC）图案中的聚苯乙烯换算的数均分子量为除了溶剂以外的组合物的总和为750以上的氨基甲酸酯（甲基）氨基甲酸酯化合物（B）的质量％ 以及通过使固化组合物固化而形成的固化物和包含固化物的层压体; 被提供。 版权所有（C）2006，JPO＆NCIPI

公开(公告)号：JP2006328237A

公开(公告)日：2006-12-07

申请号：JP2005154360

申请日：2005-05-26

Applicant: Jsr Corp ,  Jsr株式会社

Inventor： USUI NOBUSHI ,  HATORI SHIN ,  SHINOHARA NOBUYASU ,  TANABE TAKAYOSHI

IPC: C08G59/14 ,  C07C271/28 ,  C08F299/00 ,  C08G18/67

Abstract: PROBLEM TO BE SOLVED: To provide a radiation-curable composition which exhibits an excellent coatability and forms a coating film having high hardness, reflective index and scratch resistance and an excellent adhesion to a substrate and a low reflective layer and its cured material.
SOLUTION: The radiation-curable composition includes (B) a compound expressed by formula (2), (C) a photopolymerization initiator and (E) a solvent. In formula (2), R
1 's are each independently a monovalent organic group having a (meth)acryloyl group; R
2 's are each a divalent organic group having a (meth)acryloyl group; m and n are each independently an integer of 0-3.
COPYRIGHT: (C)2007,JPO&INPIT

Abstract translation: 要解决的问题：提供一种具有优异涂布性的可辐射固化组合物，并形成具有高硬度，反射指数和耐刮擦性以及对基材和低反射层及其固化物质的优异粘附性的涂膜 。 解决方案：可辐射固化组合物包括（B）由式（2）表示的化合物，（C）光聚合引发剂和（E）溶剂。 在式（2）中，R“SP”1各自独立地为具有（甲基）丙烯酰基的一价有机基团; R 2 SP 2各自为具有（甲基）丙烯酰基的二价有机基团; m和n各自独立地为0-3的整数。 版权所有（C）2007，JPO＆INPIT

公开(公告)号：JP2006199912A

公开(公告)日：2006-08-03

申请号：JP2005131739

申请日：2005-04-28

Applicant: Japan Fine Coatings Co Ltd ,  Jsr Corp ,  Jsr株式会社 ,  日本特殊コーティング株式会社

Inventor： SHINOHARA NOBUYASU ,  SUZUKI YASUNOBU ,  ITAI SHINGO ,  USUI NOBUSHI ,  TANABE TAKAYOSHI

IPC: C08L33/14 ,  B32B27/20 ,  C08F2/44 ,  C09D4/02 ,  C09D7/12

CPC classification number: C09D4/00

Abstract: PROBLEM TO BE SOLVED: To provide a curable composition having excellent coating abilities, imparting antistatic properties to the surface of several substrates and forming coating film (covering) excellent in excoriation resistance, and to provide a cured film comprising the cured product.
SOLUTION: The curable composition contains following component (A) 5-50 mass% zinc antimonate particle and (B) 10-50 mass% compound represented by formula (1), based on whole composition except solvents. The cured products and laminates are obtained by curing the composition. [In formula (1), R
1 , R
2 and R
3 are each independently a univalent organic group; at least two of R
1 to R
3 are R
4 OCOCR
5 =CH
2 ; R
4 is a 2-8C divalent organic group; and R
5 is H, or methyl].
COPYRIGHT: (C)2006,JPO&NCIPI

Abstract translation: 要解决的问题：提供具有优异的涂布能力的固化性组合物，赋予多种基材的表面抗静电性能并形成耐排除性优异的涂膜（覆盖物），并提供包含该固化产物的固化膜。 解决方案：除了溶剂之外，固化性组合物含有5-50质量％的锑酸锌颗粒和（B）10-50质量％的由式（1）表示的化合物的组分（A）。 固化产物和层压体通过固化组合物获得。 [式（1）中，R SP 1，R SP 2，R SP 3各自独立地为一价有机基团; R 1 至R 3 中的至少两个是R 4 OCOCR 5 = CH < SB>; R 4 是2-8C二价有机基团; 和R 5 是H或甲基]。 版权所有（C）2006，JPO＆NCIPI